1,6-di(o-hydrxyphenyl)-4,7,10,13-tetraaza-3,14-dimethyl-2,14-diene-1,8,9,16-hexadecatetraone | 160156-75-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1,6-di(o-hydrxyphenyl)-4,7,10,13-tetraaza-3,14-dimethyl-2,14-diene-1,8,9,16-hexadecatetraone
• CAS: 160156-75-2
• 化学式: C₂₆H₃₀N₄O₆
• 分子量: 494.547
• InChiKey: TVKMQFLQUOZAPN-UHFFFAOYSA-N

物化性质

• 密度：
  1.262±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.38
• 重原子数：
  36.0
• 可旋转键数：
  12.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  156.86
• 氢给体数：
  6.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  1,6-di(o-hydrxyphenyl)-4,7,10,13-tetraaza-3,14-dimethyl-2,14-diene-1,8,9,16-hexadecatetraone 在 LiOH*H₂O 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Tetra- and Polynuclear Metal Complexes Derived from an Oxamido Homodinuclear Cu(II) Complex as a Chelating Agent

  摘要：

  The homodinuclear Cu(II) complex, [(H2L)Cu-2].2H(2)O, of an axamido ligand, 1,6-di(o-hydroxyphenyl)-4, 7, 10, 13-tetraza-3,14-dimethyl-2,14,-diene-1,8,9,16-hexadecatetraone, H6L, was used as a chelating agent towards metal cations. Homo- and heterotetranuclear and polynuclear complexes of the types [LCu2M2Cl2]. xH(2)O or [(HL)Cu2MCl(OH)(2)](2) . xH(2)O (M = Cu(II), Ni(II), Mn(II) or Co(II)), [(Hl)Cu-2(UO2)(1/2)(H2O)(1/2)](2) . 6H(2)O, [LCu2Fe4Cl10(OH2)(4)]. 8H(2)O and [LCu2Fe2(O4S)(2)(MeOH)(2)](n) are obtained. Addition of LiOH as a deprotonating agent plays an important rule in producing different products. In addition, on changing the molar ratios of the reactants, different complexes were obtained. The products were characterized by chemical analyses, UV-Visible, IR and ESR spectroscopy, mass spectrometry and magnetic moment determinations. Antiferromagnetic interactions between adjacent metal cations were observed and are attributed to the effect of the oxamido linkage and chloride or oxygen bridges in transferring magnetic effects between different metalic cations in the complex molecules.

  DOI：

  10.1080/00945719708000236

文献信息

• Stefan, Shaker L.; El-Behairy, Moustafa; Khalil, Saied M. E., Journal of Chemical Research - Part S
  作者：Stefan, Shaker L.、El-Behairy, Moustafa、Khalil, Saied M. E.、El-Halim, Hanan F. Abd

  DOI：——

  日期：——