O,O-bis(4-((2-(dichlorophosphorothioyl)-2-methylhydrazineylidene)methyl)phenyl) (diphenyl(vinyl)-l5-phosphaneylidene)phosphoramidothioate | 318956-66-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: O,O-bis(4-((2-(dichlorophosphorothioyl)-2-methylhydrazineylidene)methyl)phenyl) (diphenyl(vinyl)-l5-phosphaneylidene)phosphoramidothioate
• CAS: 318956-66-0
• 化学式: C₃₀H₂₉Cl₄N₅O₂P₄S₃
• 分子量: 853.498
• InChiKey: NDKBAEWMEBYTHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.3
• 重原子数：
  48.0
• 可旋转键数：
  14.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  62.02
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  O,O-bis(4-((2-(dichlorophosphorothioyl)-2-methylhydrazineylidene)methyl)phenyl) (diphenyl(vinyl)-l5-phosphaneylidene)phosphoramidothioate 以 四氢呋喃 为溶剂， 反应 3.0h， 生成
  参考文献：
  名称：

  Varying Topology of Dendrimers − A New Approach toward the Synthesis of Di-Block Dendrimers

  摘要：

  DOI：

  10.1002/1099-0682(200107)2001:7<1681::aid-ejic1681>3.0.co;2-t
• 作为产物：
  描述：

  bis(4-formylphenyl) azidothiophosphonate 以 四氢呋喃 、 二氯甲烷 、 氯仿 为溶剂， 反应 15.0h， 生成 O,O-bis(4-((2-(dichlorophosphorothioyl)-2-methylhydrazineylidene)methyl)phenyl) (diphenyl(vinyl)-l5-phosphaneylidene)phosphoramidothioate
  参考文献：
  名称：

  具有受控分子结构的含磷树枝状聚合物的快速合成：从同一树枝发出的表面块状、层状块状和段块状树枝状聚合物的第一个例子

  摘要：

  第三代树枝状分子具有连接到核心的一个活化乙烯基和连接到表面的 16 个氯，已在核心（伯胺、膦或叠氮化物）和表面（醛、叔胺或腈）。这些功能化的树突用作合成几种复杂树突结构的构建块，通过核-核、核-表面或核-核-表面-核耦合使用这些功能之间非常简单的一步反应获得，例如迈克尔乙烯基和伯氨基之间的加成或膦和叠氮化物之间的施陶丁格反应。这些反应最终诱导了层块树突、表面块树状聚合物、层块树状聚合物、层状表面块树状聚合物和链段块树状聚合物的形成，

  DOI：

  10.1021/ja992099j

文献信息

• Diversified Strategies for the Synthesis of Bifunctional Dendrimeric Structures
  作者：David Riegert、Anna Pla-Quintana、Sabine Fuchs、Régis Laurent、Cédric-Olivier Turrin、Carine Duhayon、Jean-Pierre Majoral、Alexandra Chaumonnot、Anne-Marie Caminade

  DOI：10.1002/ejoc.201300456

  日期：2013.8

  The synthesis of three new families of dendrimeric compounds possessing two different types of functions is reported. These functions are triethoxysilyl group(s), potentially suitable for grafting onto materials, in particular silica, and primary amines (in their protected form), potentially suitable for trapping CO2. All these dendrimeric compounds are based on phosphorus dendrimers, and possess either

  报道了具有两种不同类型功能的三个新的树枝状化合物家族的合成。这些官能团是三乙氧基甲硅烷基，可能适合接枝到材料上，特别是二氧化硅，和伯胺（以它们的保护形式），可能适合捕获 CO2。所有这些树枝状化合物都基于磷树枝状大分子，并且在树枝状大分子或“偏心”树枝状大分子的核心具有一个 Si(OEt)3 基团，或者几个 Si(OEt)3 基团精确地放置在一半的端基上. 这些化合物的特征在于 31P NMR 光谱，这提供了关于结构的宝贵信息，在一个案例中，通过第一代树枝状聚合物的 X 射线衍射结构证实了这一点。
• The First Linear Multiphosphazene Having Five Different Types of Side Groups and Its Use as the Core of a Dendrimeric Species
  作者：Germinal Magro、Bruno Donnadieu、Anne-Marie Caminade、Jean-Pierre Majoral

  DOI：10.1002/chem.200204630

  日期：2003.5.23

  synthesis of the first oligophosphazenes having more than two types of side functions is described. These multifunctionalized oligophosphazenes possess up to four phosphazene linkages and up to four types of functional side groups. These compounds may serve as models for a better understanding of electronic delocalization phenomena in linear inorganic chains, and constitute novel cores for the synthesis

  描述了具有两种以上副功能的第一低聚磷腈的逐步合成。这些多官能的低聚磷腈具有最多四个磷腈键和最多四种类型的官能侧基。这些化合物可作为模型，以更好地理解线性无机链中的电子离域现象，并构成新的核心，用于合成新的树枝状分子，该树枝状分子在端基上和分支内具有几种作为端基的功能。
• Michael-Type Addition of Amines to the Vinyl Core of Dendrons − Application to the Synthesis of Multidendritic Systems
  作者：Valérie Maraval、Régis Laurent、Sonia Merino、Anne-Marie Caminade、Jean-Pierre Majoral

  DOI：10.1002/1099-0690(200011)2000:21<3555::aid-ejoc3555>3.0.co;2-v

  日期：2000.11

  Michael-type additions of functionalized amines to CH2=CH−P=N−P=S linkages located at the core of phosphorus-containing dendrons allowed for the grafting of functions suitable to join these dendrons together or to various dendritic molecules. This reactivity led to original multidendritic systems incorporating different types of subunits.

  官能化胺的迈克尔型加成到位于含磷树突核心处的CH 2 = CH-P = NP-S = S键上可以接枝适合将这些树突连接在一起或结合到各种树突分子上的功能。这种反应性导致原始的多树突系统结合了不同类型的亚基。
• Decorating step-by-step and independently the surface and the core of dendrons
  作者：Inma Angurell、Cédric-Olivier Turrin、Régis Laurent、Valérie Maraval、Paul Servin、Oriol Rossell、Miquel Seco、Anne-Marie Caminade、Jean-Pierre Majoral

  DOI：10.1016/j.jorganchem.2007.01.001

  日期：2007.4

  Dendrons possessing one activated vinyl group at the core and several chlorine atoms at the end of the branches are used as starting materials to study the possibility to react independently the surface functions and the core function. In particular, the most powerful sequence of reactions for decorating them by organometallic complexes as end groups and amine or alcohol at the core has been determined. In the first step, phenol phosphines are grafted as end groups of the dendrons, and they can be used for the complexation of metals. However, these phosphines must be kept free when amines are used to react with the vinyl core in the next step. Depending on the type of phosphine end groups and on the type of function of the core (amine or alcohol), the complexation of ruthenium ([RuCl2(p-cymene)](2)) and rhodium ([RhCl(COD)](2)) derivatives by the phosphine end groups can occur without side reaction at the core. (c) 2007 Elsevier B.V. All rights reserved.