vinyl 2-methylpentanoate | 17361-48-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: vinyl 2-methylpentanoate
• 英文别名: 2-methyl-valeric acid vinyl ester；2-Methyl-valeriansaeure-vinylester；Ethenyl 2-methylpentanoate
• CAS: 17361-48-7
• 化学式: C₈H₁₄O₂
• 分子量: 142.198
• InChiKey: ZAPBLOWGJNQWBJ-UHFFFAOYSA-N

物化性质

• 沸点：
  162.5±9.0 °C(Predicted)
• 密度：
  0.891±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  vinyl 2-methylpentanoate 、 1H,1H,9H-十六氟-1-壬醇 在 磷脂酶B 作用下， 以 正己烷 为溶剂， 反应 44.0h， 生成 vinyl 2-methylpentanoate 、 vinyl 2-methylpentanoate 、 、
  参考文献：
  名称：

  Enantiomeric partitioning using fluorous biphase methodology for lipase-mediated (trans)esterifications

  摘要：

  在均质全氟碳氢化合物溶剂中进行脂肪酶催化的（反式）酯化反应，可通过液-液分离对产物进行直接对映体分配（ee高达95%）。

  DOI：

  10.1039/b204607p

文献信息

• ORGANIC COMPOUND, THREE-DIMENSIONAL ORGANIC FRAMEWORK FORMED BY USING ORGANIC COMPOUND, SEPARATION SIEVE AND OPTICAL LAYER, WHICH COMPRISE ORGANIC FRAMEWORK, AND OPTICAL DEVICE COMPRISING OPTICAL LAYER AS OPTICAL AMPLIFICATION LAYER
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US20190031586A1

  公开（公告）日：2019-01-31

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  提供一种有机化合物，通过使用该有机化合物形成的三维有机结构、分离筛和具有该有机结构的光学层，以及具有光学层作为光学放大层的光学器件。该有机结构包括通过非共价键自组装的多个有机分子。每个单元有机分子具有芳香环，第一对取代基连接到芳香环的可取代位置的相邻位置，第二对取代基连接到芳香环的剩余可取代位置的相邻位置。单元有机分子通过范德华力相互作用、伦敦分散相互作用或氢键作用于第一和第二对取代基之间的π-π相互作用而自组装。
• Organic compound, three-dimensional organic framework formed by using organic compound, separation sieve and optical layer, which comprise organic framework, and optical device comprising optical layer as optical amplification layer
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US11066351B2

  公开（公告）日：2021-07-20

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  本文提供了一种有机化合物、利用该有机化合物形成的三维有机结构、具有该有机结构的分离筛和光学层，以及具有该光学层作为光放大层的光学设备。有机结构包括多个通过非共价键自组装的有机分子。每个单元有机分子都有一个芳香环，第一对取代基连接到芳香环可取代位置的紧邻位置，第二对取代基连接到芳香环其余可取代位置的紧邻位置。通过第一对和第二对取代基之间的范德华相互作用、伦敦色散相互作用或氢键作用，以及芳香环之间的π-π相互作用，单元有机分子得以自组装。
• Liquid electrostatic ink composition
  申请人：HP Indigo B.V.

  公开号：US11442373B2

  公开（公告）日：2022-09-13

  An electrostatic ink composition comprising a carrier liquid; a first resin comprising a copolymer of an alkylene monomer and a methacrylic acid monomer; and a second resin comprising a copolymer of an alkylene monomer and an acrylic acid monomer, wherein the second resin constitutes at least 35 wt. % of the total amount of resin is disclosed.

  本发明公开了一种静电油墨组合物，该组合物包括载液、第一树脂（由亚烷基单体和甲基丙烯酸单体的共聚物组成）和第二树脂（由亚烷基单体和丙烯酸单体的共聚物组成），其中第二树脂至少占树脂总量的 35%。
• Transvinylation process by reactive distillation
  申请人：UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

  公开号：EP0497340B1

  公开（公告）日：1995-11-22
• CLEANING PROCESS AND APPARATUS
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0813590A1

  公开（公告）日：1997-12-29