diphenylphosphine sulphide | 55905-05-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenylphosphine sulphide
• 英文别名: diphenylphosphine sulfide；Ph2PSH；diphenylphosphane sulfide；diphenyl-phosphinothious acid；diphenylthiophosphinous acid；Diphenyl-phosphinsulfid；diphenylphosphinothious acid
• CAS: 55905-05-0
• 化学式: C₁₂H₁₁PS
• 分子量: 218.259
• InChiKey: UWIXFSXAFXDQNW-UHFFFAOYSA-N

物化性质

• 沸点：
  317.2±25.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bis(N,N-diethyldithiocarbamate)platinum(II) 、 diphenylphosphine sulphide 以 乙醇 为溶剂， 以10%的产率得到bis[(N,N-diethyldithiocarbamato)(μ-diphenylthiophosphinito)platinum(II)]
  参考文献：
  名称：

  Anderson, David M.; Ebsworth, E. A. V.; Stephenson, T. Anthony, Journal of the Chemical Society, Dalton Transactions, 1982, p. 2343 - 2352

  摘要：

  DOI：
• 作为产物：
  描述：

  二苯基膦 在 sulfur 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 生成 diphenylphosphine sulphide
  参考文献：
  名称：

  Syntheses, crystal structures, and electrochemical studies of Fe₂(CO)₆(μ-PPh₂)(μ-L) (L = OH, OPPh₂, PPh₂)

  摘要：

  DOI：

  10.1080/00958972.2014.940925

文献信息

• Room-temperature nickel-catalysed cross-couplings of aryl chlorides with arylzincs
  作者：Ning Liu、Li Wang、Zhong-Xia Wang

  DOI：10.1039/c0cc03064c

  日期：——

  P,N,O-chelate nickel complexes efficiently catalyse the cross-coupling reaction of aryl chlorides with arylzinc reagents in a 1:1 THF-NMP mixture. The reactions proceed at room temperature with low catalyst loading.

  P，N，O-螯合物镍络合物可有效催化芳基氯化物与芳基锌试剂在1：1 THF-NMP混合物中的交叉偶联反应。反应在室温下以低催化剂负载进行。
• Phosphorus substituted 4-methyloxetan-2-ones, processes for their
  申请人：Ciba-Geigy Corporation

  公开号：US04384966A1

  公开（公告）日：1983-05-24

  Compounds having the formula ##STR1## are described, wherein X is oxygen or sulphur or the moiety X is absent and A and D are as defined in claim 1. Compounds I may be prepared by reacting a compound ##STR2## with diketene in the presence of an agent capable of forming free radicals. They are useful as friction modifiers and/or antiwear additives in lubricating oils or for imparting flame-retardancy to natural or synthetic polymers.

  描述了具有公式##STR1##的化合物，其中X是氧或硫，或者X基团不存在，A和D如权利要求1所定义。化合物I可通过将化合物##STR2##与二酮乙烯在能够形成自由基的试剂存在下反应制备而得。它们可用作润滑油中的摩擦剂和/或抗磨添加剂，或者用于赋予天然或合成聚合物阻燃性。
• Synthesis, characterization and electrocatalytic H2 production of base-containing Fe/S and Fe/Se clusters
  作者：Jin-Ping Li、Yao-Cheng Shi

  DOI：10.1016/j.ica.2018.05.018

  日期：2018.10

  (Ph2PCH2)2NCH3) with [Fe3(CO)12] in THF at room temperature forms [Fe2(CO)6(µ-PPh2)}2(µ4-S2)] (1) and [Fe3(CO)8(µ3-S)2kP-PPh2CH2N(CH3)CH2P( S)Ph2}] (2) resulting from P S bond cleavage and P Fe bond formation. Similarly, NPSe2 reacts with Fe3(CO)12 to provide [Fe2(CO)6(µ-PPh2)}2(µ4-Se2)] (3) and [Fe3(CO)7(µ3-Se)2k2P,P-(PPh2CH2)2NCH3}] (4). All the compounds have been completely characterized by

  摘要室温下，含碱的二膦配体NPS2（NP2（Ph2PCH2）2NCH3）与[Fe3（CO）12]在THF中的反应为[Fe2（CO）6（µ-PPh2）} 2（µ4-S2）]。 （1）和[Fe3（CO）8（μ3-S）2 kP-PPh2CH2N（CH3）CH2P（S）Ph2}]（2）是由于PS键断裂和P Fe键形成所致。类似地，NPSe2与Fe3（CO）12反应以提供[Fe2（CO）6（µ-PPh2）} 2（µ4-Se2）]（3）和[Fe3（CO）7（µ3-Se）2 k2P ，P-（PPh2CH2）2NCH3}]（4）。所有化合物均已通过元素分析，IR，1H NMR，13C NMR和31P NMR光谱进行了完全表征，并通过X射线晶体学进行了结构测定。电化学研究表明，当使用HOAc或TFA作为质子源时，2和4显示出催化的H2产生。
• Thermoplastic polyamideimide copolymers and method of preparation
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0017422A1

  公开（公告）日：1980-10-15

  Thermoplastic polyamideimide copolymers are provided which are excellent in both heat stability and melt viscosity characteristics at a temperature of from about 300°C to about 400°C. The copolymers of the invention comprise Units A of the formula in an amount of about 50 mole %, Units B of the formula in an amount of about 15-48 mole % and Units C of the formula in an amount of about 35-2 mole %, wherein Z is a trivalent aromatic group having two of its three carbonyl groups attached to adjacent carbon atoms, a is 0 or 1, b is 0,1,2,3 or 4, R1 is alkyl (C1-4), R2 is selected from alkyl (C1-4), halo and nitro, c is an integer from 1 to 25 and X is chosen from - SO2 -CO- or -C(CH3)2-. The copolymers may be made by reacting diamines containing the Units B and C respectively, e.g. I and II, with trimellitic acid (or another aromatic tribasic carboxylic acid with two carboxyl groups attached to adjacent carbon atoms) in an organic polar solvent using a dehydrating catalyst - or alternatively the diamines may be reacted with the acid anhydride acid chloride using a hydrochloride scavenger, subsequently closing the ring of the polyamide-amic acid thus formed.

  本发明提供的热塑性聚酰胺酰亚胺共聚物在约 300°C 至约 400°C 的温度条件下，热稳定性和熔融粘度特性都非常出色。 本发明的共聚物包含式中的单元 A，其含量约为 50 摩尔%；式中的单元 B，其含量约为 50 摩尔%。 约 50 摩尔%，式中单元 B 含量约为 15-48 摩尔%，以及式中的单元 C 其中 Z 是三价芳香基团，其三个羰基中的两个与相邻碳原子相连；a 是 0 或 1；b 是 0、1、2、3 或 4；R1 是烷基（C1-4）；R2 选自烷基（C1-4）、卤代和硝基；c 是 1 至 25 的整数；X 选自-SO2-CO-或-C(CH3)2-。共聚物的制造方法是：使用脱水催化剂，在有机极性溶剂中，将分别含有单元 B 和单元 C 的二胺（如 I 和 II）与偏苯三酸（或另一种在相邻碳原子上连接有两个羧基的芳香族三元羧酸）反应，或者使用盐酸盐清除剂，将二胺与酸酐酰氯反应，然后封闭由此形成的聚酰胺-氨基甲酸酯环。
• Catalysis with Phosphine-Containing Amino Acids in Various “Turn” Motifs
  作者：Anton Agarkov、Scott J. Greenfield、Takahiro Ohishi、Scott E. Collibee、Scott R. Gilbertson

  DOI：10.1021/jo049103g

  日期：2004.11.1

  We have been actively involved in the development of parallel approaches for the discovery of phosphine ligands. Our approach has been based on the incorporation of phosphine-containing amino acids into peptide sequences that are designed to have stable secondary structures. We have examined helical and turn secondary structures and have reported that alkylation of cyclopentenyl acetate with dimethylmalonate can be catalyzed in high enantiomeric excess (ee) with a beta-turn-based ligand. The importance of the peptide secondary structure was demonstrated through the synthesis of a series of peptide ligands where the nature of the turn-forming residues was probed. Additionally, other turn-forming units and a variety of different phosphine-containing amino acids have been examined for their ability to control the selectivity of the allylation reaction. This paper reports the results obtained through the examination of different turn motifs as well as different phosphine substitutions on the "best" turn sequence, Pps-Pro-D-Xxx-Pps.