苯基二丙基磷酸酯 | 38299-59-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯基二丙基磷酸酯
• 英文名称: phosphoric acid phenyl ester-dipropyl ester
• 英文别名: Phosphorsaeure-phenylester-dipropylester；Di-n-Propyl-phenylphosphat；Dipropyl-phenyl-phosphat；Dipropylphenylphosphat；Phenyl dipropyl phosphate
• CAS: 38299-59-1
• 化学式: C₁₂H₁₉O₄P
• 分子量: 258.254
• InChiKey: VUTSVIHQBJIUOS-UHFFFAOYSA-N

物化性质

• 沸点：
  170 °C(Press: 0.25 Torr)
• 密度：
  1.109±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  苯基二丙基磷酸酯 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Li, Shusen; Wang, Guoquan, Phosphorus, Sulfur and Silicon and the Related Elements, 1991, vol. 61, # 12, p. 119 - 129

  摘要：

  DOI：
• 作为产物：
  描述：

  丙醇 、 二氯磷酸苯酯 在 吡啶 、 苯 作用下， 生成 苯基二丙基磷酸酯
  参考文献：
  名称：

  磷酸化的研究。第十二部分。磷酸和硫代磷酸的中性酯的选择性阴离子脱烷基

  摘要：

  DOI：

  10.1039/jr9540002381

文献信息

• [EN] METAL-FREE DIRECT ARYLATION OF DIALKYL PHOSPHONATES FOR THE SYNTHESIS OF MIXED ALKYL ARYL PHOSPHONATES<br/>[FR] ARYLATION DIRECTE SANS MÉTAL DE PHOSPHONATES DE DIALKYLE POUR LA SYNTHÈSE DE PHOSPHONATES D'ARYLE ALKYLE MIXTES
  申请人：THE BOARD OF REGENTS OF THE NEVADA SYSTEM OF HIGHER EDUCATION ON BEHALF OF THE UNIV OF NEVADA LAS VE

  公开号：WO2019028391A1

  公开（公告）日：2019-02-07

  Provided herein are phosphates, thiophosphates, phosphonates, and phosphinates, methods of making same, and methods of using these compounds and methods for the generation of pharmaceutically relevant phosphate, phosphonate, and phosphinate analogs. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

  本文提供了磷酸盐、硫代磷酸盐、膦酸盐和膦酸盐，以及制备这些化合物的方法，以及使用这些化合物和用于生成与药用相关的磷酸盐、膦酸盐和膦酸盐类似物的方法。此摘要旨在作为搜索特定领域的扫描工具，并不限制本发明。
• Selective Hydrogenation Catalyst and Methods of Making and Using Same
  申请人：Cheung Tin-Tack Peter

  公开号：US20100228065A1

  公开（公告）日：2010-09-09

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

  一种包括支持的氢化催化剂的组合物，其中氢化催化剂包括钯和有机磷化合物，支持的氢化催化剂能够选择性地将高度不饱和烃氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括将支持物与含钯化合物接触以形成支持的钯组合物，将支持的钯组合物与有机磷化合物接触以形成催化剂前体，并还原催化剂前体以形成催化剂。一种将高度不饱和烃选择性氢化为富含不饱和烃的组合物的方法，包括将包括钯和有机磷化合物的支持催化剂与含高度不饱和烃的进料接触，在适宜的氢化条件下至少部分氢化高度不饱和烃进料以形成富含不饱和烃的组合物。
• Viscosity index improving additives for phosphate ester-containing hydraulic fluids
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0823472A1

  公开（公告）日：1998-02-11

  Polymer compositions derived from selected alkyl (meth)acrylate ester monomers used in certain weight ratios to provide improved viscosity control and low temperature performance characteristics in phosphate ester aircraft hydraulic fluids is disclosed. Polymer compositions for use as viscosity index improving additives in aircraft hydraulic fluids contain from 40 to 100 weight percent (C1-C10)alkyl (meth)acrylate and zero to 60 weight percent (C11-C20)alkyl (meth)acrylate monomer units. Preferred polymer compositions based on 40 to 70 weight percent (C1-C10)alkyl (meth)acrylate and 30 to 60 weight percent (C11-C15)alkyl (meth)acrylate monomer units combine good solubility in the phosphate ester hydraulic fluids with good viscosity control at low and high temperatures.

  本发明公开了由选定的(甲基)丙烯酸烷基酯单体按一定重量比制成的聚合物组合物，用于改善磷酸酯飞机液压油的粘度控制和低温性能特性。用作飞机液压油粘度指数改进添加剂的聚合物组合物含有 40 至 100 重量百分比的（C1-C10）烷基（甲基）丙烯酸酯和零至 60 重量百分比的（C11-C20）烷基（甲基）丙烯酸酯单体单元。以 40% 至 70% 重量百分比的(C1-C10)烷基（甲基）丙烯酸酯和 30% 至 60% 重量百分比的(C11-C15)烷基（甲基）丙烯酸酯单体单元为基础的优选聚合物组合物兼具在磷酸酯液压油中的良好溶解性和在低温和高温下的良好粘度控制性。
• SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP3144064A2

  公开（公告）日：2017-03-22

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons.

  一种由钯和有机磷化合物组成的载体加氢催化剂组成的组合物，该载体加氢催化剂能选择性地将高度不饱和烃加氢为不饱和烃。
• Reactive flame retardant blends for flexible polyurethane foam
  申请人：ICL-IP America Inc.

  公开号：US10597511B2

  公开（公告）日：2020-03-24

  The present invention provides dialkyl phosphorus-containing compounds, namely reactive mono-hydroxyl-functional dialkyl phosphinates in a blend with a phosphate compound, said blend serving as highly efficient reactive flame retardant blend in flexible polyurethane foam. The invention further provides fire-retarded polyurethane compositions comprising said the reaction product of the flame retardant blend with polyol and isocyanate foam forming components.

  本发明提供了含磷的二烷基化合物，即活性单羟基官能二烷基膦酸盐与磷酸盐化合物的混合物，所述混合物可作为软质聚氨酯泡沫塑料中的高效活性阻燃混合物。本发明进一步提供了阻燃聚氨酯组合物，该组合物包含上述阻燃混合物与多元醇和异氰酸酯泡沫成型成分的反应产物。