2-((3-methylbutan-2-yloxy)carbonyl)benzoic acid | 198284-10-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-((3-methylbutan-2-yloxy)carbonyl)benzoic acid
• 英文别名: Mono(1,2-dimethylpropyl)phthalate；(+/-)-phthalic acid mono-(1,2-dimethyl-propyl ester)；(+/-)-Phthalsaeure-mono-(1,2-dimethyl-propylester)；Mono(1,2-dimethylpropyl) phthalate；2-(3-methylbutan-2-yloxycarbonyl)benzoic acid
• CAS: 198284-10-5
• 化学式: C₁₃H₁₆O₄
• 分子量: 236.268
• InChiKey: AJRMLQSJNSDUHW-UHFFFAOYSA-N

物化性质

• 沸点：
  363.2±25.0 °C(Predicted)
• 密度：
  1.143±0.06 g/cm3(Predicted)
• 保留指数：
  1839

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  苯酐 、 3-甲基-2-丁醇 生成 2-((3-methylbutan-2-yloxy)carbonyl)benzoic acid
  参考文献：
  名称：

  Pickard; Kenyon, Journal of the Chemical Society, 1911, vol. 99, p. 55,71

  摘要：

  DOI：

文献信息

• Process for producing butene-1 polymer
  申请人：IDEMITSU PETROCHEMICAL CO. LTD.

  公开号：EP0249984A2

  公开（公告）日：1987-12-23

  This invention provides a process for producing a butene-1 polymer in the presence of a catalyst obtained from a solid catalyst component (A) prepared from a magnesium compound, an electron donating compound and a titanium compound, an organoaluminum compound (B) and an electron donating compound (C), said electron donating compound (C) being at least one compound selected from the group consisting of organophosphorus compound of the following general formula(1) and heterocyclic compound of the follwoing qeneral formula(2): . (wherein R1 and R2 each represents an alkyl, cycloalkyl or aryl group of 1-10 carbon atoms, X represents a halogen atom and m and n are real numbers which satisfy 0

  本发明提供了一种在催化剂存在下生产丁烯-1聚合物的工艺，催化剂由镁化合物、电子供体化合物和钛化合物制备的固体催化剂组分(A)、有机铝化合物(B)和电子供体化合物(C)组成，所述电子供体化合物(C)是至少一种选自以下通式(1)的有机磷化合物和以下通式(2)的杂环化合物组成的化合物： .(其中 R1 和 R2 分别代表 1-10 个碳原子的烷基、环烷基或芳基，X 代表卤素原子，m 和 n 是实数，满足 0
• Process for producing polybutene-1
  申请人：IDEMITSU PETROCHEMICAL CO. LTD.

  公开号：EP0294767A1

  公开（公告）日：1988-12-14

  Disclosed is a process for producing polybutene-1 suitable to be molded into pipes and the like by vapor phase polymerization in the presence of a catalyst obtained from (A) a solid catalyst component obtained from a magnesium compound, an electron donating compound and a halide of tetravalent titanium (B) an organoaluminum compound and (C) an electron donor wherein said solid catalyst component (A) has an average particle size of 5-200µm, a geometrical standard deviation (σ g) of particle size distribution of less than 2.1 and a molar ratio of electron donating compound/magnesium of 0.01 or more and said electron donor (C) is at least one compound selected from the group consisting of a heterocyclic compound represented by the formula: (wherein R¹, R², R³, R⁴ and R⁵ are as defined before), an ether compound represented by the formula:     R6nC(OR⁷)4-n      (2) (wherein R⁶ and R⁷ and n are as defined before) and an organic peroxide represented by the formula: (wherein R⁸, R⁹, R¹⁰ and R¹¹ are as defined), and the vapor phase polymerization is carried out at a molar ratio of hydrogen/butene-1 of 0.001-0.1.

  本发明公开了一种通过气相聚合生产聚丁烯-1 的工艺，该聚丁烯-1 适合在以下催化剂的存在下模塑成管道或类似物：(A) 由镁化合物、电子供体化合物和四价钛的卤化物组成的固体催化剂组分 (B) 有机铝化合物和 (C) 电子供体，其中所述固体催化剂组分 (A) 的平均粒径为 5-200µm，粒径分布的几何标准偏差 (σg)小于 2.1 且电子供体化合物/镁的摩尔比为 0.01 或更高，且所述电子供体 (C) 至少是一种选自以下组别的化合物：由式表示的杂环化合物： (其中 R¹、R²、R³、R⁴ 和 R⁵ 如前定义）、 由以下式子表示的醚化合物 R6nC(OR⁷)4-n (2) (其中 R⁶、R⁷ 和 n 如前定义）和由式表示的有机过氧化物： (其中 R⁸、R⁹、R¹⁰ 和 R¹¹ 如前定义），以及 气相聚合在氢/丁烯-1 的摩尔比为 0.001-0.1 的条件下进行。
• Polypropylene composition comprising lubricants for calendering
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP0744439A1

  公开（公告）日：1996-11-27

  A polypropylene resin composition is herein disclosed which is obtainable by blending (A) 100 parts by weight of a polypropylene resin comprising (a) 100 to 20% by weight of a homopolymer of propylene and/or a propylene copolymer containing 4% by weight or less of another olefin unit in which in a pentad fraction by 13C-NMR, [rrrr/(1-mmmm)]×100 is in the range of 20 to 60%, a Tm measured by a DSC is 150°C or more, and a melt enthalpy is 100 J/g or less, and (b) 0 to 80% by weight of a propylene copolymer containing 10 to 80% by weight of an olefin unit other than propylene, with (B) 0.01 to 5 parts by weight of an octyltin salt of a fatty acid, an alkylenebisfatty acid amide, a fatty acid ester of a polyvalent alcohol, or a metal salt of an aliphatic monocarboxylic acid. The employment of this polypropylene resin composition permits, under a good moldability by the calender molding machine, the manufacture of films and sheets having less thickness unevenness, excellent appearance and heat resistance and such flexibility as in molded articles of a plastic polyvinyl chloride.

  本文公开了一种聚丙烯树脂组合物，该组合物可通过混合以下物质获得：(A) 100 份（按重量计）聚丙烯树脂，该树脂包含(a) 100%至 20%（按重量计）的丙烯均聚物和/或丙烯共聚物，该丙烯均聚物和/或丙烯共聚物含有 4%（按重量计）或更少的另一种烯烃单元，在 13C-NMR 测量的五元组分中，[rrrr/(1-mmm)]×100 在 20%至 60%的范围内，通过 DSC 测量的 Tm 为 150°C 或更高，熔体焓为 100 J/g、[rrrr/(1-mmm)]×100在20%至60%的范围内，用DSC测量的Tm为150℃或以上，熔体焓为100焦耳/克或以下，以及(b)0至80%(重量)的丙烯共聚物，其中含有10%至80%(重量)的丙烯以外的烯烃单元，以及(B)0.01 至 5 份(重量)脂肪酸的辛基锡盐、亚烷基二脂肪酸酰胺、多价醇的脂肪酸酯或脂族单羧酸的金属盐。 使用这种聚丙烯树脂组合物，可以在压延成型机的良好成型条件下，制造出厚度不均匀度较小、外观和耐热性极佳的薄膜和片材，其柔韧性与聚氯乙烯塑料成型品相当。
• PROPYLENE RESIN COMPOSITION FOR INTERIOR MATERIAL FOR AUTOMOBILES, AND INTERIOR MATERIAL FOR AUTOMOBILES
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP0784074A1

  公开（公告）日：1997-07-16

  There are here disclosed a propylene resin composition which can be used for the manufacture of automotive interior parts as a molding material having a good weld appearance, a less gloss unevenness, a good appearance performance and a low glossiness and permitting non-coating, and the automotive interior parts obtained from the composition. The propylene resin composition for the automotive interior parts of the present invention is a crystalline propylene polymer-containing composition having a specific melt index and relaxation time (τ) or a specific molecular-weight distribution index (PDI) in addition to these characteristics, or a propylene resin composition comprising the crystalline propylene polymer-containing composition, an inorganic filler and the like. The automotive interior parts of the present invention obtained by injection molding these compositions can suitably be used as installment panels, console boxes or trims.

  本发明公开了一种丙烯树脂组合物，该组合物可用于制造汽车内饰件，作为一种成型材料，具有良好的焊接外观、较少的光泽不均匀度、良好的外观性能和较低的光泽度，并且允许不涂覆，以及由该组合物获得的汽车内饰件。 本发明的汽车内饰件用丙烯树脂组合物是具有特定熔融指数和松弛时间（τ）或除这些特性外还具有特定分子量分布指数（PDI）的含结晶丙烯聚合物组合物，或者是由含结晶丙烯聚合物组合物、无机填料等组成的丙烯树脂组合物。本发明的汽车内饰件通过注塑这些组合物而获得，可适当用作安装面板、控制台盒或饰件。
• FLEXIBLE POLYPROPYLENE RESIN
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP1273596A1

  公开（公告）日：2003-01-08

  The present invention relates to a soft polypropylene resin having a melt index falling in a specific range, prepared by melting and kneading a substantial propylene homopolymer or a propylene copolymer composition each having specific properties in the presence of a radical-generating agent. According to the present invention, capable of being provided at a good productivity is a soft polypropylene resin which is useful as an alternative for a polyvinyl chloride resin in the fields of films, sheets, construction materials and the like and which is excellent in fluidity.

  本发明涉及一种熔融指数在特定范围内的软质聚丙烯树脂，其制备方法是在有自由基生成剂存在的情况下，熔化和捏合具有特定性质的大量丙烯均聚物或丙烯共聚物组合物。 根据本发明，可以提供一种生产效率高的软质聚丙烯树脂，它可以在薄膜、板材、建筑材料等领域替代聚氯乙烯树脂，而且流动性极佳。