butyl [(tosyloxy)methyl]phenyl phosphinate | 1382936-98-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: butyl [(tosyloxy)methyl]phenyl phosphinate
• 英文别名: [Butoxy(phenyl)phosphoryl]methyl 4-methylbenzenesulfonate
• CAS: 1382936-98-2
• 化学式: C₁₈H₂₃O₅PS
• 分子量: 382.417
• InChiKey: FGKGABWAZMCJDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  25
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  78
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  butyl [(tosyloxy)methyl]phenyl phosphinate 在 异丙基氯化镁 、 sodium iodide 作用下， 以 四氢呋喃 、 丙酮 为溶剂， 反应 26.5h， 生成 butyl (3-butenyl)phenyl phosphinate
  参考文献：
  名称：

  Chemistry of the Versatile (Hydroxymethyl)phosphinyl P(O)CH₂OH Functional Group

  摘要：

  (Hydroxymethyl)phosphorus compounds are well-known and valuable compounds in general; however the use of (hydroxymethyl)phosphinates (RP)-P-1(O)(OR2)CH2OH in particular has been much more limited. The potential of this functionality has not yet been fully realized because the mild unmasking of the hydroxymethyl group was not available. The mild oxidative conversion of (RP)-P-1(O)(OR2)CH2OH into (RP)-P-1(O)(OR2)H using the Corey-Kim oxidation is described. Other reactions preserving the methylene carbon are also reported.

  DOI：

  10.1021/ol3013793
• 作为产物：
  描述：

  butyl phenylphosphinate 在 吡啶 、 N,N-二异丙基乙胺 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 45.0h， 生成 butyl [(tosyloxy)methyl]phenyl phosphinate
  参考文献：
  名称：

  Chemistry of the Versatile (Hydroxymethyl)phosphinyl P(O)CH₂OH Functional Group

  摘要：

  (Hydroxymethyl)phosphorus compounds are well-known and valuable compounds in general; however the use of (hydroxymethyl)phosphinates (RP)-P-1(O)(OR2)CH2OH in particular has been much more limited. The potential of this functionality has not yet been fully realized because the mild unmasking of the hydroxymethyl group was not available. The mild oxidative conversion of (RP)-P-1(O)(OR2)CH2OH into (RP)-P-1(O)(OR2)H using the Corey-Kim oxidation is described. Other reactions preserving the methylene carbon are also reported.

  DOI：

  10.1021/ol3013793

文献信息

• NEAR-INFRARED-RAY-ABSORBING COMPOSITION, NEAR-INFRARED-RAY CUT FILTER USING SAME, MANUFACTURING METHOD THEREFOR, CAMERA MODULE, AND MANUFACTURING METHOD THEREFOR
  申请人：FUJIFILM CORPORATION

  公开号：US20160037034A1

  公开（公告）日：2016-02-04

  Provided are a near-infrared-ray-absorbing composition having strong near-infrared shielding properties when a cured film is produced, a near-infrared-ray cut filter, a manufacturing method therefor, a camera module, and a manufacturing method therefor. The near-infrared-ray-absorbing composition includes a copper complex obtained by reacting a compound (A) having at least two coordination sites with a copper component.

  提供了一种近红外光吸收组合物，当产生固化膜时具有强大的近红外屏蔽性能，以及一种近红外光切割滤光片、其制造方法、相机模块以及其制造方法。该近红外光吸收组合物包括通过将至少具有两个配位位点的化合物（A）与铜组分反应而获得的铜配合物。
• US9826129B2
  申请人：——

  公开号：US9826129B2

  公开（公告）日：2017-11-21
• Modular Synthesis of Polysubstituted α-Phosphorylated Arenes via the Catellani Strategy
  作者：Chen Chen、Jia-Hui Song、Lu-Yao Ding、Xiao-Xu Zhang、Kui Wang、Chunjie Ni、Jian Hu、Bolin Zhu

  DOI：10.1021/acs.orglett.4c01944

  日期：2024.7.12