2,3,5,6-Tetrafluorobenzene, (difluoromethylthio)-

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2,3,5,6-Tetrafluorobenzene, (difluoromethylthio)-
• 英文别名: 3-(difluoromethylsulfanyl)-1,2,4,5-tetrafluorobenzene
• 化学式: C₇H₂F₆S
• 分子量: 232.149
• InChiKey: HJVMMUFUTZDDEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  2,3,5,6-Tetrafluorobenzene, (difluoromethylthio)- 在 硝酸 作用下， 反应 20.0h， 生成 1-[(difluoromethyl)sulfinyl]-2,3,5,6-tetrafluorobenzene
  参考文献：
  名称：

  Organofluorine sulfur-containing compounds

  摘要：

  Polyfluorinated aryldifluoromethyl sulfides have been obtained by treatment of polyfluorinated 4-X-substituted thiophenols with chlorodifluoromethane in an alkaline medium. Reactions of difluoromethylpentafluorophenyl sulfide with H2O2, KMnO4, and HNO3, giving the corresponding sulfoxide and sulfone, were studied.

  DOI：

  10.1007/bf01433751
• 作为产物：
  描述：

  氟里昂-22 、 2,3,5,6-四氟苯硫酚 在 sodium hydroxide 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 2.2h， 以92%的产率得到2,3,5,6-Tetrafluorobenzene, (difluoromethylthio)-
  参考文献：
  名称：

  Organofluorine sulfur-containing compounds

  摘要：

  Polyfluorinated aryldifluoromethyl sulfides have been obtained by treatment of polyfluorinated 4-X-substituted thiophenols with chlorodifluoromethane in an alkaline medium. Reactions of difluoromethylpentafluorophenyl sulfide with H2O2, KMnO4, and HNO3, giving the corresponding sulfoxide and sulfone, were studied.

  DOI：

  10.1007/bf01433751

文献信息

• 10.1016/j.mencom.2024.06.021
  作者：Koshcheev, Borislav V.、Maksimov, Alexander M.、Andreev, Rodion V.

  DOI：10.1016/j.mencom.2024.06.021

  日期：——
• Organofluorine sulfur-containing compounds
  作者：A. M. Maksimov、V. V. Kireenkov、V. E. Platonov

  DOI：10.1007/bf01433751

  日期：1996.1

  Polyfluorinated aryldifluoromethyl sulfides have been obtained by treatment of polyfluorinated 4-X-substituted thiophenols with chlorodifluoromethane in an alkaline medium. Reactions of difluoromethylpentafluorophenyl sulfide with H2O2, KMnO4, and HNO3, giving the corresponding sulfoxide and sulfone, were studied.