2-methyl-4-[(E)-2-(4-nitrophenyl)-1-ethenyl]anilino-1-ethanol | 122008-76-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 2-methyl-4-[(E)-2-(4-nitrophenyl)-1-ethenyl]anilino-1-ethanol
• 英文别名: 4-N-2-Hydroxyethyl-N-methylamino-4'-nitrostilbene；2-[N-methyl-4-[(E)-2-(4-nitrophenyl)ethenyl]anilino]ethanol
• CAS: 122008-76-8
• 化学式: C₁₇H₁₈N₂O₃
• 分子量: 298.342
• InChiKey: KBHNWBMEOJIFAG-NSCUHMNNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  69.3
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-methyl-4-[(E)-2-(4-nitrophenyl)-1-ethenyl]anilino-1-ethanol 、 Hoffer's chlorosugar 在 calcium sulfate 、 silver(l) oxide 作用下， 以 氯仿 为溶剂， 反应 24.0h， 生成 、
  参考文献：
  名称：

  Teo, Yin Nah; Wilson, James N.; Kool, Eric T., Journal of the American Chemical Society, 2009, vol. 131, p. 3923 - 3933

  摘要：

  DOI：
• 作为产物：
  描述：

  对氟苯甲醛 在 哌啶 、 甲基三辛基氯化铵 、 potassium carbonate 作用下， 以 二甲基亚砜 、 N,N-二甲基甲酰胺 为溶剂， 反应 45.0h， 生成 2-methyl-4-[(E)-2-(4-nitrophenyl)-1-ethenyl]anilino-1-ethanol
  参考文献：
  名称：

  Synthesis and Nonlinear-Optical Properties of Vinyl-Addition Poly(norbornene)s

  摘要：

  Vinyl-addition poly(norbornene) copolymers functionalized with nonlinear optical chromophore side groups have been prepared using (eta(6)-toluene)Ni(C6F5)(2), and their electrooptic properties have been characterized. The nickel complex used to polymerize the norbornene monomers is tolerant to many functional groups found in nonlinear optical chromophores although nitriles and amines other than trisubstituted amines strongly inhibit the reaction. A vinyl-addition copolymer of hexylnorbornene and a norbornene-functionalized Disperse Red 1 chromophore was scaled up and studied in detail. Initial studies indicate that electric field poling is effective but that relaxation of polar order in the poly(norbornene) is faster than in a comparable methacrylate copolymer.

  DOI：

  10.1021/ma040044i

文献信息

• Methods for treatment of dermatological conditions
  申请人：Wang Bing

  公开号：US20050032751A1

  公开（公告）日：2005-02-10

  A method of reducing the appearance of skin conditions associated with loss of skin tightness, skin firmness, or dark circles under the eyes with topical compositions comprising compounds of any of the Formulae I or Ia as described herein, is disclosed.

  本文揭示了一种通过含有本文所述的任何Formulae I或Ia化合物的局部组合物来减少与皮肤松弛、皮肤紧致度或眼部黑眼圈相关的皮肤状况的方法。
• METHODS FOR TREATMENT OF DERMATOLOGICAL CONDITIONS
  申请人：Wang Bing

  公开号：US20100202989A1

  公开（公告）日：2010-08-12

  A method of reducing the appearance of skin conditions associated with loss of skin tightness, skin firmness, or dark circles under the eyes with topical compositions comprising compounds of any of the Formulae I or Ia as described herein, is disclosed.

  本发明揭示了一种使用含有任何公式I或Ia中所述化合物的局部组合物来减少与皮肤紧致度丧失、皮肤紧致度降低或眼部黑眼圈相关的皮肤状况的外观的方法。
• Acrylic copolymers exhibiting nonlinear optical response
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0312856A1

  公开（公告）日：1989-04-26

  This invention provides novel isotropic acrylic copolymers which exhibit nonlinear optical response, and which have utility as a transparent optical component in optical light switch and light modulator devices. An invention isotropic acrylic copolymer is illustrated by the following structure:

  本发明提供了新型各向同性丙烯酸共聚物，这种共聚物具有非线性光学响应，可用作光开关和光调制器装置中的透明光学元件。 本发明各向同性丙烯酸共聚物的结构如下：
• Copolymeric nonlinear optical media
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0378185A2

  公开（公告）日：1990-07-18

  In a preferred embodiment this invention provides a second order nonlinear optical film medium which consists of a thermoplastic copolymer which has a crystallographic molecular alignment, and a net dipolar molecular orientation normal to the film plane. The crystallographic molecular alignment is formed by axial mechanical stressing, and the dipolar molecular orientation is induced by an electric or magnetic field. Illustrative of an invention polymer is a copolymer of vinylidene fluoride and 4-[N-(10-methacroyloxydecyl)]-4′-­nitrostilbene:

  在一个优选的实施方案中，本发明提供了一种二阶非线性光学薄膜介质，该介质由热塑性共聚物组成，热塑性共聚物具有晶体学分子排列和法向薄膜平面的净偶极分子取向。结晶分子排列是通过轴向机械应力形成的，而偶极分子取向则是由电场或磁场诱导的。 本发明聚合物的示例是亚乙烯基氟化物和 4-[N-（10-甲酰氧基癸基）]-4′-硝基二苯乙烯的共聚物：
• Self-poled electro-optic and nonlinear optical polymer, method of manufacturing the polymer, and film manufactured from the polymer
  申请人：Park Koo Seung

  公开号：US20060131548A1

  公开（公告）日：2006-06-22

  A polyamic ester (PAE) film, which shows an electro-optic (EO) and nonlinear optical (NLO) properties without a poling process, is prepared. The chromophore in the film seems to be slightly oriented normally to the film surface (transverse magnetic field (TM) direction even though the polymer solution is spin-coated. This is due to the nano-configuration structure of PAE controlled by introducing a designed chemical structure into the monomeric repeating unit of PAE. Manufacturing the relating devices can be simplified by using the self-poled polymer film as a polymer waveguide. Additionally, the EO property of the film is thermodynamically stable.

  我们制备了一种聚氨基酯（PAE）薄膜，它无需极化过程即可显示出电光（EO）和非线性光学（NLO）特性。尽管聚合物溶液是旋涂的，但薄膜中的发色团似乎与薄膜表面（横向磁场 (TM) 方向）呈微妙的正常取向。这是由于 PAE 的单体重复单元中引入了设计的化学结构，从而控制了 PAE 的纳米配置结构。利用自极化聚合物薄膜作为聚合物波导，可以简化相关器件的制造。此外，薄膜的环氧乙烷特性在热力学上是稳定的。