4-bromo-4'-(phenyl-m-tolylamino)benmzene | 207345-05-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-bromo-4'-(phenyl-m-tolylamino)benmzene
• 英文别名: N-(4-bromophenyl)m-tolyl-phenylamine；N-(4-bromophenyl)phenyl-m-tolylamine；4-(3-methyldiphenylamine)bromobenzene；N-(4-Bromophenyl)-3-methyl-N-phenylaniline
• CAS: 207345-05-9
• 化学式: C₁₉H₁₆BrN
• 分子量: 338.247
• InChiKey: JQTJMVUCCJECSH-UHFFFAOYSA-N

物化性质

• 沸点：
  445.3±38.0 °C(Predicted)
• 密度：
  1.336±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-bromo-4'-(phenyl-m-tolylamino)benmzene 在 正丁基锂 、 硼酸三甲酯 、 盐酸 、 水 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 14.0h， 生成 4-(3-methyldiphenylamino)phenylboronic acid
  参考文献：
  名称：

  JP2005/162660

  摘要：

  公开号：
• 作为产物：
  描述：

  1,4-二溴苯 、 3-甲基二苯胺 在 1,1'-双(二苯基膦)二茂铁 、 tris(dibenzylideneacetone)dipalladium (0) 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以82%的产率得到4-bromo-4'-(phenyl-m-tolylamino)benmzene
  参考文献：
  名称：

  Designing Interfaces That Function to Facilitate Charge Injection in Organic Light-Emitting Diodes

  摘要：

  Layer-by-layer (LbL) assembly of triarylamine (TAA)-containing polymers has been applied for anode functionalizations in organic light-emitting diodes (OLEDs). Surface work function of the ITO electrodes was significantly altered with the functionalizations, and the values changed depending on electron affinity of the substituents (X) on the TAA units. When the functionalized ITO electrodes were utilized for the conventional TPD/Alq OLED, the multilayers of P1 (X = 4-OMe) and P2 (X = none) were found to promote better energy matching at the ITO/TPD interface to reduce the hole injection barrier. Furthermore, the multilayers having heterodeposited structure of several TAA polymers provided stepped and graded electronic profiles to facilitate hole mobility from ITO to TPD, so that the resulting OLED devices can exhibit appreciably reduced turn-on voltage and higher luminous intensities.

  DOI：

  10.1021/ja052170n

文献信息

• Materials for injecting or transporting holes and organic electroluminescence devices using the same
  申请人：Kim Eun Ji

  公开号：US20050225235A1

  公开（公告）日：2005-10-13

  The present invention relates to a novel compound that can significantly improve the lifespan, efficiency and thermal stability of an organic light emitting device, and to an organic electroluminescence device or light emitting device comprising the compound in an organic compound layer is also disclosed.

  本发明涉及一种新型化合物，可以显著改善有机发光器件的寿命、效率和热稳定性，并且还披露了包含该化合物的有机化合物层的有机电致发光器件或发光器件。
• Metallocene-catalyzed synthesis of polyethylenes with side-chain triarylamines: Effects of catalyst structure and triarylamine functionality
  作者：Myung Hwan Park、Jun Ha Park、Youngkyu Do、Min Hyung Lee

  DOI：10.1016/j.polymer.2010.08.033

  日期：2010.10

  Copolymerization results of ethylene with M1–M3 using C4/MAO indicate that M1–M3 are well tolerated by both the cationic active species of C4 and MAO cocatalyst, giving rise to the copolymers with high levels of activity and molecular weight. Inspection of the aliphatic region of the 13C NMR spectra of the copolymers (P1–P3) having ca. 11 mol% of M1–M3, respectively, reveals the presence of isolated comonomer units

  乙烯与8-三芳基胺（TAA）的共聚取代的1-辛烯的单体（TAA =三苯胺（M1），Ñ，Ñ二苯基米-tolylamine（M2），Ñ，ñ -二苯基-1-萘基胺（M3））使用各种类型的第4组单点催化系统（Cp 2 ZrCl 2（C1），rac -EBIZrCl 2（C2），rac -SBIZrCl 2（C3），i -PrCpFluZrCl 2（C4），Me2的Si（η 5 -C 5我4）（η 1 -N-吨卜）的TiCl 2（C5））进行了研究，以制备具有侧链TAA基团官能化的聚乙烯。茂金属/甲基铝氧烷（MAO）催化体系（C1 - C4）有效地导致了高分子量聚（乙烯-co - M1）的生产。虽然C4 / MAO催化体系显示出最高的共聚单体响应，但C5 / MAO体系显示出与M1共聚单体的不良相容性。乙烯与M1的共聚结果- M3使用C4 / MAO表明M1 - M3深受两者的阳离子活性种耐受C4和
• Hole-transporting polymers
  申请人：——

  公开号：US20010017155A1

  公开（公告）日：2001-08-30

  Polymers comprising triarylamine substituent monomers. The polymers are products of anionic or radical polymerization of monovinylated triarylamine monomers or of ROMP polymerization of monomers comprising a triarylamine component, a linker component, and a cyclic olefin that is capable of undergoing a ring-opening polymerization reaction. The resulting polymers possess hole-transporting properties and are useful as hole transport layers in light-emitting diodes or as components of photorefractive materials.

  包含三芳胺取代单体的聚合物。这些聚合物是单乙烯化三芳胺单体的阴离子或自由基聚合或由包含三芳胺组分、连接组分和能够进行环开启聚合反应的环烯烃的ROMP聚合单体聚合而成。所得到的聚合物具有传输空穴的性质，可用作发光二极管中的空穴传输层或作为光折变材料的组分。
• Diarylamino group-containing copolymer, organic electroluminescent device, and method of producing hole transport layer for organic electroluminescent device
  申请人：Kato Shinji

  公开号：US20050008893A1

  公开（公告）日：2005-01-13

  An organic electroluminescent device is provided which has a high degree of adhesion between an anode and a hole transport layer, the device emitting light of high luminance even when driven by low applied voltages. Copolymers useful in hole transport layers in organic electroluminescent devices are also provided. Methods of producing hole transport layers for organic electroluminescent devices which can emit light of high luminance even when driven by low applied voltages are also provided, the hole transport layers having high degrees of adhesion with anode. A copolymer comprises a monomer unit including in its structure an electron-donating N,N-diaryl-substituted amino group such as an N,N-diphenylaminophenyl group, or a group having an N,N-diaryl-substituted amino moiety, and a monomer unit having at least one functional group. Also, a hole transport layer, which has excellent thickness accuracy, has an extremely smooth surface, and is very thin, can be formed of this copolymer or a copolymer having the same hole transport functional group. An organic electroluminescent device, which emits light of high luminance even when driven by low applied voltages, can be obtained by using this hole transport layer.

  提供了一种有机电致发光器件，其阳极和空穴传输层之间具有高度的粘附性，即使在低电压驱动下也能发出高亮度的光。还提供了在有机电致发光器件中用于空穴传输层的共聚物。还提供了制备空穴传输层的方法，该方法可以在低电压驱动下发出高亮度的光，空穴传输层与阳极具有高度的粘附性。共聚物包括一个单体单元，其结构中包括一个电子给体的N，N-二芳基取代氨基，例如N，N-二苯基氨基苯基基团，或具有N，N-二芳基取代氨基基团的基团，以及至少具有一个功能基团的单体单元。此共聚物或具有相同空穴传输功能基团的共聚物可以形成具有优异厚度精度、极其光滑表面且非常薄的空穴传输层。通过使用此空穴传输层，可以获得发出高亮度光的有机电致发光器件，即使在低电压驱动下也能发光。
• Green Light-Emitting Diodes (LED) Based on Diarylethene
  作者：Youngjin Kang、Taegweon Lee、Il Jung、Jaejung Ko、Soon-Ki Kwon、Ki-Min Park、Seokjong Lee

  DOI：10.1080/15421400500365334

  日期：2006.2.1

  A novel class of diarylethene derivatives, (diaryl = N-7-azaindolylpheny, naphthylphenylamine, m-tolylphenylamine, ethene = perfluorocyclopentene) were synthesized and experiments were performed their usage in organic light-emitting diodes (OLEDs). Compound 3 , 1,2-Bis4-[(phenyl)(m-tolyl)amino]biphenyl}-3,3,4,4,5,5-hexafluorocyclopentene, exhibits a strong green emission in both a solution and a thin film at similar to 540 nm. The device with 3 as an emitting material (structure: ITO/TPD/3/Alq 3 (q = tris-(8-hydroxyquinolinolate))/Al:Li) shows high quantum efficiency with 7677 cd/m(2) at similar to 13 V.