[(2,4,6-tri-tert-butylphenyl)PGe(SiMe(t-Bu)2)2] | 1175216-73-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(2,4,6-tri-tert-butylphenyl)PGe(SiMe(t-Bu)2)2]
• CAS: 1175216-73-5
• 化学式: C₃₆H₇₁GePSi₂
• 分子量: 663.694
• InChiKey: KWYPSQGVAYZIMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.66
• 重原子数：
  40.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  potassium graphite 、 [(2,4,6-tri-tert-butylphenyl)PGe(SiMe(t-Bu)2)2] 以 四氢呋喃 为溶剂， 生成 [(2,4,6-tri-tert-butylphenyl)PGe(SiMe(t-Bu)2)2]K
  参考文献：
  名称：

  A “Push−Pull” Phosphasilene and Phosphagermene and Their Anion-Radicals

  摘要：

  Phosphasilene 1a and phosphagermene 1b, featuring unprecendented substitution patterns (donors on Si or Ge and acceptor on P), were synthesized utilizing a one-step synthetic approach; direct coupling of dilithiosilane/dilithiogermane and dichlorophosphine. The structural features of both 1a and 1b based on their NMR and X-ray crystal data are discussed, as well as their one-electron reduction forming persistent phosphasilene and phosphagermene anion-radicals.

  DOI：

  10.1021/om900310u
• 作为产物：
  描述：

  bis[di-tert-butyl(methyl)silyl]-1,1-dilithiogermane 、 2,4,6-tri-t-butylphenylphosphonous dichloride 以 四氢呋喃 为溶剂， 以40%的产率得到[(2,4,6-tri-tert-butylphenyl)PGe(SiMe(t-Bu)2)2]
  参考文献：
  名称：

  A “Push−Pull” Phosphasilene and Phosphagermene and Their Anion-Radicals

  摘要：

  Phosphasilene 1a and phosphagermene 1b, featuring unprecendented substitution patterns (donors on Si or Ge and acceptor on P), were synthesized utilizing a one-step synthetic approach; direct coupling of dilithiosilane/dilithiogermane and dichlorophosphine. The structural features of both 1a and 1b based on their NMR and X-ray crystal data are discussed, as well as their one-electron reduction forming persistent phosphasilene and phosphagermene anion-radicals.

  DOI：

  10.1021/om900310u