4-[[4-(苯氨基)苯基]氨基]苯酚 | 101-74-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-[[4-(苯氨基)苯基]氨基]苯酚
• 英文名称: p-(p-anilinoanilino)phenol
• 英文别名: 4-(4-Anilino-anilino)-phenol；N-Phenyl-N'-(4-oxy-phenyl)-p-phenylendiamin；4-Oxy-4'-anilino-diphenylamin；4-(4-anilinoanilino)phenol
• CAS: 101-74-6
• 化学式: C₁₈H₁₆N₂O
• 分子量: 276.338
• InChiKey: JWKZWDVKRDSMLD-UHFFFAOYSA-N

物化性质

• 熔点：
  145 °C
• 沸点：
  484.6±20.0 °C(Predicted)
• 密度：
  1.256±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  44.3
• 氢给体数：
  3
• 氢受体数：
  3

安全信息

• 海关编码：
  2922299090

反应信息

• 作为反应物：
  描述：

  4-[[4-(苯氨基)苯基]氨基]苯酚 在 mercury(II) oxide 、 苯 作用下， 生成 4-[[4-(苯基氨基)苯基]亚氨基]环己-2,5-二烯-1-酮
  参考文献：
  名称：

  Heller, Justus Liebigs Annalen der Chemie, 1919, vol. 418, p. 263

  摘要：

  DOI：
• 作为产物：
  描述：

  对苯二酚 、 对氨基二苯胺 在 zinc(II) chloride 作用下， 生成 4-[[4-(苯氨基)苯基]氨基]苯酚
  参考文献：
  名称：

  Heller, Justus Liebigs Annalen der Chemie, 1919, vol. 418, p. 263

  摘要：

  DOI：

文献信息

• Preparation of Linear Oligoaniline Derivatives Using Titanium Alkoxide as a Condensing Agent
  作者：Miyoko Ochi、Hitoshi Furusho、Jun Tanaka

  DOI：10.1246/bcsj.67.1749

  日期：1994.6

  oligoaniline derivatives were prepared by the reaction of aromatic amines and phenols using various titanium alkoxides as condensing agents. The oligomers obtained were silver white microscopic crystals. Titanium alkoxides used were titanium alkoxide or titanium alkoxide aryloxide and the latter showed high dehydration condensation activity in comparison with the usual titanium alkoxides.

  使用各种钛醇盐作为缩合剂，通过芳香胺和苯酚反应制备线性低聚苯胺衍生物。所得低聚物为银白色显微晶体。所使用的钛醇盐是钛醇盐或钛醇盐芳氧基，后者与通常的钛醇盐相比显示出高脱水缩合活性。
• DIBLOCK COPOLYMER MODIFIED NANOPARTICLE/POLYMER COMPOSITES
  申请人：SCHADLER Linda S.

  公开号：US20100261808A1

  公开（公告）日：2010-10-14

  The invention relates to a modified nanoparticle including a nanoparticle and a diblock copolymer covalently attached to the nanoparticle, the diblock copolymer comprising a first block polymer of molecular weight greater than 1000 attached to the nanoparticle and a second block polymer of molecular weight greater than 1000 covalently linked to the first block polymer, wherein at least one of the first block polymer and second block polymer comprises repeating units having an azide, acetylene or triazole side chain. Nanocomposites incorporating modified nanoparticles, as well as methods of making modified nanoparticles and nanocomposites are also disclosed.

  本发明涉及一种改性纳米颗粒，包括纳米颗粒和共价连接到纳米颗粒上的二嵌段共聚物，该二嵌段共聚物包括分子量大于1000的第一块聚合物连接到纳米颗粒上和与第一块聚合物共价连接的分子量大于1000的第二块聚合物，其中第一块聚合物和/或第二块聚合物中至少有一种包含具有偶氮基，乙炔或三唑侧链的重复单元。还公开了包含改性纳米颗粒的纳米复合材料以及制备改性纳米颗粒和纳米复合材料的方法。
• DIBLOCK COOPOLYMER MODIFIED NANOPARTICLE/POLYMER COMPOSITES
  申请人：Rensselaer Polytechnic Institute

  公开号：US20140128502A1

  公开（公告）日：2014-05-08

  The invention relates to a modified nanoparticle including a nanoparticle and a diblock copolymer covalently attached to the nanoparticle, the diblock copolymer comprising a first block polymer of molecular weight greater than 1000 attached to the nanoparticle and a second block polymer of molecular weight greater than 1000 covalently linked to the first block polymer, wherein at least one of the first block polymer and second block polymer comprises repeating units having an azide, acetylene or triazole side chain. Nanocomposites incorporating modified nanoparticles, as well as methods of making modified nanoparticles and nanocomposites are also disclosed.

  本发明涉及一种改性纳米颗粒，包括纳米颗粒和与纳米颗粒共价连接的二嵌段共聚物，所述二嵌段共聚物包括分子量大于1000的第一块聚合物连接到纳米颗粒和分子量大于1000的第二块聚合物与第一块聚合物共价连接，其中第一块聚合物和/或第二块聚合物中至少有一种包含具有偶氮基、乙炔基或三唑基侧链的重复单元。还公开了包含改性纳米颗粒的纳米复合材料，以及制备改性纳米颗粒和纳米复合材料的方法。
• Co-polymer-bound amine antioxidants
  申请人：HERCULES INCORPORATED

  公开号：EP0331074A2

  公开（公告）日：1989-09-06

  An improved amine-containing antioxidant compound for stabilizing the polymeric products of ring-opening metathesis-catalyst-polymerization of the norbornene-type monomer reactions described above, and that effectively delays degradation by olefin oxidation of physical properties as well as avoiding discoloration of such polymeric products and discoloration of surface coatings applied for aesthetic purposes, and its use as a comonomer in a ring-opening metathesis-catalyst-polymerization of a norbornene-type monomer that undergoes ring-opening polymerization in the presence of a metathesis catalyst are disclosed.

  一种改进的含胺抗氧化剂化合物，用于稳定上述降冰片烯类单体反应的开环偏聚催化剂聚合反应的聚合物产物，并能有效延缓物理性能因烯烃氧化而降解，以及避免此类聚合物产物变色和为美观目的而使用的表面涂层变色、本发明还公开了其在降冰片烯类单体的开环偏合成催化剂聚合反应中作为共聚单体的用途，该单体在偏合成催化剂存在下进行开环聚合反应。
• OLIGOANILINE COMPOUNDS
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP2062870B1

  公开（公告）日：2016-11-09