N,N',N''-(1,3,5-Triazine-2,4,6-triyl)tris(2-chloroacetamide) | 30360-27-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N',N''-(1,3,5-Triazine-2,4,6-triyl)tris(2-chloroacetamide)
• 英文别名: N-[4,6-bis[(2-chloroacetyl)amino]-1,3,5-triazin-2-yl]-2-chloroacetamide
• CAS: 30360-27-1
• 化学式: C₉H₉Cl₃N₆O₃
• 分子量: 355.568
• InChiKey: YJJIEWIAKNUQIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  126
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N',N''-(1,3,5-Triazine-2,4,6-triyl)tris(2-chloroacetamide) 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 丙酮 为溶剂， 反应 7.0h， 生成 3,3',3''-(1,3,5-triazine-2,4,6-triyl)tris(2-(heptylimino)thiazolidin-4-one)
  参考文献：
  名称：

  A New Series of Triazine-core Based Mesogenic Derivatives: Synthesis, Characterization and Mesomorphic Study

  摘要：

  The synthesis, characterization and mesomorphic properties of two new series of triazine-core based liquid crystals have been investigated. The amino triazine derivatives were characterized by elemental analysis, Fourier transforms infrared (FTIR), 1HNMR and mass spectroscopy. The liquid crystalline properties of these compounds were examined by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM). DSC and POM confirmed nematic (N) and columnar mesophase textures of the materials. The formation of mesomorphic properties was found to be dependent on the number of methylene unit in alkoxy side chains.

  DOI：

  10.1080/15421406.2019.1624032
• 作为产物：
  描述：

  三聚氰胺 、 氯乙酰氯 在 三乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以85%的产率得到N,N',N''-(1,3,5-Triazine-2,4,6-triyl)tris(2-chloroacetamide)
  参考文献：
  名称：

  A New Series of Triazine-core Based Mesogenic Derivatives: Synthesis, Characterization and Mesomorphic Study

  摘要：

  The synthesis, characterization and mesomorphic properties of two new series of triazine-core based liquid crystals have been investigated. The amino triazine derivatives were characterized by elemental analysis, Fourier transforms infrared (FTIR), 1HNMR and mass spectroscopy. The liquid crystalline properties of these compounds were examined by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM). DSC and POM confirmed nematic (N) and columnar mesophase textures of the materials. The formation of mesomorphic properties was found to be dependent on the number of methylene unit in alkoxy side chains.

  DOI：

  10.1080/15421406.2019.1624032

文献信息

• Process for preparing amide derivatives from halomines and acid halides
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0541966A2

  公开（公告）日：1993-05-19

  This invention provides a process for preparing amide derivatives of acids by the reaction of haloamines and acid halides. Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process. Amides, carbamates, sulfonamides, phosphoramides, and related amide derivatives may be prepared by the novel process of the invention.

  本发明提供了一种通过卤胺和酸卤化物反应制备酸酰胺衍生物的工艺。 三氯和六氯甲胺与氯甲酸酯和酸性氯化物反应制备三聚氰胺衍生酸酰胺。副产品氯可以在此过程中回收利用。 酰胺、氨基甲酸酯、磺酰胺、磷酰胺和相关的酰胺衍生物可通过本发明的新工艺制备。
• Process for preparing amide derivatives from halominotriazines and acid halides
  申请人：CYTEC TECHNOLOGY CORP.

  公开号：EP0565774A2

  公开（公告）日：1993-10-20

  This invention provides a process for preparing amide derivatives of acids by the reaction of haloaminotriazines and acid halides. This invention also provides a process for preparing isocyanates and isocyanate adducts from amide derivatives derived from haloaminotriazines and acid halides such as oxalyl chloride, phosgene and phosgene analogs. Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process. Amides, carbamates, sulfonamides, phosphoramides, and related amide derivatives may be prepared by the novel processes of the invention.

  本发明提供了一种通过卤代氨基三嗪和酸卤化物反应制备酸的酰胺衍生物的工艺。 本发明还提供了一种由卤胺三嗪和草酰氯、光气和光气类似物等酸卤化物衍生的酰胺衍生物制备异氰酸酯和异氰酸酯加合物的工艺。 三氯和六氯甲胺与氯甲酸酯和酸性氯化物反应可制备三聚氰胺衍生酸性酰胺。副产品氯可以在此过程中回收利用。 酰胺、氨基甲酸酯、磺酰胺、磷酰胺和相关的酰胺衍生物可通过本发明的新工艺制备。
• A process for preparing isocyanate compounds from haloaminotriazines and acid halides
  申请人：CYTEC TECHNOLOGY CORP.

  公开号：EP0930303A2

  公开（公告）日：1999-07-21

  This invention provides a process for preparing isocyanates and isocyanate adducts from amide derivatives derived from haloaminotriazines and acid halides such as oxalyl chloride, phosgene and phosgene analogs. Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process.

  本发明提供了一种由卤胺三嗪和酸性卤化物（如草酰氯、光气和光气类似物）衍生的酰胺衍生物制备异氰酸酯和异氰酸酯加合物的工艺。 三氯和六氯甲胺与氯甲酸酯和酸性氯化物反应可制备三聚氰胺衍生酸性酰胺。副产品氯可以在此过程中回收利用。
• Tris-(omega-haloacyl)melamines
  申请人：CYTEC TECHNOLOGY CORP.

  公开号：EP0933369A1

  公开（公告）日：1999-08-04

  A composition of matter represented by the formula: wherein nis an integer from 1 to 5; and Xis a leaving group selected from the group consisting of chloride, bromide, iodide, fluoride, alkysulfonate, arylsulfonate, and mixtures thereof.

  由以下式子表示的物质组合物 其中 n 是 1 至 5 的整数；以及 X 是选自氯化物、溴化物、碘化物、氟化物、烷基磺酸盐、芳基磺酸盐及其混合物的离去基团。
• Tris-(2,2,6,6-tetramethyl-piperid-4-yl-aminocarbonyl)melamine
  申请人：CYTEC TECHNOLOGY CORP.

  公开号：EP0933370A1

  公开（公告）日：1999-08-04

  This invention provides the novel compound tris-(2,2,6,6-tetramethyl-piperid-4-yl-aminocarbonyl) melamine.

  本发明提供了新型化合物三-(2,2,6,6-四甲基-哌啶-4-基-氨基羰基)三聚氰胺。