acetic acid-(β,β'-diphenoxy-isopropyl ester) | 71159-31-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: acetic acid-(β,β'-diphenoxy-isopropyl ester)
• 英文别名: Essigsaeure-(β,β'-diphenoxy-isopropylester)；1.3-Diphenoxy-2-acetoxy-propan；Glycerin-α.α'-diphenylaether-β-acetat；α.γ-Diphenoxy-β-acetoxy-propan；1,3-diphenoxy-2-propanol, acetate；1,3-diphenoxy-2-propyl acetate；1,3-Diphenoxypropan-2-yl acetate
• CAS: 71159-31-4
• 化学式: C₁₇H₁₈O₄
• 分子量: 286.328
• InChiKey: ZDBQRKQOKLVMIN-UHFFFAOYSA-N

物化性质

• 熔点：
  33°C
• 沸点：
  388.69°C (rough estimate)
• 密度：
  1.1634 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  potassium phenolate 生成 acetic acid-(β,β'-diphenoxy-isopropyl ester)
  参考文献：
  名称：

  骨的红外显微成像：CO3（2-）的空间分布。

  摘要：

  本文介绍了一种新技术，用于定量确定骨矿物中CO3（2-）取代的空间分布，该技术使用的是约6微米空间分辨率的红外（IR）成像。这项新颖的技术包括一个64 x 64元素的IR阵列检测器，该检测器映射到IR显微镜焦平面上的400 microm x 400 microm点。在每次扫描期间，将从阵列中的每个元素获取完整的红外光谱。可以映射整个阵列上任何IR参数的变化。在当前的研究中，在一系列的一系列的观察中，观察到在1415 cm（-1）处的CO3（2-）v3轮廓的谱带面积或峰高比与PO4（3-）v1，v3轮廓之间的线性关系。合成的碳酸磷灰石。光谱和分析确定的比率之间的相关系数（R2 = 0。989）证明了该IR面积比在确定骨CO3（2-）水平方面的实用性。该关系形成了使用红外成像确定组织切片中的CO3（2-）的基础。在四张小梁骨图像中，平均CO3（2-）水平为5.95 wt％（2298个数据点），6

  DOI：

  10.1359/jbmr.2001.16.5.893

文献信息

• New Ring Opening Reactions of Oxiranes with Aryl Carboxylates
  作者：Kazutoshi Funahashi

  DOI：10.1246/bcsj.52.1488

  日期：1979.5

  Oxiranes reacted with aryl esters in the presence of base. The reactions of aryl carboxylates with alkyloxiranes afforded almost exclusively 1-alkyl-2-(aryloxy) ethyl carboxylates, whereas the reactions with aryloxiranes gave a mixture of 1-aryl-2-(aryloxy) ethyl carboxylates and 2-aryl-2-(aryloxy) ethyl carboxylates. Similar results were also obtained in the reaction with S-aryl thiocarboxylates and diaryl carbonates. The rate of reaction between phenyl acetate and phenoxymethyloxirane (PMO) in the presence of tributylamine (n-Bu3N) as a catalyst has been determined in the temperature range 110 to 130 °C and may be expressed by –d[PMO]⁄dt=k2[n-Bu3N]·[PMO]. The apparent activation energy calculated from the Arrhenius plots is 85.8 kj/mol. The reaction catalyzed by tributylamine is assumed to proceed through zwitter ions, n-Bu3\overset+NCH2CH(R)O− and n-Bu3\overset+NCH(R)CH2O−, which attack aryl carboxylate.

  在碱存在下，环氧乙烷与芳基酯反应。烷基环氧乙烷与芳基羧酸酯的反应主要生成1-烷基-2-芳氧基乙基羧酸酯，而芳基环氧乙烷的反应则生成1-芳基-2-芳氧基乙基羧酸酯和2-芳基-2-芳氧基乙基羧酸酯的混合物。在硫代芳基羧酸酯和二芳基碳酸酯与环氧乙烷的反应中也得到了类似的结果。在110至130°C的温度范围内，测定了苯甲酸乙酯与苯氧甲基环氧乙烷（PMO）在三丁胺（n-Bu3N）催化下的反应速率，可以用-d[PMO]/dt=k2[n-Bu3N]·[PMO]表示。从阿伦尼乌斯图计算出的表观活化能为85.8 kJ/mol。三丁胺催化的反应被认为是通过两性离子进行的，n-Bu3\overset+NCH2CH(R)O−和n-Bu3\overset+NCH(R)CH2O−，它们攻击芳基羧酸酯。
• Process for producing organic compound epoxy resin composition, cured article obtained from the epoxy resin, and semiconductor device obtained with epoxy resin
  申请人：——

  公开号：US20040260039A1

  公开（公告）日：2004-12-23

  There are disclosed a process for producing an organic compound in the presence of a particular substituted triarylphosphine compound, particularly, a process for producing an oxyalkylene derivative at a high yield using the above compound which is very active and easy to handle, by reacting an organic epoxy compound with a carboxylic acid ester, a carboxylic acid anhydride, a sulfonic acid ester or a carbonic acid ester, and an epoxy resin composition using a particular substituted triarylphosphine compound as a curing accelerator, a cured material of the composition and a semiconductor device using the composition.

  本文披露了一种在特定取代三芳基膦化合物存在下生产有机化合物的工艺，特别是一种使用上述化合物作为催化剂，通过将有机环氧化合物与羧酸酯、羧酸酐、磺酸酯或碳酸酯反应，以及使用特定取代三芳基膦化合物作为固化促进剂的环氧树脂组合物的工艺，从而高产地生产氧代烷基衍生物，还包括该组合物的固化材料和使用该组合物的半导体器件。
• Oxime derivatives and the use thereof as latent acids
  申请人：——

  公开号：US20040002007A1

  公开（公告）日：2004-01-01

  New oxime sulfonate compounds of the formula I, II, III, IV, V, VI and VII 1 2 R 1 is for example C 1 -C 18 alkylsulfonyl, R 2 is halogen or C 1 -C 10 haloalkyl; R 3 is for example unsubstituted or substituted phenylenedisulfonyl, diphenylenedisulfonyl, or oxydiphenylenedisulfonyl; Ar 1 is for example a direct bond, C 1 -C 12 alkylene; —O—C—bond or a —0—Si-bond which cleaves upon the action of an acid; A 1 , A 2 , A 3 , A 4 , A 5 , A 6 , A 7 , A 8 , A 9 , A 10 , A 11 and A 12 are for example a direct bond, —O—, or —S—, or are C 1 -C 12 alkylene or phenylene unsubstituted or substituted; Y 1 is C 1 -C 12 alkylene which is for example substituted by OR 4 , or SR 7 ; Y 2 is e.g. a trivalent radical of C 1 -C 12 alkylene; Y 3 is e.g. a tetravalent radical of C 1 -C 12 alkylene; X is halogen; Ar′ 1 is for example C 1 -C 12 alkyl which is unsubstituted or substituted; Ar″ 1 is for example phenylene; provided that at least one of the radicals Ar′ 1 , Ar″ 1 , is substituted by 1 to 3 groups of 3 is for example halogen; R 15 , R 16 , R 17 and R 18 e.g. hydrogen or phenyl; R 19 , R 20 , R 21 , R 22 and R 23 are e.g. phenyl; are especially suitable for the preparation of photoresists.

  公式I、II、III、IV、V、VI和VII的新氧肟磺酸盐化合物，其中12R1例如C1-C18烷基磺酰基，R2为卤素或C1-C10卤基烷基；R3例如未取代或取代的苯基二磺酰基，二苯基二磺酰基或氧二苯基二磺酰基；Ar1例如直接键，C1-C12烷基，—O—C—键或在酸作用下断裂的—0—Si键；A1、A2、A3、A4、A5、A6、A7、A8、A9、A10、A11和A12例如直接键，—O—或—S—，或是未取代或取代的C1-C12烷基或苯基；Y1例如C1-C12烷基，例如被OR4或SR7取代；Y2例如C1-C12烷基的三价基团；Y3例如C1-C12烷基的四价基团；X是卤素；Ar′1例如未取代或取代的C1-C12烷基；Ar″1例如苯基；至少一个Ar′1、Ar″1基团被1至3个3例如卤素取代；R15、R16、R17和R18例如氢或苯基；R19、R20、R21、R22和R23例如苯基；特别适用于光刻胶的制备。
• A phosphine sulfide, a manufacturing process therefor and a use thereof
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0972776A1

  公开（公告）日：2000-01-19

  A basic organic compound which is soluble in an organic solvent, does not have problems in its preparation or handling and exhibits catalytic activity as a basic compound, is a phosphine sulfide represented by the (1): The phosphine sulfide represented by formula (1), is made by reacting one molecule of thiophosphoryl chloride with three molecules of a phosphorane represented by formula (2): A process for effectively manufacturing a poly(alkylene oxide) involves polymerizing an alkylene oxide in the presence of the above organic compound (phosphine sulfide), or in the presence of the phosphine sulfide and an active hydrogen compound selected from water and organic compounds having a partial structure of -OH or -NH-. A process for manufacturing a 1,2-dioxyethane derivative from an epoxy compound, i.e. manufacturing a 1,2-dioxyethane derivative involves reacting an epoxy compound with a carboxylate, carboxylic anhydride, carbonate or phenol compound, respectively, in the presence of the phosphine sulfide.

  一种可溶于有机溶剂、在制备或处理过程中不会出现问题并具有催化活性的碱性有机化合物是硫化膦，其代表式为（1）： 式（1）代表的硫化膦是由一分子硫代磷酰氯与三分子式（2）代表的磷烷反应制得的： 一种有效制造聚环氧亚烷烃的工艺是在上述有机化合物（硫化膦）存在下，或在硫化膦和选 自水和部分结构为-OH 或-NH-的有机化合物的活性氢化合物存在下，聚合环氧亚烷烃。 由环氧化合物制造 1，2-二氧乙烷衍生物的工艺，即制造 1，2-二氧乙烷衍生物的工艺包括在硫化膦存在下，环氧化合物分别与羧酸盐、羧酸酐、碳酸盐或苯酚化合物反应。
• Alkoxy methyl ether and alkoxy methyl ester derivatives
  申请人：SYNTEX (U.S.A.) INC.

  公开号：EP0187297B1

  公开（公告）日：1991-08-21