4-cyanobenzoate | 16885-67-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-cyanobenzoate
• CAS: 16885-67-9
• 化学式: C₈H₄NO₂
• 分子量: 146.125
• InChiKey: ADCUEPOHPCPMCE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  水 、 4-cyanobenzoate 、 silver nitrate 以 水 为溶剂， 生成 [Ag(4-cyanobenzoate)]n*n(water)
  参考文献：
  名称：

  A Direct White-Light-Emitting Metal−Organic Framework with Tunable Yellow-to-White Photoluminescence by Variation of Excitation Light

  摘要：

  A direct white-light metal-organic framework (MOF); [AgL](n)center dot nH(2)O (1, L = 4-cyanobenzoate), obtained by the reaction of deprotonated 4-cyanobenzoic acid and AgNO3 in water, was found to exhibit tunable yellow-to-white photoluminescence by variation of excitation tight. Interestingly, the close pure white emission of 1 has CIE-1931 chromaticity coordinates of (0.33, 0.34) when excited by 349-nm UV light, which is compatible to the tight output of the deep UV LED.

  DOI：

  10.1021/ja903947b
• 作为产物：
  描述：

  4-氰基苯甲酸苯酯 在 hydroxide 、 N,N,N-三乙基-1-十六烷基溴化铵 作用下， 以 水 、 乙腈 为溶剂， 生成 苯氧基自由基 、 4-cyanobenzoate
  参考文献：
  名称：

  Bartoletti, Antonella; Bartolini, Simona; Germani, Raimondo, Journal of the Chemical Society. Perkin transactions II, 1994, # 4, p. 723 - 728

  摘要：

  DOI：

文献信息

• A Direct White-Light-Emitting Metal−Organic Framework with Tunable Yellow-to-White Photoluminescence by Variation of Excitation Light
  作者：Ming-Sheng Wang、Sheng-Ping Guo、Yan Li、Li-Zhen Cai、Jian-Ping Zou、Gang Xu、Wei-Wei Zhou、Fa-Kun Zheng、Guo-Cong Guo

  DOI：10.1021/ja903947b

  日期：2009.9.30

  A direct white-light metal-organic framework (MOF); [AgL](n)center dot nH(2)O (1, L = 4-cyanobenzoate), obtained by the reaction of deprotonated 4-cyanobenzoic acid and AgNO3 in water, was found to exhibit tunable yellow-to-white photoluminescence by variation of excitation tight. Interestingly, the close pure white emission of 1 has CIE-1931 chromaticity coordinates of (0.33, 0.34) when excited by 349-nm UV light, which is compatible to the tight output of the deep UV LED.
• Bartoletti, Antonella; Bartolini, Simona; Germani, Raimondo, Journal of the Chemical Society. Perkin transactions II, 1994, # 4, p. 723 - 728
  作者：Bartoletti, Antonella、Bartolini, Simona、Germani, Raimondo、Savelli, Gianfranco、Bunton, Clifford A.

  DOI：——

  日期：——