1,3,5-三(二溴甲基)-苯 | 1889-66-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,3,5-三(二溴甲基)-苯
• 英文名称: α,α,α',α',α'',α''-hexabromomesitylene
• 英文别名: 1,3,5-tris(dibromomethyl)benzene；α,α,α',α',α'',α''-Hexabrom-mesitylen；1,3,5-Tris(dibrommethyl)benzol；1,3,5-Tris-dibrommethyl-benzol；Hexabrommesitylen
• CAS: 1889-66-3
• 化学式: C₉H₆Br₆
• 分子量: 593.571
• InChiKey: BXGZVNSQLBRQQO-UHFFFAOYSA-N

物化性质

• 熔点：
  190 °C
• 沸点：
  424.9±40.0 °C(Predicted)
• 密度：
  2.701±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2903999090

反应信息

• 作为反应物：
  描述：

  1,3,5-三(二溴甲基)-苯 在 硫酸 作用下， 以 水 为溶剂， 反应 1.0h， 以80%的产率得到均苯三甲醛
  参考文献：
  名称：

  A C3-symmetric colorimetric anion sensor bearing hydrazone groups as binding sites

  摘要：

  Tris-hydrazone (1) functioned as a colorimetric chemosensor for a variety of anions such as F-, AcO- and H2PO4-. The anion binding could be easily detected by naked-eye according to color changes. The high binding ability of the receptor 1 to anions was further investigated by UV-vis absorption spectroscopy in DMSO. The results of job plot of the receptor 1 with different anions demonstrated that the stoichiometry of the complex between 1 and F- was 1:1 (1:anion) and the stoichiometry of the other complexes studied was 1:3 (1:anion). (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2008.06.025
• 作为产物：
  描述：

  均三甲苯 在 溴 作用下， 生成 1,3,5-三(二溴甲基)-苯
  参考文献：
  名称：

  Colonge,J.; von Arx,P., Bulletin de la Societe Chimique de France, 1965, p. 1858 - 1862

  摘要：

  DOI：

文献信息

• Synthesis and Mesomorphic Properties of New Columnar Liquid Crystal Containing 1,3,5-triiminebenzene with Pendant 1,3,4-thiadiazole Group
  作者：Mustafa K. S. Al-Malki、Ayad S. Hameed、Ammar H. Al-Dujaili

  DOI：10.1080/15421406.2013.864546

  日期：2014.4.13

  A novel discotic liquid crystal series based on 1,3,5-benzenetrisazomethine derivatives with three pendant 2-amino-5-(4'-n-alkoxy) phenyl-1,3,4-thiadiazole has been synthesized, which is the first columnar molecules containing 1,3,4-thiadiazole moiety exhibiting a discotic liquid crystal. The molecular structure of compounds was confirmed by FT-IR, H-1-NMR, and mass spectroscopy and elemental analysis. The electron excitation properties of these compounds were investigated by UV-vis absorption spectroscopy. Their liquid crystalline properties were studied by polarizing optical microscopy and differential scanning calorimetry. The formation of a columnar mesophase was found to be dependent on the number of methylene unit in alkoxy side chains.
• Kerfanto,M.; Soyer,N., Bulletin de la Societe Chimique de France, 1966, p. 2966 - 2971
  作者：Kerfanto,M.、Soyer,N.

  DOI：——

  日期：——
• WO2007/119998
  申请人：——

  公开号：——

  公开（公告）日：——
• DOMBROVSKIJ V. A.; YANOVSKAYA L. A., IZV. AN CCCP. CEP. XIM. <IKAK-AK>, 1975, HO 8, 1886-188
  作者：DOMBROVSKIJ V. A.、 YANOVSKAYA L. A.

  DOI：——

  日期：——
• [EN] DIIMIDAZOLE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] COMPOSÉ DIIMIDAZOLE ET DISPOSITIF ORGANIQUE ÉLECTROLUMINESCENT COMPRENANT CE DERNIER
  申请人：DONGJIN SEMICHEM CO LTD

  公开号：WO2007119998A1

  公开（公告）日：2007-10-25

  [EN] The invention provides a diimidazole compound and an organic electroluminescent device using the same and more particularly, the diimidazole compounds according to the invention have excellent blue luminescent characteristics and hole transmission characteristics and at the same time, they not only can be used as a blue luminescent material or used as a host to a variety of phosphorescent or fluorescent dopants such as red, green, blue and white but also enable high efficient luminescence when applied to organic electroluminescent devices and can confer such performances as low voltage, high brightness and long lifetime.
  [FR] La présente invention concerne un composé diimidazole et un dispositif organique électroluminescent qui comprend ce dernier. Plus particulièrement, les composés diimidazole selon l'invention présentent d'excellentes caractéristiques de luminescence bleue et des caractéristiques de transmission des trous, de surcroît on peut les utiliser non seulement en tant que matière luminescente bleue ou en tant qu'hôte pour divers dopants phosphorescents ou fluorescents tels que le rouge, le vert, le bleu et le blanc mais ils produisent également une luminescence très efficiente lorsqu'on les utilise dans des dispositifs organiques électroluminescents et peuvent conférer des propriétés telles qu'une faible tension, une haute luminosité et une longue durée de vie.