benzohydroximoyl azide | 6914-23-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzohydroximoyl azide
• 英文别名: Benzazidoxim；Phenylazidoxim-= Benzhydroximsaeureazid；Phenylazidoxim；N-hydroxy-benzimidoyl azide；Benzohydroximoylazid；N-hydroxybenzenecarboximidoyl azide
• CAS: 6914-23-4
• 化学式: C₇H₆N₄O
• 分子量: 162.151
• InChiKey: YCMRJQCZSPZHHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  benzohydroximoyl azide 在 盐酸 作用下， 以 乙醚 为溶剂， 生成 Acetic acid 5-phenyl-tetrazol-1-yl ester
  参考文献：
  名称：

  摘要：

  Chlorination of 1-hydroxyiminopentane gave 1-chloro-1-nitrosopentane which reacted with sodium azide in DMF to form pentanohydroximoyl azide. The azidation of benzohydroximoyl chlorides was always accompanied by decomposition to benzonitriles. Treatment of carbohydroximoyl azides in ether with gaseous hydrogen chloride afforded 5-butyl- and 5-aryl-1-hydroxytetrazoles which reacted with acetic anhydride to form the corresponding acetates.

  DOI：

  10.1023/a:1012453012799
• 作为产物：
  描述：

  苯甲醛肟 在 盐酸 、 N-氯代丁二酰亚胺 、 sodium azide 作用下， 以 水 、 乙腈 、 苯 为溶剂， 反应 48.5h， 生成 benzohydroximoyl azide
  参考文献：
  名称：

  1-Benzyloxy-5-phenyltetrazole derivatives highly active against androgen receptor-dependent prostate cancer cells

  摘要：

  DOI：

  10.1016/j.ejmech.2022.114982

文献信息

• Montmorillonite clay Cu(II) catalyzed domino one-pot multicomponent synthesis of 3,5-disubstituted isoxazoles
  作者：Sandip B. Bharate、Anil K. Padala、Bashir A. Dar、Rammohan R. Yadav、Baldev Singh、Ram A. Vishwakarma

  DOI：10.1016/j.tetlet.2013.04.102

  日期：2013.7

  corresponding aldehydes and terminal alkynes using recyclable montmorillonite clay supported Cu(II)/NaN3 catalytic system under aqueous conditions have been developed. The ‘domino’ one-pot MCR approach involves hydroxyamination of aldehydes followed by chlorination and then generation of reactive ‘nitrile oxide’ which undergoes 1,3-dipolar cycloaddition with alkynes to produce 3,5-disubstituted isoxazoles

  已经开发了一种简单有效的单锅多组分方法，该方法使用可回收的蒙脱石粘土负载的Cu（II）/ NaN 3催化体系，在水性条件下直接从相应的醛和末端炔烃直接合成3,5-二取代的异恶唑。“多米诺”一锅式MCR方法涉及醛的羟基胺化，然后氯化，然后生成反应性“腈”，该炔与炔烃进行1,3-偶极环加成反应，生成3,5-二取代异恶唑。该方法操作简单，区域选择性，经济，并且具有出色的官能团相容性，可以高收率合成结构多样的异恶唑。
• A general route to pentaco-ordinate amino(oxy)- and diamino(oxy)-phosphoranes from azido-compounds and phosphorus(III) reagents
  作者：J. I. G. Cadogan、Ian Gosney、Elizabeth Henry、Thomas Naisby、Barry Nay、Nevin J. Stewart、Neil J. Tweddle

  DOI：10.1039/c39790000189

  日期：——

  Bifunctional azido-compounds such as benzohydroximic azide, α-azidobenzaldehyde 2,4-dibromophenylhydrazone, trans-1-azido-2-hydroxycyclohexane, 2-azido-1-phenylethanol, 2-azidobenzyl alcohol, o-azidoaniline, and α-azidoacetophenones react with a variety of phosphorus(III) reagents to give pentaco-ordinate amino-(oxy)- and diamino(oxy)-phosphoranes.

  双功能叠氮基化合物如苯并氢叠氮化物，α-叠氮基苯甲醛2,4-二溴苯基hydr，反式-1-叠氮基-2-羟基环己烷，2-叠氮基-1-苯基乙醇，2-叠氮基苄醇，邻叠氮基苯胺和α-叠氮基苯乙酮反应与多种磷（III）试剂一起生成五位配位的氨基-（氧基）-和二氨基（氧基）-膦酸酯。
• Notes. Evidence on the Existance of Azidoximes.
  作者：F Eloy

  DOI：10.1021/jo01062a612

  日期：1961.3
• POWER CABLE OF ALUMINIUM COATED WITH A TETRAZOLE COMPOUND CORROSION INHIBITOR
  申请人：Prysmian S.p.A.

  公开号：EP3353334B1

  公开（公告）日：2020-09-23
• POWER CABLE COMPRISING AN ALUMINIUM CORROSION INHIBITOR
  申请人：PRYSMIAN S.p.A.

  公开号：US20180254123A1

  公开（公告）日：2018-09-06

  The present invention relates to a power cable comprising a metallic electric conductor surrounded by one or more semiconductive layer and one or more insulating layer, said cable having at least one metallic element made of aluminium, wherein a corrosion inhibitor is provided in direct contact with said at least one metallic element made of aluminium, and wherein said corrosion inhibitor is a corrosion inhibitor of formula (I).