9-[3-Carbazol-9-yl-5-(3,5-diphenylpyrazol-1-yl)phenyl]carbazole | 607740-13-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-[3-Carbazol-9-yl-5-(3,5-diphenylpyrazol-1-yl)phenyl]carbazole
• CAS: 607740-13-6
• 化学式: C₄₅H₃₀N₄
• 分子量: 626.76
• InChiKey: WLXNEFMVNUHLCT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.4
• 重原子数：
  49
• 可旋转键数：
  5
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-(3,5-Dibromophenyl)-3,5-diphenylpyrazole 、 咔唑 在 copper(l) iodide 、 (1R,2R)-1,2-diaminocyclohexane potassium phosphate 作用下， 以 1,4-二氧六环 为溶剂， 反应 18.0h， 以87%的产率得到9-[3-Carbazol-9-yl-5-(3,5-diphenylpyrazol-1-yl)phenyl]carbazole
  参考文献：
  名称：

  MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICES AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE MATERIAL

  摘要：

  一种用于有机电致发光器件的材料，包括一种化合物，其中含有氮的杂环基与芳基咔唑基或咔唑基烷基结合，以及包括至少一层的有机薄膜层的有机电致发光器件，该有机薄膜层位于阳极和阴极之间，并且至少一层在有机薄膜层中包含上述有机电致发光器件的材料。该材料可以提供发出高纯度蓝光的有机电致发光器件。该有机电致发光器件使用该材料。

  公开号：

  US20120319099A1

文献信息

• AROMATIC HETEROCYCLIC DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Kato Tomoki

  公开号：US20120273766A1

  公开（公告）日：2012-11-01

  An aromatic heterocyclic derivative represented by the following formula (1), a material for an organic electroluminescence device and an organic electroluminescence device including these:

  由以下公式（1）表示的芳香杂环衍生物，用作有机电致发光器件的材料以及包括这些材料的有机电致发光器件：
• NITROGEN-CONTAINING AROMATIC HETEROCYCLIC DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Kato Tomoki

  公开号：US20120181524A1

  公开（公告）日：2012-07-19

  A nitrogen-containing aromatic heterocyclic derivative represented by the following formula, wherein X 1 to X 3 are a single bond, CRaRb, NRc, an oxygen atom or a sulfur atom, and when all of X 1 to X 3 is a single bond, at least one of Ara, Arb and Arc is an aryl group having 6 to 20 ring carbon atoms substituted with a heteroaryl group, an aryloxy group or a heteroaryloxy group, or a substituted or unsubstituted heteroaryl group having 5 to 20 ring atoms.

  一种含氮芳香杂环衍生物，其化学式如下，其中X1至X3是单键，CRaRb，NRc，氧原子或硫原子，当X1至X3全部为单键时，至少有一个Ara，Arb和Arc是取代有杂芳基，芳氧基或杂芳氧基的6至20个环碳原子的芳基基团，或带有5至20个环原子的取代或未取代的杂芳基团。
• BISCARBAZOLE DERIVATIVE HOST MATERIALS AND RED EMITTER FOR OLED EMISSIVE REGION
  申请人：Yamamoto Hitoshi

  公开号：US20150194622A1

  公开（公告）日：2015-07-09

  The organic electroluminescence device utilizes a novel combination of a biscarbazole derivative compound as a phospherescent host materials and an orgaphosphorescent material as a red phosphorescent dopant material in the light emitting region of the device, where the biscarbazole derivative compound is represented by a formula (1); wherein the red phosphorescent dopant material is a phosphorescent organometallic complex having a substituted chemical structure represented by one of the partial chemical structures represented by a formulas (D1), (D2) and (D3).

  这个有机电致发光器件利用了一种新颖的组合，即在器件的发光区域中使用一种双咔唑衍生物化合物作为荧光主体材料，以及一种有机磷光材料作为红色磷光掺杂材料。其中，双咔唑衍生物化合物由公式（1）表示；红色磷光掺杂材料是一种磷光有机金属配合物，具有由公式（D1）、（D2）和（D3）中的任一部分化学结构进行替代的化学结构。
• ORGANIC EL DEVICE
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2166589A1

  公开（公告）日：2010-03-24

  An organic EL device includes: an anode (3); a cathode (4); and an organic thin-film layer (5) provided between the anode (3) and the cathode (4). The organic thin-film layer (5) includes: a fluorescent-emitting layer (51) containing a fluorescent host and a blue fluorescent dopant; a red phosphorescent-emitting layer (52) containing a red phosphorescent host and a red phosphorescent dopant; and a green phosphorescent-emitting layer (53) containing a green phosphorescent host and a green phosphorescent dopant. The red phosphorescent dopant emits light mainly by receiving transfer of triplet energy from the fluorescent host. The green phosphorescent dopant emits light mainly by recombination of charges within the green phosphorescent-emitting layer.

  有机 EL 器件包括：阳极 (3)；阴极 (4)；以及位于阳极 (3) 和阴极 (4) 之间的有机薄膜层 (5)。有机薄膜层（5）包括：荧光发光层（51），包含荧光主控体和蓝色荧光掺杂剂；红色磷光发光层（52），包含红色磷光主控体和红色磷光掺杂剂；以及绿色磷光发光层（53），包含绿色磷光主控体和绿色磷光掺杂剂。红色磷光掺杂剂主要通过接收荧光宿主的三重态能量转移发光。绿色磷光掺杂剂主要通过绿色磷光发光层内的电荷重组发光。
• AROMATIC AMINE DERIVATIVE, ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP2816025A1

  公开（公告）日：2014-12-24

  An organic EL device that has a high efficiency and a long service life, an electronic apparatus containing the organic EL device, and a compound capable of providing the organic EL device. The compound is specifically represented by the following general formula (1): wherein in the general formula (1), Ar1 represents an organic group A represented by the following general formula (A-1); Ar2 represents the organic group A or an organic group B represented by the following general formula (B-1); and Ar3 represents the organic group B or an organic group C represented by the following general formula (C-1), provided that in the case where both Ar1 and Ar2 are the organic groups A, the organic groups A may be the same as or different from each other, in the general formula (A-1), R1 and R2 each represent a hydrogen atom, an alkyl group or an aryl group, and R1 and R2 may be bonded to each other to form a hydrocarbon ring; R3 to R6 each represent an alkyl group, a cycloalkyl group or an aryl group; and a, b, c and d each independently represent an integer of from 0 to 2, provided that R3 and R4 may be bonded to each other to form a hydrocarbon ring; and in the case where a or b is 2, adjacent groups of R3 or adjacent groups of R4 may be bonded to each other to form a hydrocarbon ring, in the general formula (B-1), Ar4 and Ar5 each represent an arylene group; Ar6 represents an aryl group; R7 to R9 each represent an alkyl group, a cycloalkyl group or an aryl group; e, f and g each represent an integer of from 0 to 2; and h and i each represent 0 or 1, provided that R7 to R9 may be bonded to each other to form a hydrocarbon ring; and in the case where e, f or g is 2, adjacent groups of R7, adjacent groups of R8 or adjacent groups of R9 may be bonded to each other to form a hydrocarbon ring, in the general formula (C-1), Ar7 represents an aryl group; R10 represents an alkyl group, a cycloalkyl group or an aryl group; and j represents an integer of from 0 to 2, provided that in the case where j is 2, adjacent groups of R10 may be bonded to each other to form a hydrocarbon ring.

  一种具有高效率和长使用寿命的有机电致发光器件，一种包含该有机电致发光器件的电子设备，以及一种能够提供该有机电致发光器件的化合物。该化合物具体由以下通式（1）表示： 其中，在通式（1）中，Ar1 代表由以下通式（A-1）表示的有机基团 A；Ar2 代表有机基团 A 或由以下通式（B-1）表示的有机基团 B；以及 Ar3 代表有机基团 B 或由以下通式（C-1）表示的有机基团 C，条件是在 Ar1 和 Ar2 都是有机基团 A 的情况下，有机基团 A 可以彼此相同或彼此不同、 在通式（A-1）中，R1 和 R2 分别代表氢原子、烷基或芳基，R1 和 R2 可相互键合形成烃环；R3 至 R6 分别代表烷基、环烷基或芳基；a、b、c 和 d 各自独立地代表 0 至 2 的整数，条件是 R3 和 R4 可以相互键合以形成一个烃环；在 a 或 b 为 2 的情况下，R3 的相邻基团或 R4 的相邻基团可以相互键合以形成一个烃环、 在通式（B-1）中，Ar4 和 Ar5 分别代表芳烯基；Ar6 代表芳基；R7 至 R9 分别代表烷基、环烷基或芳基；e、f 和 g 分别代表 0 至 2 的整数；以及 h 和 i 各自代表 0 或 1，条件是 R7 至 R9 可相互键合形成一个烃环；在 e、f 或 g 为 2 的情况下，R7 的相邻基团、R8 的相邻基团或 R9 的相邻基团可相互键合形成一个烃环、 在通式（C-1）中，Ar7 代表芳基；R10 代表烷基、环烷基或芳基；j 代表 0 至 2 的整数，但在 j 为 2 的情况下，R10 的相邻基团可相互键合形成烃环。