1-(3-溴丙基)-4-乙烯基苯 | 41996-95-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-(3-溴丙基)-4-乙烯基苯
• 英文名称: 1-(3-bromopropyl)-4-vinylbenzene
• 英文别名: 1-bromo-3-p-styrylpropane；p-(3-Bromopropyl)styrene；4-(3-Brompropyl)-styrol；1-(3-Bromopropyl)-4-ethenylbenzene
• CAS: 41996-95-6
• 化学式: C₁₁H₁₃Br
• 分子量: 225.128
• InChiKey: KMOVNOPNNLQXEJ-UHFFFAOYSA-N

物化性质

• 沸点：
  269.0±9.0 °C(Predicted)
• 密度：
  1.265±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-(3-溴丙基)-4-乙烯基苯 在 sodium hydroxide 作用下， 以 甲醇 为溶剂， 反应 20.0h， 生成 3-(4-vinylphenyl)propane-1-thiol
  参考文献：
  名称：

  Self-Limiting Robust Surface-Grafted Organic Nanofilms

  摘要：

  Robust surface-bound insulating polymer films with controlled thickness in <5 nm range are important for technological advances in diverse disciplines such as electrochemical sensors, molecular electronics, separations, and anticorrosive coatings. Creating these films by simple methods from readily available materials has been a significant challenge. Here we report a newly synthesized molecule combining styrene and thiol moieties, joined via a short linker, that binds to the gold surface, polymerizes, and cross-links polymer chains to form robust films with uniform and controlled thickness and complete surface coverage. Additional layers can be deposited. These films that bridge two- and three-dimensional materials show excellent stability and insulating properties.

  DOI：

  10.1021/cm903024h
• 作为产物：
  描述：

  2-甲基苯磺酸 以 正己烷 、 水 、 乙酸乙酯 、 甲苯 为溶剂， 生成 1-(3-溴丙基)-4-乙烯基苯
  参考文献：
  名称：

  Nanothin polymer coatings containing thiol and methods of use thereof

  摘要：

  本发明提供了一种新单体及其使用方法，用于制备控制厚度在1至5纳米之间的坚固聚合物表面涂层。该涂层由一种新材料组成，其中包含4-乙烯基苯基丙硫醇聚合单体。聚合物表面涂层可应用于金属和硅。该方法包括将金属基底暴露于己烷中的单体溶液中，以便将单体的单层沉积到金属表面上。然后，用紫外线辐射以便在表面上嫁接一层薄聚合物涂层。该程序可以重复进行，以控制涂层的厚度在约1纳米至5纳米之间。或者，通过热引发聚合或部分寡聚单体沉积到表面上，提供具有相同性能的纳米薄涂层。该涂层提供完全的表面覆盖，极其坚固，并表现出优异的绝缘和防腐蚀性能。

  公开号：

  US07829155B1

文献信息

• General access to para-substituted styrenes
  作者：Sandrine Langle、Franck David-Quillot、Alexia Balland、Mohamed Abarbri、Alain Duchêne

  DOI：10.1016/s0022-328x(03)00053-6

  日期：2003.4

  efficient procedure has been developed for the synthesis of organogermanium compounds and styrenes para-substituted with groups containing an atom of the 14th group by one-pot reaction of halogenosilanes, germanes or stannanes, organic halides and magnesium using ultrasound methods.

  已经开发了一种简单有效的程序，用于通过超声方法通过卤代硅烷，锗烷或锡烷，有机卤​​化物和镁的一锅反应来合成有机锗化合物和被含第14个原子的基团对位取代的苯乙烯。
• In situ coupled oxidation cycle catalyzed by highly active and reusable Pt-catalysts: dehydrogenative oxidation reactions in the presence of a catalytic amount of o-chloranil using molecular oxygen as the terminal oxidant
  作者：Hiroyuki Miyamura、Kanako Maehata、Shu Kobayashi

  DOI：10.1039/c0cc02865g

  日期：——

  An in situ coupled oxidation cycle that allows catalytic oxidation of a substrate with catalytic amounts of o-chloranil and novel reusable polymer-immobilized platinum nanocluster catalysts using molecular oxygen as the terminal oxidant was developed.

  开发了一种原位耦合氧化循环，该循环允许使用催化量的邻氯苯甲酸酯和使用分子氧作为末端氧化剂的新型可重复使用的聚合物固定化的铂纳米簇催化剂对底物进行催化氧化。
• Multi-branched polymer, process for producing the same, and applications thereof
  申请人：——

  公开号：US20040220346A1

  公开（公告）日：2004-11-04

  A group of polymers comprising a plurality of polyolefin chains and polar polymer chains and having a multi-branched structure such as a block structure, a graft structure and a star-shaped structure is produced efficiently by polymerizing or reacting a combination of various polar monomers and their polymers i.e. polar polymer chains by using a functional group-containing polyolefin as a macroinitiator, a macromonomer or a reactive polymer. The resulting multi-branched polymer has a specific shape such as a block structure, a graft structure or a star-shaped structure, and has properties of both the polyolefin and polar polymer, thus exhibiting useful performance in various uses in films and compatibilizing agents as a novel polyolefin-based polymer.

  通过使用含有功能性基团的聚烯烃作为宏启动剂、宏单体或反应性聚合物，聚合或反应各种极性单体及其聚合物即极性聚合物链，可以高效地生产出由多个聚烯烃链和极性聚合物链组成的聚合物群，其具有诸如块状结构、嫁接结构和星形结构等多分支结构。所得到的多分支聚合物具有特定形状，如块状结构、嫁接结构或星形结构，并具有聚烯烃和极性聚合物的性质，因此在薄膜和相容剂等各种用途中表现出有用的性能，是一种新型的基于聚烯烃的聚合物。
• CHARGE CONTROL RESIN AND MANUFACTURING METHOD OF THE SAME
  申请人：YASUMATSU Masashi

  公开号：US20150025213A1

  公开（公告）日：2015-01-22

  Here is provided a charge control resin which is prompt in charge rising up, excellent in electrostatic charging propensity and easy in manufacturing. This charge control resin contains a polymer as an active ingredient having a constituent unit represented by following Formula (1) in the Formula (1), R 1 is independent of one another, and is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; R 2 is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; g is a number of 1-3; h is a number of 1-3; and M is a hydrogen atom, an alkali metal, a straight-chained or branched alkyl group having 1-18 carbon atoms, an ammonium radical or a mixture of any of these.

  这里提供了一种电荷控制树脂，它在电荷上升方面快速，具有优异的静电充电倾向并且易于制造。该电荷控制树脂包含一种聚合物作为活性成分，该聚合物具有由以下公式（1）表示的组成单元。在公式（1）中，R1互不相同，可以是氢原子、羟基、卤素原子、含羧基的基团、直链或支链烷基（碳数为1-18）或直链或支链烷氧基（碳数为1-18）；R2可以是氢原子、羟基、卤素原子、含羧基的基团、直链或支链烷基（碳数为1-18）或直链或支链烷氧基（碳数为1-18）；g为1-3的数字；h为1-3的数字；M可以是氢原子、碱金属、直链或支链烷基（碳数为1-18）、铵基或任何这些的混合物。
• Three-component aminofluorination of alkenes with electronically rich amino sources
  作者：Yang Li、Jiamin Bao、Yu Zhang、Xue Peng、Weijie Yu、Tao Wang、Dengtao Yang、Qun Liu、Qian Zhang、Junkai Fu

  DOI：10.1016/j.chempr.2022.02.014

  日期：2022.4

  alkylaminyl radical formation and maintain the nucleophilicity of fluoride ion. This protocol exhibits excellent functional-group tolerance toward various aryl and unactivated alkenes, furnishing the corresponding β-fluoroamines with high regioselectivity. Mechanistic investigation reveals an aziridinium intermediate via a radical pathway. The synthetic utility of this transformation was demonstrated by

  通过 umpolung 策略开发了具有丰富电子氨基源的烯烃的第一个分子间三组分氨基氟化。在该反应中，亲电的N-溴二烷基胺被用作胺亲电子试剂，而多功能 AgF 同时作为亲核氟化物源和还原催化剂，首次与N引发单电子转移-溴二烷基胺。添加六氟异丙醇作为助溶剂对于促进质子化烷基胺自由基的形成和保持氟离子的亲核性至关重要。该协议对各种芳基和未活化烯烃表现出优异的官能团耐受性，为相应的 β-氟胺提供了高区域选择性。机理研究揭示了一种通过自由基途径产生的氮丙啶中间体。这种转化的合成效用通过几种生物活性分子的氨基氟化来证明，包括通往利扎曲坦类似物的有效途径。我们预计我们的发现有望为药物化学和胺化反应的新发现带来希望。