| 105011-36-7

• 分子结构分类: 有机化合物
• CAS: 105011-36-7
• 化学式: C₁₀H₁₂MoN₂O₄S₂
• 分子量: 384.288
• InChiKey: JCTJZQRIOHRGGH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 thioglycolic acid 作用下， 以 甲醇 为溶剂， 以65%的产率得到oxomolybdenum(IV) 1-((methylthio)carbonothioyl)-2-(2-oxidobenzylidene)hydrazin-1-ide
  参考文献：
  名称：

  Reactivity of Mo−O_t Terminal Bonds toward Substrates Having Simultaneous Proton- and Electron-Donor Properties:  A Rudimentary Functional Model for Oxotransferase Molybdenum Enzymes

  摘要：

  In order to study the reactivity pattern of Mo-O-t bonds associated with anionic sulfur ligands, precursor complexes MoO2L . D (H2L = S-methyl 3-(2-hydroxyphenyl)methylenedithiocarbazate; DCH3OH (1), H2O (2)) were synthesized. Complex 2 crystallizes in the orthorhombic space group P2(1)2(1)2(1), With a = 6.079(1) Angstrom, b = 11.638-(2) Angstrom, c = 17.325(2) Angstrom, V = 1225.7(4) Angstrom(3) and Z = 4. In its reaction with PhNHOH, 1 forms a seven-coordinate oxaziridine compound [MoO(eta(2)-ONPh)L . CH3OH] (3) by ore-rearrangement (elimination-substitution) without a change in the molybdenum oxidation state. The crystal data for 3 are a = 9.573(3) Angstrom, b = 9.859(2) Angstrom, c = 10.604(3) Angstrom, alpha = 95.90(2)degrees, beta = 95.81(2)degrees, gamma = 112.12(2)degrees, V = 911.5(4) Angstrom(3), Z = 2, and triclinic space group . In contrast to that of the precursor compound 1 (Mo-O-t 1.700(4) Angstrom), the terminal Mo-O-t distance in 3 (1.668(2) Angstrom) is typical of Mo-O bonds of order 3, which drives the formation of an apparently unstable three-membered metallacycle via spectator oxo stabilization (Rappe, A. K.; Goddard, W. A., III. J. Am. Chem, Sec. 1982, 104, 448). With thioglycolic acid, 1 undergoes an oxo-transfer reaction through a coupled electron-proton transfer mechanism involving two steps, each having first-order dependence on H(2)tga concentration. The system offers an interesting reactivity model for the ore-transfer pathway of oxidoreductase Mo enzymes.

  DOI：

  10.1021/ic960670z
• 作为产物：
  描述：

  甲醇 、 bis(acetylacetonato)dioxomolybdenum(VI) 、 S-methyl-β-N-(2-hydroxyphenylmethylene)dithiocarbazate 以 甲醇 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Reactivity of Mo−O_t Terminal Bonds toward Substrates Having Simultaneous Proton- and Electron-Donor Properties:  A Rudimentary Functional Model for Oxotransferase Molybdenum Enzymes

  摘要：

  In order to study the reactivity pattern of Mo-O-t bonds associated with anionic sulfur ligands, precursor complexes MoO2L . D (H2L = S-methyl 3-(2-hydroxyphenyl)methylenedithiocarbazate; DCH3OH (1), H2O (2)) were synthesized. Complex 2 crystallizes in the orthorhombic space group P2(1)2(1)2(1), With a = 6.079(1) Angstrom, b = 11.638-(2) Angstrom, c = 17.325(2) Angstrom, V = 1225.7(4) Angstrom(3) and Z = 4. In its reaction with PhNHOH, 1 forms a seven-coordinate oxaziridine compound [MoO(eta(2)-ONPh)L . CH3OH] (3) by ore-rearrangement (elimination-substitution) without a change in the molybdenum oxidation state. The crystal data for 3 are a = 9.573(3) Angstrom, b = 9.859(2) Angstrom, c = 10.604(3) Angstrom, alpha = 95.90(2)degrees, beta = 95.81(2)degrees, gamma = 112.12(2)degrees, V = 911.5(4) Angstrom(3), Z = 2, and triclinic space group . In contrast to that of the precursor compound 1 (Mo-O-t 1.700(4) Angstrom), the terminal Mo-O-t distance in 3 (1.668(2) Angstrom) is typical of Mo-O bonds of order 3, which drives the formation of an apparently unstable three-membered metallacycle via spectator oxo stabilization (Rappe, A. K.; Goddard, W. A., III. J. Am. Chem, Sec. 1982, 104, 448). With thioglycolic acid, 1 undergoes an oxo-transfer reaction through a coupled electron-proton transfer mechanism involving two steps, each having first-order dependence on H(2)tga concentration. The system offers an interesting reactivity model for the ore-transfer pathway of oxidoreductase Mo enzymes.

  DOI：

  10.1021/ic960670z