Diphenyl-thiophosphinyl-amido-diphenyl-phosphinsaeure | 17162-83-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Diphenyl-thiophosphinyl-amido-diphenyl-phosphinsaeure
• 英文别名: Phosphinic amide, N-(diphenylphosphinothioyl)-P,P-diphenyl-；[(diphenylphosphinothioylamino)-phenylphosphoryl]benzene
• CAS: 17162-83-3
• 化学式: C₂₄H₂₁NOP₂S
• 分子量: 433.45
• InChiKey: OKHXMELHTQCGKS-UHFFFAOYSA-N

物化性质

• 沸点：
  573.9±33.0 °C(Predicted)
• 密度：
  1.28±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.2
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Diphenyl-thiophosphinyl-amido-diphenyl-phosphinsaeure 在 potassium tert-butylate 作用下， 以 乙醚 为溶剂， 反应 12.0h， 以95%的产率得到tetraphenylimidothioxodiphosphinic acid potassium salt
  参考文献：
  名称：

  Roesler, Roland; Drake, John E.; Silvestru, Cristian, Journal of the Chemical Society, Dalton Transactions, 1996, p. 391 - 400

  摘要：

  DOI：
• 作为产物：
  描述：

  (diphenylphosphinoamino)diphenylphosphine oxide 在 sulfur 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以96%的产率得到Diphenyl-thiophosphinyl-amido-diphenyl-phosphinsaeure
  参考文献：
  名称：

  Slawin, Alexandra M. Z.; Smith, Martin B.; Woollins, J. Derek, Journal of the Chemical Society, Dalton Transactions, 1996, # 18, p. 3659 - 3666

  摘要：

  DOI：

文献信息

• Towards Cationic Gallium Derivatives: Metallacycles from the Reactions of Organogallium Compounds with Tetraorganodichalcogenoimidodiphosphinates and a New <i>N</i> ‐(Diphenylthiophosphinyl)thioureato Ligand
  作者：Virginia Montiel‐Palma、Estefanía Huitrón‐Rattinger、Sara Cortés‐Llamas、Miguel‐Ángel Muñoz‐Hernández、Verónica García‐Montalvo、Eddie López‐Honorato、Cristian Silvestru

  DOI：10.1002/ejic.200400087

  日期：2004.9

  were obtained by facile methane elimination reactions from GaMe3 and the acidic ligands L1H [(XPPh2)2NH (X = O, S, Se), (OPPh2)(SPPh2)NH, and (OPMe2)(SPPh2)NH] and L2H [Ph2P(S)NHC(S)(C9H10N)] in toluene. Replacement of one phosphorus atom by a carbon atom in the ligand skeleton of L1H gave the new ligand L2H, which, upon reaction with GaMe3, gave compound 6, which shows no significant structural differences

  通式[Me2Gaη2-E,E'-[R2P(E)NP(E')R'2]}][R = R' = Ph, E = E' = O (1); R = R' = Ph, E = E' = S (2); R = R' = Ph, E = E' = Se (3); R = R' = Ph, E = O, E' = S (4); R = Me, R' = Ph, E = S, E' = O (5)] 和 [Me2Gaη2-S,S'-[Ph2P(S)NC(S)(C9H10N)]}] (6)通过从 GaMe3 和酸性配体 L1H [(XPPh2)2NH (X = O, S, Se)、(OPPh2)(SPPh2)NH 和 (OPMe2)(SPPh2)NH] 和 L2H [Ph2P (S)NHC(S)(C9H10N)]在甲苯中。L1H 的配体骨架中的一个磷原子被一个碳原子取代得到新的配体 L2H，它与 GaMe3
• Gold(0) and Gold( <scp>III</scp> ) Reactivity towards the Tetraphenyldithioimidodiphosphinic Acid, [Ph ₂ P(S)NHP(S)Ph ₂ ]
  作者：G. Luca Abbati、M. Carla Aragoni、Massimiliano Arca、M. Bonaria Carrea、Francesco A. Devillanova、Alessandra Garau、Francesco Isaia、Vito Lippolis、Marco Marcelli、Cristian Silvestru、Gaetano Verani

  DOI：10.1002/ejic.200400651

  日期：2005.2

  complex [Au(L)]2, to separate the neutral AuI complex [Au(L′2H)], L′ = [Ph2P(S)NP(O)Ph2]−, the crystal structure of which features a AuI ion linearly coordinated to two sulfur atoms and a proton bridging two oxygen atoms of the PO groups. 31P NMR CP MAS spectroscopy is in accordance with the nature of the ligands in the complex. The reaction chemistry of [Au(L′2H)] in CH2Cl2 towards the acid CF3COOH and

  金粉与 Ph2P(S)NHP(S)Ph2 (HL) 在 Et2O 中的碘加合物反应，在温和的反应条件下得到络合物 [Au(L)I2]。其晶体结构由离散的单体分子组成，中心的 AuIII 离子通过阴离子配体 L 和两个碘化物阴离子键合到两个硫原子上，呈略微扭曲的方形平面配位几何结构。从 [AuCl3(tht)] 与 HL 在 CH2Cl2 中的反应中，除了主要配合物 [Au(L)]2 之外，还可以分离出中性的 AuI 配合物 [Au(L'2H)]，L' = [Ph2P (S)NP(O)Ph2]-，其晶体结构的特点是一个 AuI 离子与两个硫原子线性配位，一个质子桥接 PO 基团的两个氧原子。31P NMR CP MAS 光谱与配合物中配体的性质一致。报道了 [Au(L'2H)] 在 CH2Cl2 中对酸 CF3COOH 和有机碱 1,8-双（二​​甲氨基）萘的反应化学。(© Wiley-VCH
• Reactivity of [Ru3(CO)12] towards (EPR2)()NH (R=Ph, Me; R′=Ph; E, E′=O, S, Se): 31P and 77Se NMR spectroscopic characterization and structural analysis of the complexes formed
  作者：Efrén V. García-Báez、M. Gabriela Ballinas-López、María J. Rosales-Hoz、Marco A. Leyva、Ionel Haiduc、Cristian Silvestru

  DOI：10.1016/j.poly.2009.08.026

  日期：2009.11

  [Ru3(CO)12] with the phosphorus chalcogenide ligands (EPR2)( E ′ PR 2 ′ )NH [E = E′ = S, R = Ph, R′ = Me (L1) and E = E′ = Se, R = R′ = Ph (L2)] produced the complexes [Ru3(μ2-H)(μ3-S)μ2-S,S,P′-(SPPh2)(PMe2)N}(CO)8] 1, [Ru3(μ2-H)(μ3-S)μ2-S,S,P′-(SPMe2)(PPh2)N}(CO)8] 2, [Ru3(μ3-S)2μ2-P,P′-(Ph2P)(PMe2)NH}(CO)7] 3, [Ru4(μ4-S)2μ2-P,P′-(Ph2P)(PMe2)NH}(CO)8(μ2-CO)] 4, [Ru3(μ2-H)(μ3-Se)μ2-Se,Se,P′-(S

  摘要[Ru3（CO）12]与硫族磷配体（EPR2）（E'PR 2'）NH [E = E'= S，R = Ph，R'= Me（L1）和E = E ''= Se，R = R'= Ph（L2）]生成络合物[Ru3（μ2-H）（μ3-S）μ2-S，S，P'-（SPPh2）（PMe2）N}（CO） 8] 1，[Ru3（μ2-H）（μ3-S）μ2-S，S，P'-（SPMe2）（PPh2）N}（CO）8] 2，[Ru3（μ3-S）2 μ2-P，P′-（Ph2P）（PMe2）NH}（CO）7] 3，[Ru4（μ4-S）2 μ2-P，P′-（Ph2P）（PMe2）NH}（CO）8 （μ2-CO）] 4，[Ru3（μ2-H）（μ3-Se）μ2-Se，Se，P'-（SePPh2）（PPh2）N}（CO）8]，5，[Ru3（μ3 -Se）2 μ2-P，P′-（PPh2）2NH}（CO）7] 6和[Ru4（μ4-Se）2
• Tetrahedral Co ^II Complexes with CoI ₂ O ₂ and CoO ₂ S ₂ Cores – Crystal Structures of [Co{HN(OPPh ₂ )(SPPh ₂ )‐ <i>O</i> } ₂ I ₂ ] and [Co{N(OPPh ₂ )(SPPh ₂ )‐ <i>O</i> , <i>S</i> } ₂ ]
  作者：M. Carla Aragoni、Massimiliano Arca、M. Bonaria Carrea、Alessandra Garau、Francesco A. Devillanova、Francesco Isaia、Vito Lippolis、Gian Luca Abbati、Francesco Demartin、Cristian Silvestru、Serhiy Demeshko、Franc Meyer

  DOI：10.1002/ejic.200700441

  日期：2007.10

  12.0 cm–1 and g = 2.37, |D| = 11.9 cm–1 for complexes 1 and 2, respectively. The compounds were further characterised by UV/Vis and IR spectroscopy. DFT calculations were performed on model complexes [CoIIN(OPH2)(SPH2)-O,S}2] (3) and [CoIIN(SPH2)2-S,S′}2] (4) to compare the electronic properties of the CoO2S2 and CoS4 cores. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

  化合物 [CoIIHN(OPPh2)(SPPh2)-O}2I2] (1) 是通过粉末中的钴与四苯基硫代亚胺二次膦酸的碘加合物 HN(OPPh2)(SPPh2) 在 Et2O 中反应合成的；用 NaOH 处理化合物 1 导致与金属离子结合的配体去质子化并分离 [CoIIN(OPPh2)(SPPh2)-O,S}2] (2)。通过 X 射线衍射分析阐明了配合物 1 和 2 的分子结构，其揭示了化合物 1 的 CoI2O2 四面体核心，其中两个中性配体通过 CoII 离子的氧原子结合，而化合物 2 的四面体 CoO2S2 核心与氧结合每个阴离子配体的硫原子螯合一个 CoII 中心。变温磁化率测量结果与四面体高自旋 (S = 3/2) CoII 一致，其具有 4A2 基态，最佳拟合参数 g = 2.25，|D| = 12.0 cm–1 和 g = 2.37，|D| = 11.9 cm–1 对于复合物
• P–N–S/Se-containing metallacycles
  作者：J. Derek Woollins

  DOI：10.1039/dt9960002893

  日期：——

  Metal complexes containing only Group 15 and 16 elements in the chelate rings are studied extensively in M-S-N chemistry. Recently M-E-P-N type systems are starting to reveal interesting conformational and structural properties;. examples of syntheses and structures are provided. The cover shows the crystal structures (DIAMOND drawings) of [M(Pr2P)-P-1(S)NP(S)Pr-2(1)}(2)] (M = Pd or Pt) illustrating the surprising conformational change effected by replacing a palladium by a platinum centre.