(N,N'-(p-CH3OC6H4)2-2,3-Me2-1,4-diaza-1,3-butadiene)Fe(CO)3 | 65016-01-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (N,N'-(p-CH3OC6H4)2-2,3-Me2-1,4-diaza-1,3-butadiene)Fe(CO)3
• 英文别名: {biacetyl bis(4-methoxyanil)}Fe(CO)3
• CAS: 65016-01-5
• 化学式: C₂₁H₂₀FeN₂O₅
• 分子量: 436.247
• InChiKey: HUASFKRDMPTLOX-DRLFUFNGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (N,N'-(p-CH3OC6H4)2-2,3-Me2-1,4-diaza-1,3-butadiene)Fe(CO)3 、 丁炔二酸二甲酯 以 四氢呋喃 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Frühauf, Hans-Werner; Seils, Frank; Stam, Casper H., Organometallics, 1989, vol. 8, # 10, p. 2338 - 2343

  摘要：

  DOI：
• 作为产物：
  描述：

  (η2-diethyl muconate){biacetyl bis(4-methoxyanil)}dicarbonyliron 以 苯 为溶剂， 生成 、 (N,N'-(p-CH3OC6H4)2-2,3-Me2-1,4-diaza-1,3-butadiene)Fe(CO)3
  参考文献：
  名称：

  Frühauf, Hans-Werner; Pein, Ingrid; Seils, Frank, Organometallics, 1987, vol. 6, # 8, p. 1613 - 1620

  摘要：

  DOI：

文献信息

• Comparing structures and reactivity in analogous Fe and Ru complexes. (iPr-DAB)Fe(CO)2I2 and (iPr-DAB)FeI2: a perfectly reversible CO-carrier system. (R-DAB=N,N′-R2-1,4-diaza-1,3-butadiene)
  作者：Joachim Breuer、Hans-Werner Frühauf、Wilberth J.J Smeets、Anthony L Spek

  DOI：10.1016/s0020-1693(99)00162-0

  日期：1999.8

  Fe(Pr-i-DAB)(CO)(3) (1a) oxidatively adds I-2 to give (Pr-i-DAB)Fe(CO)(2)-trans-I-2 (Za). Photochemically or thermally, 2a readily dissociates both carbonyl ligands to give tetrahedral Fe(Pr-i-DAB)I-2 (3a). Under an atmosphere of CO, complex 2a is quantitatively regenerated from 3a. The X-ray crystal structures of 2a and 3a have been determined. 2a: triclinic, space group P (1) over bar, a = 8.7624(3). b = 9.0550(4), c = 10.6512(6) Angstrom, alpha = 95,429(4) beta = 105.245(4), gamma = 95.209(3)degrees Z = 2, R = 0.0251. 3a: orthorhombic, space group Aba2, a = 11.2693(10), b = 15.933(2), c = 7.5958(10) A, Z = 4, R = 0.036. Contrasting the behaviour of 2a, the analogous ruthenium complexes (R-DAB)Ru(CO)(2)trans-I-2 (4) are very stable, and the carbonyl ligands cannot be dissociated thermally. In the dichloro complexes. of which both the kinetic trans- (5) and the thermodynamic cis-compounds (6) have been isolated, both isomers undergo a photochemical CO mono-substitution to give for example the isolable trans-dichloro methanol complex (7). (C) 1999 Elsevier Science S.A. All rights reserved.
• Shi, Qi-Zhen; Richmond, Thomas G.; Trogler, William C., Organometallics, 1982, vol. 1, p. 1033 - 1037
  作者：Shi, Qi-Zhen、Richmond, Thomas G.、Trogler, William C.、Basolo, Fred

  DOI：——

  日期：——
• Frühauf, Hans-Werner; Seils, Frank; Stam, Casper H., Organometallics, 1989, vol. 8, # 10, p. 2338 - 2343
  作者：Frühauf, Hans-Werner、Seils, Frank、Stam, Casper H.

  DOI：——

  日期：——
• Frühauf, Hans-Werner; Pein, Ingrid; Seils, Frank, Organometallics, 1987, vol. 6, # 8, p. 1613 - 1620
  作者：Frühauf, Hans-Werner、Pein, Ingrid、Seils, Frank

  DOI：——

  日期：——