4,4'-bis[4-(4-hydroxyphenoxy)phenoxy]diphenyl ether | 15051-28-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-bis[4-(4-hydroxyphenoxy)phenoxy]diphenyl ether
• 英文别名: p,p'-Bis--diphenylether；p,p'-Bis-[p-(p-hydroxy-phenoxy)-phenoxy]-diphenylether；4-[4-[4-[4-[4-(4-Hydroxyphenoxy)phenoxy]phenoxy]phenoxy]phenoxy]phenol；4-[4-[4-[4-[4-(4-hydroxyphenoxy)phenoxy]phenoxy]phenoxy]phenoxy]phenol
• CAS: 15051-28-2
• 化学式: C₃₆H₂₆O₇
• 分子量: 570.598
• InChiKey: WZRRLNNLQORQPH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  43
• 可旋转键数：
  10
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.6
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  4,4'-bis(p-iodophenoxy)diphenyl ether 、 4,4'-bis[4-(4-hydroxyphenoxy)phenoxy]diphenyl ether 在 copper(l) iodide 、 N,N-二甲基甘氨酸盐酸盐 、 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 以21%的产率得到2,7,12,17,22,27,32,37,42,47-Decaoxaundecacyclo[46.2.2.23,6.28,11.213,16.218,21.223,26.228,31.233,36.238,41.243,46]heptaconta-1(50),3(70),4,6(69),8(68),9,11(67),13(66),14,16(65),18(64),19,21(63),23(62),24,26(61),28,30,33,35,38,40,43,45,48,51,53,55,57,59-triacontaene
  参考文献：
  名称：

  Synthesis and Structure of Cyclic Oligo(p-phenylene oxide)s,  −(C₆H₄O)_n− (n = 6−10)

  摘要：

  Stepwise growth of oligo(p-phenylene oxide)s and cyclization via the Ullmann coupling reaction by using CuI/N,N-dimethyl-glycine afforded cyclic oligo( p-phenyleneoxide)s, -(C6H4O)- (n = 6-10). The structure of the new cyclophanes was determined by X-ray crystallography, which revealed that they have planar or slightly bent structures with diameters of 1.0-1.5 nm.

  DOI：

  10.1021/jo0609982
• 作为产物：
  描述：

  4,4'-二羟基二苯醚 在 盐酸 、 copper(l) iodide 、 N,N-二甲基甘氨酸盐酸盐 、 caesium carbonate 、 N,N-二异丙基乙胺 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 、 异丙醇 、 乙腈 为溶剂， 反应 14.0h， 生成 4,4'-bis[4-(4-hydroxyphenoxy)phenoxy]diphenyl ether
  参考文献：
  名称：

  Synthesis and Structure of Cyclic Oligo(p-phenylene oxide)s,  −(C₆H₄O)_n− (n = 6−10)

  摘要：

  Stepwise growth of oligo(p-phenylene oxide)s and cyclization via the Ullmann coupling reaction by using CuI/N,N-dimethyl-glycine afforded cyclic oligo( p-phenyleneoxide)s, -(C6H4O)- (n = 6-10). The structure of the new cyclophanes was determined by X-ray crystallography, which revealed that they have planar or slightly bent structures with diameters of 1.0-1.5 nm.

  DOI：

  10.1021/jo0609982

文献信息

• Vorob'ev,Yu.P.; Segeev,V.A., Journal of Organic Chemistry USSR (English Translation), 1968, vol. 4, p. 70 - 73
  作者：Vorob'ev,Yu.P.、Segeev,V.A.

  DOI：——

  日期：——
• Synthesis and Structure of Cyclic Oligo(<i>p</i>-phenylene oxide)s,  −(C₆H₄O)<i>_n</i>− (<i>n</i> = 6−10)
  作者：Daisuke Takeuchi、Itaru Asano、Kohtaro Osakada

  DOI：10.1021/jo0609982

  日期：2006.10.1

  Stepwise growth of oligo(p-phenylene oxide)s and cyclization via the Ullmann coupling reaction by using CuI/N,N-dimethyl-glycine afforded cyclic oligo( p-phenyleneoxide)s, -(C6H4O)- (n = 6-10). The structure of the new cyclophanes was determined by X-ray crystallography, which revealed that they have planar or slightly bent structures with diameters of 1.0-1.5 nm.