4-octyl-[1,3]dithiole-2-thione | 360055-94-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 4-octyl-[1,3]dithiole-2-thione
• 英文别名: 4-Octyl-1,3-dithiole-2-thione
• CAS: 360055-94-3
• 化学式: C₁₁H₁₈S₃
• 分子量: 246.462
• InChiKey: ALAIILSUMLUFKV-UHFFFAOYSA-N

物化性质

• 沸点：
  345.7±25.0 °C(Predicted)
• 密度：
  1.12±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  82.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-octyl-[1,3]dithiole-2-thione 在 间氯过氧苯甲酸 作用下， 生成 (2E)-4-octyl-2-(4-octyl-1,3-dithiol-2-ylidene)-1,3-dithiole
  参考文献：
  名称：

  Yamamoto, Takakazu; Sasaki, Takayuki; Yanagida, Tomoaki, Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 2002, vol. 381, p. 101 - 112

  摘要：

  DOI：
• 作为产物：
  描述：

  1-癸炔 在 四(三苯基膦)钯 、 四丁基氟化铵 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 15.0h， 生成 4-octyl-[1,3]dithiole-2-thione
  参考文献：
  名称：

  Preparation and reactivity studies of 1,2-bis-triisopropylsilanylsulfanyl-alkenes

  摘要：

  The cross-coupling reaction of bis-triisopropylsilyl disulfide 1 on alkynes yielded 1,2-bis-triisopropylsilanylsulfanyl-alkenes 2, a new chemical class. A series of tri and tetrasubstituted olefins 2 were prepared and their behavior toward electrophiles was studied. The triisopropylsilyl groups could be readily removed by treatment with TBAF at 0 degreesC for 1 h or cesium acetate at 70 degreesC for 2 h. Soft and hard electrophiles were submitted to 2 under these conditions. The electrophiles can either react to yield double addition products with alkyl and activated halides, epoxides and acyl chlorides or cyclic adducts with chloroformate derivatives. In the latter case, 1,3-dithiol-2-ones or 1,3-dithiol-2-thiones are prepared. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(01)00517-8

文献信息

• Titanium(salen)-Catalysed Synthesis of Di- and Trithiocarbonates from Epoxides and Carbon Disulfide
  作者：Christopher Beattie、Michael North

  DOI：10.1002/cctc.201400005

  日期：2014.3.12

  tributylamine forms a highly active catalyst system for the reaction between epoxides and carbon disulfide to lead to di‐ and/or trithiocarbonates. Reactions can be performed at 90 °C by using just 0.5–1.0 mol % of the catalysts. The reactions proceed with the inversion of the epoxide configuration and on the basis of kinetic and spectroscopic evidence, a mechanism to account for the results is proposed.

  双金属钛（salen）配合物[Ti（salen）O] 2和四丁基溴化铵或三丁胺的组合形成了高活性的催化剂体系，可用于环氧化物和二硫化碳之间的反应，从而生成二硫代和/或三硫代碳酸盐。通过仅使用0.5–1.0 mol％的催化剂，即可在90°C下进行反应。反应随着环氧化物构型的转化而进行，并基于动力学和光谱学证据，提出了一种解释结果的机制。
• ACCUMULATOR MATERIAL AND ACCUMULATOR DEVICE
  申请人：Hojo Nobuhiko

  公开号：US20110091767A1

  公开（公告）日：2011-04-21

  An electricity storage device including a positive electrode 31 , a negative electrode 32 , and an electrolytic solution 29 located between the positive electrode and the negative electrode. At least one of the positive electrode 31 and the negative electrode 32 contains an electricity storage material containing a polymerization product having a tetrachalcogenofulvalene structure in a repeat unit of a main chain.

  一种电力储存装置，包括正极31、负极32和位于正极和负极之间的电解质29。正极31和负极32中的至少一个包含一种电力储存材料，该电力储存材料包含一个具有四硫属富瓦烯结构的聚合物化合物，在主链的重复单元中。
• POLYMER, SEMICONDUCTOR FILM, ELECTRODE, ELECTRODE ACTIVE MATERIAL, ELECTROCHEMICAL ELEMENT AND ELECTRICITY STORAGE DEVICE
  申请人：Yamamoto Takakazu

  公开号：US20110086267A1

  公开（公告）日：2011-04-14

  A polymer having a structure represented by the following general formula (1), wherein in general formula (1), Ph is a phenyl group; X is an oxygen atom, a sulfur atom, a selenium atom or a tellurium atom; and R1 and R1 each independently contains at least one selected from the group consisting of a chained saturated hydrocarbon group, a chained unsaturated hydrocarbon group, a cyclic saturated hydrocarbon group, a cyclic unsaturated hydrocarbon group, a phenyl group, a hydrogen atom, a hydroxyl group, a cyano group, an amino group, a nitro group and a nitroso group. The chained saturated hydrocarbon group, the chained unsaturated hydrocarbon group, the cyclic saturated hydrocarbon group and the cyclic unsaturated hydrocarbon group each contain at least one selected from the group consisting of a carbon atom, an oxygen atom, a nitrogen atom, a sulfur atom and a silicon atom.
• US8481674B2
  申请人：——

  公开号：US8481674B2

  公开（公告）日：2013-07-09
• US8945769B2
  申请人：——

  公开号：US8945769B2

  公开（公告）日：2015-02-03