[(1E,3E)-4-chlorobuta-1,3-dien-1-yl]benzene | 18685-02-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(1E,3E)-4-chlorobuta-1,3-dien-1-yl]benzene
• 英文别名: 1-[(1E,3E)-4-chlorobuta-1,3-dienyl]benzene；[(1E,3E)-4-chloro-1,3-butadienyl]benzene；(1E,3E)-1-chloro-4-phenyl-1,3-butadiene；1t-chloro-4t-phenyl-buta-1,3-diene；1t-Chlor-4t-phenyl-buta-1,3-dien；[(1E,3E)-4-chlorobuta-1,3-dienyl]benzene
• CAS: 18685-02-4
• 化学式: C₁₀H₉Cl
• 分子量: 164.634
• InChiKey: IBQSWRZSFAZZQG-KBXRYBNXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  [(E)-4,4-dichlorobut-1-enyl]benzene 、 [(1E,3E)-4-chlorobuta-1,3-dien-1-yl]benzene 、 正丁基锂 以70%的产率得到
  参考文献：
  名称：

  VILLIERAS J.; PERRIOT P.; NORMANT J. F., SYNTHESIS, 1979, NO 7, 502-504

  摘要：

  DOI：
• 作为产物：
  描述：

  (4R,5R)-4-chloro-5-[(E)-2-phenylethenyl]-1,3-oxathiolane 3,3-dioxide 以31%的产率得到
  参考文献：
  名称：

  NAGASHIMA, ENKOU;SUZUKI, KUNIO;ISHIKAWA, MOTOAKI;SEKIYA, MINORU, HETEROCYCLES, 1985, 23, N 8, 1873-1879

  摘要：

  DOI：

文献信息

• The effect of vicinyl olefinic halogens on cross-coupling reactions using Pd(0) catalysis
  作者：Michael G. Organ、Haleh Ghasemi、Cory Valente

  DOI：10.1016/j.tet.2004.08.006

  日期：2004.10

  products reliably under all reaction conditions. Compound 5 did not provide cross coupled products under any of the reaction conditions used. The Negishi reaction was the only one that worked for templates 4 and 11. Studies indicate that oxidative addition of the most reactive carbon–halogen bond to Pd(0) is followed by elimination of the second halide, when the second halide is a bromide or an iodide

  （反式）1-氯-2-碘乙烯（3），（反式）1-溴-2-碘乙烯（4），（反式）1,2-二碘乙烯（5）和（顺式和反式）1,2-二溴乙烯（11）在Puz催化下，在Suzuki，Sonogashira和Negishi交叉偶联条件下反应以获得单偶联产物。在所有反应条件下，只有烯烃模板3才能可靠地提供所需的偶联产物。在使用的任何反应条件下，化合物5均不提供交叉偶联产物。Negishi反应是唯一适用于模板的反应4和11。研究表明，当第二个卤化物是溴化物或碘化物时，将最具反应性的碳-卤素键氧化加成到Pd（0）上，然后消除第二个卤化物。当第二个卤素是氯化物时，发生的程度要小得多。
• A Very Simple Synthesis of Chloroalkenes and Chlorodienes by Selective Suzuki Couplings of 1,1- and 1,2-Dichloroethylene
  作者：José Barluenga、Patricia Moriel、Fernando Aznar、Carlos Valdés

  DOI：10.1002/adsc.200505302

  日期：2006.2

  Chloroalkenes, important building blocks for cross-coupling reactions, are prepared in one step by the Suzuki reaction of 1,1-dichloroethylene and 1,2-dichloroethylene with alkenyl- and arylboronic acids. Under the proper reaction conditions, it is possible to obtain the monocoupling reaction to provide the corresponding chloroalkenes with good yields. This method represents an excellent route for

  氯烯烃是交叉偶联反应的重要组成部分，可通过1，1-二氯乙烯和1,2-二氯乙烯与烯基和芳基硼酸的Suzuki反应一步制备。在适当的反应条件下，有可能获得单偶联反应，从而以良好的产率提供相应的氯代烯烃。该方法代表了从商购可得的原料制备氯代烯烃和氯二烯的绝佳途径。
• Toner for developing electrostatic image and process for production thereof
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0560341A1

  公开（公告）日：1993-09-15

  A novel toner for developing electrostatic images is disclosed, which comprises at least a resin and a granulated carbon black having a grain hardness of 2 g or less as starting raw materials blended therein. In addition, a novel process for the production of the novel toner is described.

  本发明公开了一种用于显影静电图像的新型墨粉，它至少包括一种树脂和一种颗粒硬度为 2 克或更小的粒状炭黑作为起始原料混合在一起。此外，还介绍了生产这种新型墨粉的新工艺。
• SOLVENT ABSORBING RESIN AND METHOD FOR PREPARATION THEREOF
  申请人：Sony Corporation

  公开号：EP1277767A1

  公开（公告）日：2003-01-22

  The present invention is relative with an organic liquid absorbent resin comprised of a water-insoluble resin to which have been introduced hydrophilic polar groups. This organic liquid absorbent resin is produced on introducing hydrophilic groups to the water-insoluble resin. This organic liquid absorbent resin is inexpensive, high in safety and superior in is performance in absorbing not only hydrophilic solvents but also oleophilic solvents.

  本发明涉及一种有机液体吸水树脂，它由水不溶性树脂和亲水极性基团组成。这种有机液体吸收树脂是在不溶于水的树脂中加入亲水基团而制成的。这种有机液体吸收树脂价格低廉，安全性高，性能优越，不仅能吸收亲水性溶剂，还能吸收亲油性溶剂。
• External additive for toner for electrophotography, toner for electrophotography, double-component developer for electrophotography, image forming process using the toner, and image-forming apparatus using the toner
  申请人：Ricoh Company Ltd.

  公开号：EP1383010A1

  公开（公告）日：2004-01-21

  An external additive for a toner for electrophotography which contains oxide fine particles which contain silicon, in which the oxide fine particles have a primary particle diameter of 30nm to 300nm in number average, a standard deviation σ of a particle size distribution of the primary particle diameter satisfies a relation of: R/4 ≤ σ ≤ R, in which the R expresses the primary particle diameter, the oxide fine particles are substantially spherical having a circularity SF1 defined as equation (1) of 100 to 130 and a circularity SF2 defined as equation (2) of 100 to 125;SF1 = (L2/A) ×(π/4) × 100SF2 = (P2/A) × (1/4π) × 100 in the equations, "L" expresses the absolute maximum length of the oxide fine particles; "A" expresses a projected area of the oxide fine particles; and "P" expresses a maximum perimeter of the oxide fine particles.

  一种用于电致发光墨粉的外部添加剂，它含有含硅的氧化物微粒，其中氧化物微粒的主颗粒直径平均为30纳米至300纳米，主颗粒直径的粒度分布的标准偏差σ满足以下关系式：R/4 ≤ σ ≤ R，其中 R 表示主颗粒直径、 氧化物微粒基本上是球形的，其圆度 SF1 定义为式（1）的 100 至 130，圆度 SF2 定义为式（2）的 100 至 125；SF1 = (L2/A) ×(π/4) × 100SF2 = (P2/A) × (1/4π) × 100 在公式中，"L "表示氧化物微粒的绝对最大长度；"A "表示氧化物微粒的投影面积；"P "表示氧化物微粒的最大周长。