环己基三甲基氢氧化铵 | 19895-48-8

• 物质功能分类: 化学试剂 - 有机试剂 - 胺盐（铵盐）
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 环己基三甲基氢氧化铵
• 英文名称: [cyclo-C6H11NMe3][OH]
• 英文别名: cyclohexyl-trimethyl-ammonium; hydroxide；Cyclohexyl-trimethyl-ammonium; Hydroxid；trimethylcyclohexylammonium hydroxide；Trimethyl-cyclohexyl-ammonium-hydroxid；N,N,N-trimethylcyclohexanaminium hydroxide；cyclohexyl(trimethyl)azanium;hydroxide
• CAS: 19895-48-8
• 化学式: C₉H₂₀N*HO
• 分子量: 159.272
• InChiKey: GWEYVXCWRZZNTB-UHFFFAOYSA-M

物化性质

• 密度：
  1.052g/cm3 at 20℃
• LogP：
  -2.19 at 23℃ and pH11.6

计算性质

• 辛醇/水分配系数(LogP)：
  1.85
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  环己基三甲基氢氧化铵 在 硼酸 作用下， 以 甲醇 、 水 为溶剂， 反应 1.0h， 生成 [cyclohexyltrimethylammonium][B5O6(OH)4]
  参考文献：
  名称：

  Templated heptaborate and pentaborate salts of cyclo-alkylammonium cations: structural and thermal properties

  摘要：

  报告了一系列环烷基五硼酸铵盐{[cyclo-CnH2n-1NR3][B5O6(OH)4]（R = H，n = 3，5-7 (1-4)；R = Me，n = 6 (5)）}的合成和表征。化合物 1、2 和 5 已通过单晶 XRD 研究得到进一步表征。在尝试重结晶 3 和 4 的过程中，发现了少量意想不到的庚硼酸盐，即 [cyclo-C6H11NH3]2[B7O9(OH)5]-3H2O-B(OH)3 (6) 和 [cyclo-C7H13NH3]2[B7O9(OH)5]-2H2O-2B(OH)3 (7)，并对其进行了晶体学表征。所有化合物都显示出由阳离子模板化的广泛的超分子 H 键阴离子晶格。对 H 键相互作用进行了详细描述。对五硼酸盐 1-5 的 TGA-DSC 分析表明，它们在 800 °C 的空气中热分解为 2.5B2O3 ，分解过程分为脱水（<250 °C）和氧化分解（250-600 °C）两步。五硼酸盐衍生材料的 BET 分析显示，其内部孔隙率小于 1 m2 g-1。

  DOI：

  10.1039/c2dt12310j
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 水 、 silver(l) oxide 作用下， 生成 环己基三甲基氢氧化铵
  参考文献：
  名称：

  Skita; Rolfes, Chemische Berichte, 1920, vol. 53, p. 1255

  摘要：

  DOI：
• 作为试剂：
  描述：

  茚满 、 叔丁醇 在 sodium hydroxide 、 环己基三甲基氢氧化铵 作用下， 生成 tert-butyl-indan-1-yl ether
  参考文献：
  名称：

  Anodic Oxidation of Aryl Activated Methylene Groups¹

  摘要：

  DOI：

  10.1021/jo01356a017

文献信息

• PRODUCTION PROCESS FOR FLUOROSULFONYLIMIDE AMMONIUM SALT
  申请人：Tsubokura Shiro

  公开号：US20130331609A1

  公开（公告）日：2013-12-12

  A compound [II] such as ammonium N,N-di(fluorosulfonyl)imide is obtained by reacting a compound [I] such as N,N-di(chlorosulfonyl)imide and NH 4 F (HF) p . A compound [IV] such as an N,N-di(fluorosulfonyl)imide alkali metal salt is obtained by reacting the obtained compound [II] and an alkali metal compound or the like.

  通过将化合物[I]，如N,N-二(氯磺酰)亚胺和NH4F (HF)p反应，可以得到类似氨基N,N-二(氟磺酰)亚胺的化合物[II]。通过将得到的化合物[II]与碱金属化合物等反应，可以得到类似N,N-二(氟磺酰)亚胺碱金属盐的化合物[IV]。
• Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins
  申请人：Cao Guang

  公开号：US20070043249A1

  公开（公告）日：2007-02-22

  The synthesis of a crystalline aluminophosphate or silicoaluminophosphate molecular sieve having a chabazite-type framework type is conducted in the presence of an organic directing agent having the formula (I) [R 1 R 2 R 3 N—R 4 ] + X − (I) wherein R 1 , R 2 and R 3 are independently selected from the group consisting of alkyl groups having from 1 to 3 carbon atoms and hydroxyalkyl groups having from 1 to 3 carbon atoms; R 4 is selected from the group consisting of 4- to 8-membered cycloalkyl groups, optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms; 4- to 8-membered heterocyclic groups having from 1 to 3 heteroatoms, said heterocyclic groups being optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms and the heteroatoms in said heterocyclic groups being selected from the group consisting of O, N, and S; and aromatic groups optionally substituted by 1 to 3 alkyl groups, said alkyl groups having from 1 to 3 carbon atoms; and X − is an anion.

  在有机引导剂的存在下，以具有方解石型骨架类型的结晶铝磷酸盐或硅铝磷酸盐分子筛的合成在以下化学式（I）[R1R2R3N—R4]+X−(I)中进行，其中R1、R2和R3分别选自由1至3个碳原子的烷基基团和1至3个碳原子的羟基烷基基团组成的群；R4选自由1至3个碳原子的烷基基团和1至3个碳原子的羟基烷基基团组成的群；R4选自由4至8个成员的环烷基基团，可选地由1至3个碳原子的烷基基团取代；由1至3个杂原子组成的4至8个成员的杂环基团，该杂环基团可选地由1至3个碳原子的烷基基团取代，且该杂环基团中的杂原子选自由O、N和S组成的群；和可选地由1至3个碳原子的烷基基团取代的芳香基团；X−是阴离子。
• Thermosetting coating composition and pigmented film formation
  申请人：KANSAI PAINT CO. LTD.

  公开号：EP0435356A1

  公开（公告）日：1991-07-03

  A thermosetting coating composition comprising as essential components: (a) a hydroxyl group-containing base resin, (b) an alicyclic polyepoxide crosslinking agent, and (c) a catalyst selected from the group consisting of a quaternary ammonium hydroxide and a metal chelate.

  一种热固性涂料组合物，其基本成分包括： (a) 含羟基的基础树脂、 (b) 脂环族聚环氧化物交联剂，和 (c) 选自季铵氢氧化物和金属螯合物的催化剂。
• Process for the production of aromatic polycarbonate
  申请人：TEIJIN LIMITED

  公开号：EP0667366A2

  公开（公告）日：1995-08-16

  A process for the production of an aromatic polycarbonate, which comprises polycondensing an aromatic dihydroxy compound and a diaryl carbonate in the presence, as a polycondensation catalyst, of at least one alkali metal salt selected from the group consisting of alkali metal salts of ate-complexes of a metal element, which is silicon, germanium, stannum or plumbum, and alkali metal salts of oxoacids of said metal elements. The above aromatic polycarbonate is almost free from being colored, is also almost free from a decrease in polymerization degree when molded, and is further almost free from forming branches and insolubles.

  一种芳香族聚碳酸酯的生产工艺，包括在至少一种碱金属盐作为缩聚催化剂的存在下，将芳香族二羟基化合物和碳酸二芳基酯进行缩聚，该碱金属盐选自金属元素（硅、锗、锡或铂）的吃络合物的碱金属盐和上述金属元素的氧化物的碱金属盐组成的组。上述芳香族聚碳酸酯几乎不着色，成型时聚合度也几乎不会降低，而且几乎不会形成分支和不溶物。
• Positive chemically amplified resist composition and method for producing compounds used therein
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0709736A1

  公开（公告）日：1996-05-01

  A positive chemically amplified resist composition is disclosed, comprising (a) a compound which generates an acid upon irradiation with active light or radiant ray; (b) a resin insoluble in water but soluble in an aqueous alkali solution; and (c) a low molecular acid-decomposable dissolution inhibitor having a molecular weight of 3,000 or less and containing an acid-decomposable alkyl ester group represented by formula (I), and which increases its solubility in an alkali developer by the action of an acid, and having a sodium content and a potassium content each of 30 ppb or less. Also disclosed is a positive chemically amplified resist composition comprising the foregoing compound (a) and (d) a resin having an acid-decomposable alkyl ester group represented by formula (I), and which increases its solubility in an alkali developer by the action of an acid, and having a sodium content and a potassium content each of 30 ppb or less. Still further disclosed are methods for producing the compounds (c) and (d).

  本发明公开了一种正化学放大抗蚀剂组合物，其中包括：(a) 一种在活性光或辐射线照射下产生酸的化合物；(b) 一种不溶于水但可溶于碱水溶液的树脂；(c) 低分子可酸分解溶解抑制剂，其分子量在 3,000 或以下，并含有由式(I)代表的可酸分解烷基酯基团，在酸的作用下可增加其在碱显影剂中的溶解度，其钠含量和钾含量均在 30 ppb 或以下。还公开了一种正化学放大抗蚀剂组合物，该组合物包含前述化合物（a）和（d），该树脂具有由式（I）表示的可酸化分解的烷基酯基团，在酸的作用下可增加其在碱显影剂中的溶解度，且钠含量和钾含量均不超过 30 ppb。还进一步公开了生产化合物（c）和（d）的方法。