2,4-bis(3-bromophenyl)-6-phenyl-1,3,5-triazine | 1238752-24-3

• 物质功能分类: 材料化学 - 配体
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-bis(3-bromophenyl)-6-phenyl-1,3,5-triazine
• CAS: 1238752-24-3
• 化学式: C₂₁H₁₃Br₂N₃
• 分子量: 467.162
• InChiKey: LVWXBDDRDWSKGY-UHFFFAOYSA-N

物化性质

• 沸点：
  623.2±65.0 °C(Predicted)
• 密度：
  1.571±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,4-bis(3-bromophenyl)-6-phenyl-1,3,5-triazine 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 、 水 、 甲苯 为溶剂， 反应 24.0h， 生成 4-[3-[4-(3-Dibenzofuran-4-ylphenyl)-6-phenyl-1,3,5-triazin-2-yl]phenyl]-9-phenylcarbazole
  参考文献：
  名称：

  ORGANIC OPTOELECTRONIC DIODE AND DISPLAY DEVICE

  摘要：

  本发明涉及一种有机光电器件，包括彼此对面的阳极和阴极，以及位于阳极和阴极之间的有机层，其中有机层包括至少一种孔注入层、孔传输层、发光层和电子传输层，发光层包括第一主机、第二主机和化学式4所表示的磷光掺杂剂，以及包括该器件的显示装置。

  公开号：

  US20200161563A1
• 作为产物：
  描述：

  间溴苯甲腈 、 苯甲酰氯 在 氨 作用下， 以 氯苯 、 水 为溶剂， 以82%的产率得到2,4-bis(3-bromophenyl)-6-phenyl-1,3,5-triazine
  参考文献：
  名称：

  具有固态固态2,4,6-三苯基-1,3,5-三嗪间隔基的分子镊子的二聚化不同。

  摘要：

  具有2,4,6-三苯基-1,3,5-三嗪间隔基的分子镊子在固态下通过pi-pi堆积相互作用表现出不同的二聚化作用，并且这些二聚体物种形成了高度组织化的超分子网络。

  DOI：

  10.1039/c0cc00454e

文献信息

• COMPOUND, LIGHT EMITTING MATERIAL, AND ORGANIC LIGHT EMITTING ELEMENT
  申请人：Kyushu University, National University Corporation

  公开号：EP2808323A1

  公开（公告）日：2014-12-03

  A compound represented by the general formula (1) is useful as a light-emitting material. In the general formula (1), Ar1 to Ar3 represent an aryl group, provided that at least one thereof represents an aryl group substituted by a group represented by the general formula (2). In the general formula (2), R1 to R8 represent a hydrogen atom or a substituent; Z represents O, S, O=C or Ar4-N; and Ar4 represents an aryl group.

  通式（1）所代表的化合物作为发光材料是有用的。在通式（1）中，Ar1至Ar3代表芳基，前提是其中至少一个代表被通式（2）所代表的基团取代的芳基。在通式（2）中，R1至R8代表氢原子或取代基；Z代表O、S、O=C或Ar4-N；Ar4代表芳基。
• 유기발광 화합물 및 이를 포함하는 유기전계발광소자
  申请人：Kyung-In Synthetic Corporation (주)경인양행(119981070884) Corp. No ▼ 120111-0005703BRN ▼137-81-00562

  公开号：KR20160059733A

  公开（公告）日：2016-05-27

  본 발명은 하기 [화학식 1]로 표시되는 유기발광 화합물 및 이를 포함하는 유기전계발광소자에 관한 것으로서, 본 발명에 따른 유기발광 화합물은 HOMO와 LUMO의 밴드갭을 감소시켜 도판트에서 발현되는 광을 보다 효율적으로 구현하여 구동 전압, 발광효율, 휘도, 열적 안정성 및 소자 수명 등의 제반 발광 특성이 더욱 향상된 유기전계발광소자를 구현할 수 있다. [화학식 1]

  This is the translation of the text you provided: This invention relates to an organic light-emitting compound represented by the following [Chemical Formula 1] and an organic electroluminescent device including the same. The organic light-emitting compound according to the present invention can implement an organic electroluminescent device with improved overall luminescent characteristics such as driving voltage, luminous efficiency, luminance, thermal stability, and device lifetime by reducing the band gap between HOMO and LUMO to more efficiently emit light in the dopant. [Chemical Formula 1]
• Novel triazine derivatives with deep LUMO energy levels as the electron-accepting components of exciplexes
  作者：Jing Guo、Cai-Jun Zheng、Ke Ke、Ming Zhang、Hao-Yu Yang、Jue-Wen Zhao、Ze-Yu He、Hui Lin、Si-Lu Tao、Xiao-Hong Zhang

  DOI：10.1039/d0tc04751a

  日期：——

  Three novel triazine-based acceptors TRZ-1SO₂, TRZ-2SO₂ and TRZ-3SO₂ were successfully developed with deep LUMO energy levels of −3.38, −3.58 and −3.74 eV, respectively. They will benefit the further development of exciplexes.

  三种基于三嗪的新型受体TRZ-1SO2、TRZ-2SO2和TRZ-3SO2成功开发，其深的LUMO能级分别为-3.38、-3.58和-3.74电子伏特。它们将有助于进一步发展异质结。
• MATERIALS FOR ORGANIC ELECTROLUMINESCENT DEVICES
  申请人：Pflumm Christof

  公开号：US20120068170A1

  公开（公告）日：2012-03-22

  The present invention describes indenocarbazole derivatives having electron- and hole-transporting properties, in particular for use in the emission and/or charge-transport layer of electroluminescent devices or as matrix material. The invention furthermore relates to a process for the preparation of the compounds according to the invention and to electronic devices comprising same.

  本发明描述了具有电子和空穴传输性质的吲哚并[3,2-b]咔唑衍生物，特别适用于电致发光器件的发射和/或电荷传输层或作为基质材料。此外，本发明还涉及根据本发明制备化合物的方法以及包括这些化合物的电子器件。
• COMPOUND, LIGHT-EMITTING MATERIAL, AND ORGANIC LIGHT-EMITTING DEVICE
  申请人：KYUSHU UNIVERSITY NATIONAL UNIVERSITY CORPORATION

  公开号：US20150041784A1

  公开（公告）日：2015-02-12

  A compound represented by the general formula (1) is useful as a light-emitting material. In the general formula (1), Ar 1 to Ar 3 represent an aryl group, provided that at least one thereof represents an aryl group substituted by a group represented by the general formula (2). In the general formula (2), R 1 to R 8 represent a hydrogen atom or a substituent; Z represents O, S, O═C or Ar 4 —N; and Ar 4 represents an aryl group.

  通式（1）所表示的化合物可用作发光材料。在通式（1）中，Ar1至Ar3表示芳基基团，但至少其中一个表示被通式（2）所表示的基团取代的芳基基团。在通式（2）中，R1至R8表示氢原子或取代基；Z表示O、S、O═C或Ar4—N；而Ar4表示芳基基团。