S-p-nitrophenyl 2-methylpropanethioate | 893445-27-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: S-p-nitrophenyl 2-methylpropanethioate
• 英文别名: S-(4-nitrophenyl) 2-methylprop-2-enethioate
• CAS: 893445-27-7
• 化学式: C₁₀H₉NO₃S
• 分子量: 223.252
• InChiKey: NAIZCEZCHPMDGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  88.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-乙炔基环戊醇 、 S-p-nitrophenyl 2-methylpropanethioate 在 copper(l) iodide 、 potassium carbonate 、 三乙胺 、 palladium dichloride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 以48%的产率得到2,3-dihydro-3-methyl-6-(1'-p-nitrophenoxy-cyclopentyl)-thiopyran-4-one
  参考文献：
  名称：

  通过Pd / Cu催化α，β-不饱和硫代酯与炔丙醇的一锅合成2,3-二氢噻喃-4-酮衍生物。

  摘要：

  在碱存在下，通过α/β-不饱和硫代酯与炔丙醇之间的Pd / Cu催化反应可轻松制备2,3-二氢噻喃-4-酮衍生物。值得注意的是，由于单一程序，两个碳-硫键均被裂解。

  DOI：

  10.1021/ol800754w
• 作为产物：
  描述：

  4-硝基苯硫醇 、 甲基丙烯酰氯 在 吡啶 作用下， 以 四氢呋喃 为溶剂， 生成 S-p-nitrophenyl 2-methylpropanethioate
  参考文献：
  名称：

  通过Pd / Cu催化α，β-不饱和硫代酯与炔丙醇的一锅合成2,3-二氢噻喃-4-酮衍生物。

  摘要：

  在碱存在下，通过α/β-不饱和硫代酯与炔丙醇之间的Pd / Cu催化反应可轻松制备2,3-二氢噻喃-4-酮衍生物。值得注意的是，由于单一程序，两个碳-硫键均被裂解。

  DOI：

  10.1021/ol800754w

文献信息

• Tandem Type Polymerization. Synthesis and Characterization of Ordered Poly(amide−thioether) from 2,6-Dichlorophenyl Methacrylate, 4,4‘-Thiobis(benznenethiol), and 4,4‘-Oxydianiline
  作者：Kousuke Tsuchiya、Yuji Shibasaki、Mitsuru Ueda

  DOI：10.1021/ma025712j

  日期：2003.3.1

  Ordered poly(amide-thioether) (17) was prepared by tandem type polymerization of 2,4-dichlorophenyl acrylate (11), 4,4'-thiobis(benznenthiol) (12), and 4,4'-oxydianiline (16). The polymerization was carried out by mixing all monomers in the presence of catalytic amounts of triethylamine (TEA) and 1-hydroxybenzotriazole (HOBt) in 1-methyl-2-pyrrolidinone (NMP) at 20 degreesC for 2 h and then 80 degreesC for 2 days, yielding polymer 17 with a number-average molecular weight (M.) of 25 000. Authentic ordered poly(amide-thioether) (18) was prepared to verify the structure of polymer 17. The microstructure of polymers obtained was investigated by H-1 and C-13 NMR spectroscopy, and it has been found the polymer obtained has the expected ordered structure. Furthermore, model reactions were studied in detail to demonstrate the feasibility of ordered polymer formation.
• Reactions of α,β-Unsaturated Thioesters with Platinum(0):  Implication of a Dual Mechanism Leading to the Formation of Acyl Platinum
  作者：Yasunori Minami、Tomohiro Kato、Hitoshi Kuniyasu、Jun Terao、Nobuaki Kambe

  DOI：10.1021/om050834w

  日期：2006.6.1

  The moderate reactivity of the alpha,beta-unsaturated thioester (ArS) C(O) C(A)-C(B)(H) toward Pt(PPh3)(2)( C2H4) has been used to extract thermodynamic and kinetic information pertaining to the oxidative addition of alpha,beta-unsaturated acid halide derivatives to low-valent transition-metal complexes. The results indicate acyl platinum product complexes can form by direct C-S bond cleavage or by attack of coordinated Pt(PPh3)(2) on the beta-carbon.
• EP1624001A1
  申请人：——

  公开号：EP1624001A1

  公开（公告）日：2006-02-08
• PHOTOCURING/THERMOSETTING INKJET COMPOSITION AND PRINTED WIRING BOARD USING SAME
  申请人：Taiyo Ink Manufacturing Co. Ltd

  公开号：EP1624001B1

  公开（公告）日：2008-04-16
• Photocurable and thermosetting composition for ink jet system and printed circuit boards made by use thereof
  申请人：Kakinuma Masahisa

  公开号：US20060058412A1

  公开（公告）日：2006-03-16

  A photocurable and thermosetting composition for an ink jet system comprises (A) a monomer having a (meth)acryloyl group and a thermosetting functional group in its molecule, (B) a photoreactive diluent having a weight-average molecular weight of not more than 700 other than the component (A) mentioned above, and (C) a photopolymerization initiator and has a viscosity of not more than 150 mPa.s at 25° C. A solder resist pattern is directly drawn on a printed circuit board by means of an ink jet printer using the above-mentioned composition, and the pattern is primarily cured by irradiation with an active energy ray and then further cured by heating.