3-butene-2-ol, sodium salt | 79345-30-5

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: 3-butene-2-ol, sodium salt
• 英文别名: Sodium;but-3-en-2-olate
• CAS: 79345-30-5
• 化学式: C₄H₇O*Na
• 分子量: 94.0887
• InChiKey: PJIGYTKEDCYYQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.07
• 重原子数：
  6
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  23.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  氯化铋 、 3-butene-2-ol, sodium salt 以 四氢呋喃 为溶剂， 以54%的产率得到[Bi(3-butene-2-ol-H)3]
  参考文献：
  名称：

  Bismuth Allyloxides

  摘要：

  Bismuth allyloxides, [Bt(OR)(3)] with R = CH2CH=CH2, CH(CH3)CH=CH2, C(CH3)(2)CH=CH2, and CH2CH-C(CH3)(2), can be prepared by alcoholysis of [Bi(O'Bu)(3)] and, in some cases, also via salt metathesis reactions starting from BiCl3 and sodium allylates They are readily soluble in common organic solvents, and NMR spectroscopic investigations do not provide any hint to aggregated species or any equilibria in solution. The majority of the compounds also proved volatile enough to be purified by sublimation Crystal structure analyses, however, provided evidence for a high degree of aggregation in the solid state, which leads to large rings and chains as structural motifs.

  DOI：

  10.1021/ic100171f

文献信息

• APPLICATIONS OF THE TANDEM [2,3]-WITTIG-OXY-COPE REARRANGEMENT TO SYNTHESES OF<i>exo</i>-BREVICOMIN AND OXOCRINOL. THE SCOPE AND LIMITATION OF THE SIGMATROPIC SEQUENCES AS A SYNTHETIC METHOD FOR δ,ε-UNSATURATED KETONES
  作者：Koichi Mikami、Takeshi Nakai

  DOI：10.1246/cl.1982.1349

  日期：1982.9.5

  The synthetic utility of the title sigmatropic sequence is illustrated in the syntheses of E-6-nonen-2-one, a precursor of exo-brevicomin, and oxocrinol. The scope and limitation of this sequence as a synthetic method for δ,e-unsaturated ketones are also discussed.

  标题 sigmatropic 序列的合成效用在 E-6-nonen-2-one、exo-brevicomin 的前体和 oxocrinol 的合成中得到了说明。还讨论了该序列作为 δ,e-不饱和酮的合成方法的范围和限制。
• Substituent effects in the aliphatic Claisen rearrangement of substituted (1-methyl-3-oxahexa-1,5-dienyl)amines: synthesis of substituted 2-aminopent-4-enals. Alternative [1,3]-sigmatropic shifts in related aromatic systems
  作者：Jose Barluenga、Fernando Aznar、Ramon Liz、Miguel Bayod

  DOI：10.1021/jo00232a024

  日期：1987.11
• Reaction of alkoxides with phenylthiocarbene: a novel oxy-anionic substituent effect on the carbon-hydrogen insertion of carbenes
  作者：Toshiro Harada、Akira Oku

  DOI：10.1021/ja00409a079

  日期：1981.9
• Synthetic approach to versatile chiral molecules containing a fluorine atom
  作者：Tomoya Kitazume、Yoshimichi Nakayama

  DOI：10.1021/jo00364a034

  日期：1986.7
• KUBOTA, TOSHIO;KONDOH, YASUO;OHYAMA, TOSHIHIRO;TANAKA, TATSUO, NIPPON KAGAKU KAJSI,(1989) N, S. 1576-1588
  作者：KUBOTA, TOSHIO、KONDOH, YASUO、OHYAMA, TOSHIHIRO、TANAKA, TATSUO

  DOI：——

  日期：——