三氯乙酸乙烯酯 | 7062-87-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 三氯乙酸乙烯酯
• 英文名称: Trichlor-essigsaeure-vinylester
• 英文别名: Vinyl-trichloracetat；Vinyl trichloroacetate；ethenyl 2,2,2-trichloroacetate
• CAS: 7062-87-5
• 化学式: C₄H₃Cl₃O₂
• mdl: MFCD00080709
• 分子量: 189.426
• InChiKey: HDSFLVZBTRAEEM-UHFFFAOYSA-N

物化性质

• 沸点：
  60°C 1mm
• 密度：
  1,3 g/cm3
• 闪点：
  >80°C

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 危险类别码：
  R36/37/38
• 海关编码：
  2915400090
• 安全说明：
  S26,S36

反应信息

• 作为反应物：
  描述：

  三氯溴甲烷 、 三氯乙酸乙烯酯 生成 Trichloro-acetic acid 1-bromo-3,3,3-trichloro-propyl ester
  参考文献：
  名称：

  Radical addition of halogen-containing addends to unsaturated compounds containing electron-acceptor groups

  摘要：

  DOI：

  10.1007/bf00857392
• 作为产物：
  描述：

  二乙烯基汞 、 三氯乙酸 反应 1.0h， 生成 三氯乙酸乙烯酯
  参考文献：
  名称：

  Organomercury Chemistry. A Novel Synthesis of Vinyl Esters, Vinyl Ethers and Vinyl Thioethers¹

  摘要：

  DOI：

  10.1021/ja01465a028

文献信息

• [EN] PROCESSES AND INTERMEDIATES FOR PREPARING MCL1 INHIBITORS<br/>[FR] PROCÉDÉS ET INTERMÉDIAIRES POUR LA PRÉPARATION D'INHIBITEURS DE MCL1
  申请人：GILEAD SCIENCES INC

  公开号：WO2021108254A1

  公开（公告）日：2021-06-03

  The present disclosure provides methods for preparing MCL1 inhibitors or a salt thereof and related key intermediates.

  本公开提供了制备MCL1抑制剂或其盐及相关关键中间体的方法。
• Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
  申请人：——

  公开号：US20030181619A1

  公开（公告）日：2003-09-25

  Improved processes for atom (or group) transfer radical polymerization (ATRP) and novel polymers have been developed and are described. In certain embodiments, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly alternating monomer sequence are described. Novel copolymers comprising a least one polymeric branch or polymeric block with a gradient monomer structure are described. Additionally, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly periodic monomer sequence are also described. Novel copolymers having a water soluble backbone and at least two hydrophobic polymeric branches grafted to the water soluble backbone are also described.

  已经开发并描述了改进的原子（或基团）转移自由基聚合（ATRP）过程和新型聚合物。在某些实施例中，描述了包括至少一个具有主要交替单体序列的聚合物支链或聚合物块的新型共聚物。还描述了包括至少一个具有梯度单体结构的聚合物支链或聚合物块的新型共聚物。此外，还描述了包括至少一个具有主要周期单体序列的聚合物支链或聚合物块的新型共聚物。还描述了具有水溶性骨架和至少两个疏水聚合物支链嫁接到水溶性骨架上的新型共聚物。
• Method for production of a sealed coating for surfaces of buildings comprising a cross-linked sealed silicone membrane, adhesive and ready-to-use kit for application of said method
  申请人：——

  公开号：US20040234786A1

  公开（公告）日：2004-11-25

  The invention relates to a method for production of a sealed surface coating, for buildings (floor/wall/ceiling), of the type where a series of layers, or elements are fixed on the surface, comprising, starting from the surface, optionally at least one primer adhesive layer, at least one watertight polymer membrane, (optionally at least one woven or non-woven fibrous material layer), at least one layer of adhesive and at least one external cover, characterised in that (a) the sealed membrane is chosen from those which may be obtained from a an aqueous dispersion of silicone oil(s), (b) the adhesive applied comprises at least one adhesion promoter (C′), (c) the aqueous dispersion of silicone oil(s) is applied as a film to the surface, (d) the cross-linking of the silicone layer occurs subsequently, preferably at an ambient temperature, (e) the application of at last one layer of adhesive with added adhesion promoter (C′) is then applied, preferably by surface coating on the cross-linked silicone film and finally the external cover is applied.

  本发明涉及一种用于建筑物（地板/墙壁/天花板）密封表面涂层的生产方法，其中在表面固定一系列层或元素，包括从表面开始，可选地至少一种底漆粘合层，至少一种防水聚合物膜层，（可选地至少一种编织或非编织纤维材料层），至少一种粘合层和至少一种外部覆盖层，其特征在于（a）密封膜是从硅油水分散液中获得的膜之一，（b）应用的粘合剂包括至少一种粘附剂（C'），（c）硅油水分散液被涂覆在表面上形成一膜，（d）硅层的交联随后发生，最好在室温下进行，（e）然后应用至少一层添加粘附剂（C'）的粘合剂，最好通过在交联的硅膜上进行表面涂层，最后应用外部覆盖层。
• Nanofilm compositions with polymeric components
  申请人：——

  公开号：US20040106741A1

  公开（公告）日：2004-06-03

  Nanofilms useful for filtration are prepared from amphiphilic species and one or more polymeric components. The amphiphilic species or components may be oriented on an interface or surface. A nanofilm may be prepared by coupling one or more of the components. The nanofilm may also be deposited or attached to a substrate.

  利用亲疏性物质和一个或多个聚合物组分制备用于过滤的纳米薄膜。亲疏性物质或组分可以定向于界面或表面上。可以通过耦合一个或多个组分来制备纳米薄膜。纳米薄膜也可以沉积或附着在基底上。
• Moisture-absorbing and desorbing polymer and compositions derived therefrom
  申请人：——

  公开号：US20020010295A1

  公开（公告）日：2002-01-24

  Disclosed herein is a moisture-absorbing and desorbing polymer, characterized in that, the said polymer is an organic high-molecular substance containing 1.0-8.0 meq/g of carboxyl group of a potassium type and having a cross-linking structure.

  本文揭示了一种具有吸湿和脱湿性能的聚合物，其特征在于该聚合物是一种有机高分子物质，含有1.0-8.0毫当量/克的钾型羧基，并具有交联结构。