碘三(4-甲基苯基)锡烷 | 41269-16-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 碘三(4-甲基苯基)锡烷
• 英文名称: Sn(C6H4Me-p)I
• 英文别名: tris(p-tolyl)tin iodide；tris(4-methylphenyl)tin(IV) iodide；tri-p-tolyl tin (1+); iodide；Tri-p-tolyl-zinn(1+); Jodid；Tris(4-methylphenyl)stannanylium;iodide
• CAS: 41269-16-3
• 化学式: C₂₁H₂₁ISn
• 分子量: 519.012
• InChiKey: CAEZKECCFAQNTQ-UHFFFAOYSA-M

物化性质

• 沸点：
  471.1±55.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.01
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  碘三(4-甲基苯基)锡烷 以20%的产率得到
  参考文献：
  名称：

  BHATTACHARYA S. N.; PREM RAJ; SAXENA A. K., INDIAN J. CHEM., 1978, A16, NO 12, 1071-1074

  摘要：

  DOI：
• 作为产物：
  描述：

  对甲苯基氯化汞 在 Na-Sn alloy 、 I₂ 作用下， 以 氯仿 为溶剂， 生成 碘三(4-甲基苯基)锡烷
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.4, page 165 - 168

  摘要：

  DOI：

文献信息

• Isostructural or not? Adducts of some aryltin halides with (<i>E</i>)-1,2-bis(4-pyridyl)ethene
  作者：Stanley A. Bajue、Choy Lewis、Karen Clarke、Fitzgerald B. Bramwell、Brian O. Patrick、Carolyn Pratt Brock

  DOI：10.1107/s0108270102023600

  日期：2003.6.15

  The title complexes [mu-(E)-4,4'-(ethene-1,2-diyl)dipyridine-kappa(2)N:N']bis[halotris(4-methylphenyl)tin(IV)], [Sn(2)(C(7)H(7))(6)X(2)(C(12)H(10)N(2))], where halo is chloro (X = Cl) and bromo (X = Br) are isostructural. In both crystals, the molecules lie on inversion centers, and there are voids of ca 80 A(3) that could, but apparently do not, accommodate water molecules. The corresponding iodo

  标题配合物[mu-（E）-4,4'-（乙烯-1,2-二基）二吡啶-kappa（2）N：N']双[卤代（4-甲基苯基）锡（IV）]，[ Sn（2）（C（7）H（7））（6）X（2）（C（12）H（10）N（2））]，其中卤素是氯（X = Cl）和溴（X = Br）是同构的。在两个晶体中，分子都位于反转中心，并且存在大约80 A（3）的空隙，这些空隙可能但显然不能容纳水分子。相应的碘结构（X = I）与其他两种化合物几乎相同，但不完全相同。当Br更改为I时，c轴的长度减少超过1 A，并且空隙不再足够大以容纳任何溶剂分子。相关复合物[mu-（E）-4,4'-（乙烯-1,2-二基）二吡啶-kappa（2）N：N']双[氯三苯基锡（IV）]，[Sn（2）（C （6）H（5））（6）Cl（2）（C（12）H（10）N（2））]结晶成相关结构，但是分子位于一般位置而不是特殊位置。四种配合物的分子结构是相
• Sulphur-substituted organometallic compounds. Part IV. Reactions of p-tolylthiomethyltriphenyltin with electrophilic reagents and oxidants. Comparison of reactions of the oxygen, selenium, and germanium analogues
  作者：Robin D. Taylor、James L. Wardell

  DOI：10.1039/dt9760001345

  日期：——

  and (iv) all reactions of HgCl2 give only Sn–Ph bond cleavage. In contrast, the reactionsof SnPh3(CH2SC6H4Me-p) with Etl and Na[IO4] each lead to SnPh3(CH2I). While attempts to prepare the tin sulphoxlde, Ph3SnCH2S(o)C6H4Me-p, have failed, the germanium analogue has been prepared using Br2, in aqueous methanol as the oxidant. The effect on the halogen reactions of changing the aryl groups (R) in SnR3(CH2SR)

  SnPh的反应3（CH 2 ZC 6 ħ 4 ME- p）（Z = O，S和Se）被Br 2，我2，的HgCl 2，和通常PhSCl给SnPh和Sn-CH 2键断裂。得出以下结论：（i）SnPh 3（CH 2 OC 6 H 4 Me- p）的所有反应仅导致Sn-Ph裂解：（ii）PhSCl反应中未发生Sn-Ph键裂解；（iii）卤素在与硫和硒化合物反应时会同时发生两种裂解：和（iv）HgCl 2的所有反应仅给出Sn-Ph键的裂解。与此相反，reactionsof SnPh 3（CH 2 SC 6 H ^ 4 ME- p）与ETL和Na [IO 4 ]分别通往SnPh 3（CH 2 I）。而尝试制备锡sulphoxlde中，Ph 3 SNCH 2 S（O）C 6 H ^ 4 ME- p，都失败了，锗类似物已使用溴制备2，在甲醇水溶液作为氧化剂。改变SnR 3（CH 2SR）已经简要的研究，作为具有GePh的反应3-
• Some Reactions of Tetra-para-tolyltin
  作者：R. W. Bost、H. R. Baker

  DOI：10.1021/ja01330a040

  日期：1933.3
• Synthesis and reactions of the carbene complexes [M(SnPh₃)(CO)₂{C(OEt)Ph}L](M = Mo or W; L =η-C₅H₅,η-C₅Me₅or indenyl), [M(SnPh₃)(CO)₂{C(OEt)Me}(η-C₅H₅)](M = Mo or W) and [MI(CO)₂{C(OEt)R}(η-C₅H₅)](M = Mo or W, R = Me or Ph). X-Ray crystal structures of [Mo(SnPh₃)(CO)₂{C(OEt)Ph}(η-C₅Me₅)] and [WI(CO)₂{C(OEt)Ph}(η-C₅H₅)]
  作者：Harry Adams、Neil A. Bailey、Gary W. Bentley、Gordon Hough、Mark J. Winter、Simon Woodward

  DOI：10.1039/dt9910000749

  日期：——

  Treatment of the tricarbonyls [M(SnPh3)(CO)3L] [M = Mo or W; L = eta-C5H5, eta-C5Me5 or eta-5-C9H7-(indenyl)] with LiPh followed by [OEt3][BF4] results in the formation of the carbenes [M(SnPh3)-(CO)2 = C(OEt)Ph}L] in good to high yields. Related reactions of [M(SnPh3)(CO)3(eta-C5H5)] but using LiMe afford [M(SnPh3)(CO)2= C(OEt)Me}(eta-C5H5)]. The complex trans-[M(SnPh3)(CO)2= C-(OEt)Ph}(eta-C5Me5)] is monoclinic, a = 14.611(36), b = 16.788(20), c = 16.183(30) angstrom, beta = 96.08(18)-degrees, and R = 0.0888 for 2117 independent reflections. While the eta-C5H5 and indenyl complexes exist as pairs of isomers in solution generated by rotation about the M = C(carbene) bond, the eta-C5Me5 complexes exist as single isomers in solution. Treatment of [M(SnPh3)(CO)2= C(OEt)Ph}(eta-C5H5)] (M = Mo or W) with I2 results in formation of the iodometal species [MI(CO)2= C(OEt)Ph}(eta-C5H5)]. The complex [WI(CO)2= C(OEt)Ph}(eta-C5H5)] is monoclinic, a = 9.34(3), b = 13.00(2), c = 13.53(3) angstrom, beta = 97.8(2)-degrees, and R = 0.0812 for 2091 independent reflections. In solution this compound exists as three trans isomers and one cis. Treatment of [M(SnPh3)(CO)2= C(OEt)Ph}(eta-C5Me5)] with I2 results in the eventual formation of [MoPh(CO)3(eta-C5Me5)] in the molybdenum case and [MI3-(CO)2(eta-C5Me5)] in both cases.
• Hydrogenolyses of Aromatic Halides with Triaryltin Hydrides¹
  作者：Donald H. Lorenz、Philip Shapiro、Alfred Stern、Ernest I. Becker

  DOI：10.1021/jo01044a042

  日期：1963.9