4,4'-bismaleimidodicyclohexylmethane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: 4,4'-bismaleimidodicyclohexylmethane
• 英文别名: 1-[4-[[4-(2,5-Dioxopyrrol-1-yl)cyclohexyl]methyl]cyclohexyl]pyrrole-2,5-dione
• 化学式: C₂₁H₂₆N₂O₄
• 分子量: 370.448
• InChiKey: LIRFWAADGFIXIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  27
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  马来酸酐 、 4,4'-二氨基二环己基甲烷 在 硫酸 、 copper dibutyldithiocarbamate 、 三乙胺 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 8.0h， 生成 4,4'-bismaleimidodicyclohexylmethane
  参考文献：
  名称：

  JP6273389

  摘要：

  公开号：

文献信息

• [EN] POLY(ALLYL ETHER)S OF POLYCYCLOPENTADIENE POLYPHENOL<br/>[FR] POLY(ALLYL ÉTHERS) DE POLYCYCLOPENTADIÈNE POLYPHÉNOL
  申请人：DOW GLOBAL TECHNOLOGIES LLC

  公开号：WO2011136847A1

  公开（公告）日：2011-11-03

  Embodiments include poly(allyl ether)s of polycyclopentadiene polyphenol that can be obtained by allylation of a polycyclopentadiene polyphenol, where the aromatic hydroxyl group(s) (-OH) are converted to HR1C=CR1-CH2-0- and/or H2R1C-CR1=HC-0-, where R1 is as described herein. Embodiments also include thermosettable compositions including the poly(allyl ether)s of polycyclopentadiene polyphenol and products obtained by curing the thermosettable compositions.

  实施例包括聚环戊二烯多酚的聚烯丙醚，其可通过多环戊二烯多酚的烯丙基化获得，其中芳香羟基(-OH)被转化为HR1C=CR1-CH2-0-和/或H2R1C-CR1=HC-0-，其中R1如本文所述。实施例还包括包括聚环戊二烯多酚聚烯丙醚的热固性组合物和通过固化热固性组合物获得的产品。
• [EN] VINYLBENZYL ETHERS OF POLYCYCLOPENTADIENE POLYPHENOL<br/>[FR] VINYLBENZYL ÉTHERS DE POLYCYCLOPENTADIÈNE POLYPHÉNOL
  申请人：DOW GLOBAL TECHNOLOGIES LLC

  公开号：WO2011136845A1

  公开（公告）日：2011-11-03

  Embodiments include vinylbenzyl ethers of polycyclopentadiene polyphenol that can be obtained by reacting a polycyclopentadiene polyphenol with a vinylbenzyl halide. Embodiments also include thermosettable compositions including the vinylbenzyl ethers of a polycyclopentadiene polyphenol and products obtained by curing the thermosettable compositions. Formula (I).

  实施例包括通过将多环戊二烯多酚与乙烯基苯基卤化物反应得到的多环戊二烯多酚乙烯基醚。实施例还包括包括多环戊二烯多酚乙烯基醚的热固性组合物和通过固化热固性组合物获得的产品。公式（I）。
• Curable Bisimide Resin Mixtures
  申请人：Technochemie GmbH - Verfahrenstechnik

  公开号：EP0141612A2

  公开（公告）日：1985-05-15

  1) Curable bisimide resins comprise a mixture of a) 5 to 95% of at least one bisimide of the general formula I in which 8 represents a divalent radical containing a carbon-carbon double bond and A is a divalent radical containing at least two carbon atoms and b) 95 to 5% of a polyhydantoin polymer of formula II wherein R1 represents an aromatic hydrocarbon radical, R2 represents hydrogen or an alkyl group having 1 to 6 carbon atoms, R3 represents an aromatic hydrocarbon radical, an alkyl radical having 4 to 10 carbon atoms optionally interrupted by one or more oxygen or sulphur atoms.

  1) 可固化双亚胺树脂由以下混合物组成 a) 5%至 95%的至少一种通式 I 的双亚胺 其中 8 代表含有碳碳双键的二价基，A 是至少含有两个碳原子的二价基，以及 b) 95%至 5%的式 II 的聚海因聚合物 其中 R1 代表芳香烃基，R2 代表氢或具有 1 至 6 个碳原子的烷基，R3 代表芳香烃基，具有 4 至 10 个碳原子的烷基，可选择被一个或多个氧原子或硫原子打断。
• Thermosetting imide resin compositions
  申请人：Secretary of State for Defence in Her Britannic Majesty's Gov. of the United Kingdom of Great Britain and Northern Ireland

  公开号：EP0165812A2

  公开（公告）日：1985-12-27

  A novel method for preparing a thermosetting imide resin composition which consists of chemically reacting a liquid mixture of a vinylidene -terminated polybutadiene/ acrylonitrile (VTBN) and a co-reactant comprising a. at least one N,N'-bisimide of an unsaturated carboxylic acid of general formula I wherein B represents a divalent radical containing a carbon-carbon double bond and A represents a divalent radical having at least two carbon atoms, or b. the amide resin reaction product of at least one N,N'-bisimide of general formula I and at least one primary organic diamine or organic hydrazide, or c. the imide resin reaction product of at least one N,N'-bisimide of general formula I, at least one monoimide, and at least one organic hydrazide, to yield a thermosetting imide resin composition containing copolymerised VTBN and co-reactant. A resin composition prepared by this method may be cured at a temperature between 100°C and 350°C to yield a fully cross-linked polyimide matrix containing a dispersion of phase-separated solid particles of copolymerised VTBN and co-reactant.

  一种制备热固性酰亚胺树脂组合物的新方法，包括使一种以乙烯基为端基的聚丁二烯/丙烯腈（VTBN）和一种共反应物的液体混合物发生化学反应，该共反应物包括 a. 至少一种通式 I 的不饱和羧酸的 N,N'-二亚胺 其中 B 代表含有碳碳双键的二价基，A 代表至少含有两个碳原子的二价基，或 b. 至少一种通式 I 的 N,N'-二亚胺与至少一种伯氨基有机二胺或有机酰肼的酰胺 树脂反应产物，或 c. 至少一种通式 I 的 N,N'-二亚胺、至少一种单亚胺和至少一种有机酰肼的亚胺树脂反应产物、 生成含有共聚 VTBN 和共反应物的热固性亚胺树脂组合物。用这种方法制备的树脂组合物可在 100°C 至 350°C 的温度下固化，以产生完全交联的聚酰亚胺基体，其中含有共聚 VTBN 和共反应物的相分离固体颗粒的分散体。
• Process for the preparation of heterocyclic styryl compounds and reaction products
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0240011A2

  公开（公告）日：1987-10-07

  Heterocyclic compounds having the formula where R is hydrogen. methyl or ethyl R, independently in each occurrence is hydrogen, alkyl group of 1-4 carbons, and -C(R):CH-Q n is a number having an average value from 0 to 5 Q has the formula Z is = 0, = S, or = N-R2 R is selected from hydrogen, alkyl, aryl, alkaryl, and aralkyl is a monocyclic or bicyclic heterocyclic ring selected from the group consisting of pyridine, pyrazine, pyridazine, pyrimidine, quinoline, isoquinoline, quinoxaline, quinazoline and phthalazine x is 1 to 3 with the proviso that when n is zero, the heterocyclic ring has at least two -C(R):CH-Q groups are prepared by condensing nitrogen heterocyclic compounds such as trimethyl pyridine with dialdehydes and heterocyclic aldehydes such as furfural. These can be further reacted and chain extended with bismaleimides or polymaleimides. The compounds and their reaction products are useful to make heat resistant composites with various fibers such as graphite fibers.

  具有以下式子的杂环化合物 其中 R 为氢、甲基或乙基 每次独立出现的 R 分别为氢、1-4 个碳原子的烷基和-C(R):CH-Q n 是一个平均值为 0 至 5 的数字 Q 的式子为 Z 是＝0、＝S 或＝N-R2 R 选自氢、烷基、芳基、烷芳基和芳烷基 是单环或双环杂环，选自由吡啶、吡嗪、哒嗪、嘧啶、喹啉、异喹啉、喹喔啉、喹唑啉和酞嗪组成的组 x 为 1 至 3 但当 n 为零时，杂环至少有两个 -C(R):CH-Q 基团 通过将含氮杂环化合物（如三甲基吡啶）与二醛和杂环醛（如糠醛）缩合制备。这些化合物可与双马来酰亚胺或聚马来酰亚胺进一步反应和扩链。这些化合物及其反应产物可与各种纤维（如石墨纤维）制成耐热复合材料。