4,5-二硝基-2-甲基苯甲醚 | 860734-17-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4,5-二硝基-2-甲基苯甲醚
• 英文名称: 4,5-dinitro-2-methylanisole
• 英文别名: 2-methyl-4,5-dinitro-anisole；Methyl-(4.5-dinitro-2-methyl-phenyl)-aether；2-Methyl-4,5-dinitro-anisol；4.5-Dinitro-2-methoxy-toluol；1-Methoxy-2-methyl-4,5-dinitrobenzene
• CAS: 860734-17-4
• 化学式: C₈H₈N₂O₅
• 分子量: 212.162
• InChiKey: HUKXSKKZEXMRTM-UHFFFAOYSA-N

物化性质

• 沸点：
  386.9±37.0 °C(Predicted)
• 密度：
  1.383±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4,5-二硝基-2-甲基苯甲醚 在 盐酸 、 甲醇 、 硫酸 、 tin(ll) chloride 、 sodium nitrite 作用下， 生成 2-甲基-4-硝基苯甲醚
  参考文献：
  名称：

  Introduction to Stephen G. West's Murray Award Address

  摘要：

  I am honored to introduce Stephen G. West, the winner of the Henry A. Murray Award for Outstanding Contributions to Personology and the Study of Human Lives. Steve's contributions as a methodologist and statistician are appreciated by anyone who has struggled with complex interactions and unusual research designs. These empirical innovations have contributed enormously to broadening and deepening the kinds of data that can be used to study personality. Perhaps less apparent, but crucial in his selection for this award, is Steve's leadership in diversifying the field of personality psychology. In his capacity as editor of the Journal of Personality in the 1980s and early 1990s, Steve effectively shepherded personology into the mainstream of personality research. Also important was Steve's willingness not only to mentor his own graduate students, but to rescue a considerable number of strays. In his generativity and inclusiveness, Steve has effectively elevated the field of personality and the persons within it.

  DOI：

  10.1111/1467-6494.7103002
• 作为产物：
  描述：

  5-硝基-2-甲基苯甲醚 在 硝酸 作用下， 反应 1.0h， 以36%的产率得到5,6-dinitro-2-methylanisole
  参考文献：
  名称：

  1,2-亚烷基二氧基取代的苯并呋喃和相关苯并呋喃的质谱：线性异构体和有角异构体之间的区别。

  摘要：

  [1,3] -dioxolo-，6，7-dihydro- [1,4] -dioxino-，7,8-dihydro-6H- [1,4] dioxepino-，6的电子电离（EI）质谱，7,8，9-四氢[1,4] dioxocino-，7,8,9,10-四氢-6H- [1,4] dioxonino-和6,7,8,9,10,11-六氢[据报道，都是线性异构体的1,4]二氧杂癸并[2,3-f] -2,1,3-苯并恶二唑（苯并呋喃）和相应的1-氧化物（苯并呋喃）。还报道了相应的角异构体[1，3] dioxolo-，7,8-dihydro [1,4] dioxino-，8,9-dihydro-7H- [1,4] dioxepino-， 7,8,9,10-四氢[1,4] dioxocino-，8,9,10,11-四氢-7H- [1，4] dioxonino-，7,8,9,10,11,12-hexahydro

  DOI：

  10.1002/(sici)1096-9888(199911)34:11<1137::aid-jms874>3.0.co;2-4

文献信息

• US4202698A
  申请人：——

  公开号：US4202698A

  公开（公告）日：1980-05-13
• US4323682A
  申请人：——

  公开号：US4323682A

  公开（公告）日：1982-04-06
• Introduction to Stephen G. West's Murray Award Address
  作者：Avril Thorne

  DOI：10.1111/1467-6494.7103002

  日期：——

  I am honored to introduce Stephen G. West, the winner of the Henry A. Murray Award for Outstanding Contributions to Personology and the Study of Human Lives. Steve's contributions as a methodologist and statistician are appreciated by anyone who has struggled with complex interactions and unusual research designs. These empirical innovations have contributed enormously to broadening and deepening the kinds of data that can be used to study personality. Perhaps less apparent, but crucial in his selection for this award, is Steve's leadership in diversifying the field of personality psychology. In his capacity as editor of the Journal of Personality in the 1980s and early 1990s, Steve effectively shepherded personology into the mainstream of personality research. Also important was Steve's willingness not only to mentor his own graduate students, but to rescue a considerable number of strays. In his generativity and inclusiveness, Steve has effectively elevated the field of personality and the persons within it.
• Mass spectra of 1,2-alkylenedioxy-substituted and related benzofurazans and benzofuroxans: differentiation between linear and angular isomers
  作者：Ioannis M. Takakis、Georgia G. Tsantali、George W. Haas、Daryl Giblin、Michael L. Gross

  DOI：10.1002/(sici)1096-9888(199911)34:11<1137::aid-jms874>3.0.co;2-4

  日期：1999.11

  ionization (EI) mass spectra of [1,3]-dioxolo-, 6, 7-dihydro-[1,4]-dioxino-, 7,8-dihydro-6H-[1,4]dioxepino-, 6,7,8, 9-tetrahydro[1,4]dioxocino-, 7,8,9,10-tetrahydro-6H-[1,4]dioxonino- and 6,7,8,9,10,11-hexahydro[1,4]dioxecino[2,3-f]-2,1, 3-benzoxadiazoles (benzofurazans) and the corresponding 1-oxides (benzofuroxans), all linear isomers, are reported. Also reported are the EI mass spectra of the corresponding

  [1,3] -dioxolo-，6，7-dihydro- [1,4] -dioxino-，7,8-dihydro-6H- [1,4] dioxepino-，6的电子电离（EI）质谱，7,8，9-四氢[1,4] dioxocino-，7,8,9,10-四氢-6H- [1,4] dioxonino-和6,7,8,9,10,11-六氢[据报道，都是线性异构体的1,4]二氧杂癸并[2,3-f] -2,1,3-苯并恶二唑（苯并呋喃）和相应的1-氧化物（苯并呋喃）。还报道了相应的角异构体[1，3] dioxolo-，7,8-dihydro [1,4] dioxino-，8,9-dihydro-7H- [1,4] dioxepino-， 7,8,9,10-四氢[1,4] dioxocino-，8,9,10,11-四氢-7H- [1，4] dioxonino-，7,8,9,10,11,12-hexahydro