1,1',2,2'-tetrahydroxy[3,3'-bianthracene]-9,9',10,10'-tetrone | 474758-41-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,1',2,2'-tetrahydroxy[3,3'-bianthracene]-9,9',10,10'-tetrone
• 英文别名: 3,3'-bializarin；3,4,3',4'-tetrahydroxy-[2,2']bianthryl-9,10,9',10'-tetraone；3,4,3',4'-Tetrahydroxy-[2,2']bianthryl-9,10,9',10'-tetraon；3-(3,4-dihydroxy-9,10-dioxoanthracen-2-yl)-1,2-dihydroxyanthracene-9,10-dione
• CAS: 474758-41-3
• 化学式: C₂₈H₁₄O₈
• 分子量: 478.414
• InChiKey: FHFNBSWGORQWDX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.73
• 重原子数：
  36.0
• 可旋转键数：
  1.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  149.2
• 氢给体数：
  4.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  1,1',2,2'-tetrahydroxy[3,3'-bianthracene]-9,9',10,10'-tetrone 、 (E)-3-Ureido-but-2-enoic acid ethyl ester 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  DE274783

  摘要：

  公开号：
• 作为产物：
  描述：

  1,2-二羟基蒽醌 在 氯 作用下， 生成 1,1',2,2'-tetrahydroxy[3,3'-bianthracene]-9,9',10,10'-tetrone
  参考文献：
  名称：

  Scholl, Chemische Berichte, 1919, vol. 52, p. 1835

  摘要：

  DOI：

文献信息

• Peroxidase-mediated transformation of hydroxy-9,10-anthraquinones
  作者：D Arrieta-Baez

  DOI：10.1016/s0031-9422(02)00173-5

  日期：2002.7

  A peroxidase (EC 1.11.1.7) has been isolated and purified from Senna angustifolia. The enzyme was purified by ion-exchange chromatography on high Q and high S columns. SDS-PAGE electrophoresis showed that the protein has a molecular mass of approximately 70 kDa. Hydroxy-anthraquinones and hydroxy-anthracenones were evaluated as substrate of S. angustifolia and horseradish peroxidases. Both peroxidases catalyzed the oxidation of alizarin and purpurin anthraquinones to the corresponding 3,3'-bializarin and the new compound 3,3'-bipurpurin, respectively, as well as the formation of 2,2'-biquinizarin from quinizarin anthracenone. The K-Mapp and V-max values for alizarin and purpurin were 97 and 95 muM, and 1.5 and 2.1 muM min(-1) mg prot(-1), respectively. The results suggest that peroxidase may participate in the biogenesis of anthraquinones. (C) 2002 Elsevier Science Ltd. All rights reserved.
• DE274784
  申请人：——

  公开号：——

  公开（公告）日：——
• Scholl, Chemische Berichte, 1919, vol. 52, p. 1835
  作者：Scholl

  DOI：——

  日期：——
• DE274783
  申请人：——

  公开号：——

  公开（公告）日：——