4-{3-(triallylsilyl)propyl}phenylbromide | 1416769-59-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-{3-(triallylsilyl)propyl}phenylbromide
• 英文别名: 4-{3-(Triallylsilyl)propyl}phenylbromide；3-(4-bromophenyl)propyl-tris(prop-2-enyl)silane
• CAS: 1416769-59-9
• 化学式: C₁₈H₂₅BrSi
• 分子量: 349.386
• InChiKey: QNMHXERDYFGVDE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.39
• 重原子数：
  20
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  4-{3-(triallylsilyl)propyl}phenylbromide 在 sodium tetrahydroborate 、 正丁基锂 、 四溴化碳 、 异丙基氯化镁 、 三苯基膦 作用下， 以 四氢呋喃 、 甲醇 、 二氯甲烷 为溶剂， 反应 20.0h， 生成 4-{3-(triallylsilyl)propyl}benzyl bromide
  参考文献：
  名称：

  (METH) ALLYLSILANE COMPOUND, SILANE COUPLING AGENT THEREFOR, AND FUNCTIONAL MATERIAL USING SAME

  摘要：

  公开号：

  EP2727923B1
• 作为产物：
  描述：

  1,4-二溴苯 在 正丁基锂 、 bis(tetrabutylammonium) hexachloroplatinate(IV) 、 异丙基氯化镁 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 、 二氯甲烷 为溶剂， 反应 43.0h， 生成 4-{3-(triallylsilyl)propyl}phenylbromide
  参考文献：
  名称：

  (METH) ALLYLSILANE COMPOUND, SILANE COUPLING AGENT THEREFOR, AND FUNCTIONAL MATERIAL USING SAME

  摘要：

  公开号：

  EP2727923B1

文献信息

• (METH)ALLYLSILANE COMPOUND, SILANE COUPLING AGENT THEREFOR, AND FUNCTIONAL MATERIAL USING SAME
  申请人：Shimada Toyoshi

  公开号：US20140142292A1

  公开（公告）日：2014-05-22

  A (meth)allylsilane compound chemically bonded to various alcohol derivatives including polyol derivatives such as saccharides, is raw material used to cause a substrate to express functionalities such as a defogging property and separation characteristics for column chromatography, can be easily prepared, is easily purified, and is stable and easy to handle, and a functional material in which those functionalities are expressed, while silyl group-containing groups are conveniently carried at a high density on the surface of the substrate, by using the (meth)allylsilane compound as a silane coupling agent for silane-coupling to the substrate. The (meth)allylsilane compound includes a (meth)allylsilyl group-containing alkyl group or a (meth)allylsilylalkyl group-containing aralkyl group that is bonded to an alcohol derivative. In the functional material, the silane coupling agent is ether-bonded to surface hydroxyl groups exposed on a substrate through the surface hydroxyl groups by silane coupling to have an ether bond on the functional material.

  一种(meth)allylsilane化合物，与多种醇衍生物包括多元醇衍生物如糖类化合物化学键合，是用于使基底表达去雾特性和柱层析分离特性等功能的原材料，可以轻松制备、易于纯化、稳定易于处理，通过使用(meth)allylsilane化合物作为硅烷偶联剂对基底进行硅烷偶联，便可方便地在基底表面高密度携带含硅基团的基团，并表达这些功能的功能性材料。 (meth)allylsilane化合物包括与醇衍生物键合的(meth)allylsilyl基团含有的烷基或(meth)allylsilyl烷基含有的芳基烷基。在功能性材料中，硅烷偶联剂通过硅烷偶联与基底表面暴露的表面羟基结合，使其在功能性材料上具有醚键。
• (METH)ALLYLSILANE COMPOUND, SILANE COUPLING AGENT THEREOF, AND FUNCTIONAL MATERIAL USING THE SAME
  申请人：Shimada Toyoshi

  公开号：US20140200311A1

  公开（公告）日：2014-07-17

  A (meth)allylsilane compound that a functional group of a (meth)allylsilyl group or a halogenosilyl group bonded to the (meth)allylsilyl group via a spacer group is bonded directly or through a divergent spacer group to a dehydrogenated residue of an amino group of an amino group-containing compound; a carbaminic acid ester group or an amide group derived from a dehydrogenated residue of the amino group; an aromatic compound; a polymerizable unsaturated groups; perfluoro group; a dehydrogenated residue of saccharide or a carbohydrate polyol (excluding when the divergent spacer group is an alkylene group, or an alkylene group and an arylene group); a dehydrogenated residue of an amino acid; a halogenosilyl group; or a substituted silyl group in which a halogen of the halogenosilyl group is substituted.

  一种(meth)allylsilane化合物，其中一个(meth)allylsilyl基团或卤代silyl基团通过间隔基团直接或通过分散的间隔基团与含氨基化合物的氨基残基的脱氢残基；一个由氨基残基脱氢得到的氨基酸酯基团或酰胺基团；一个芳香化合物；一个可聚合的不饱和基团；全氟基团；糖或碳水化合物多元醇的脱氢残基（当分散的间隔基团是一个烷基或一个烷基和一个芳基时除外）；一个氨基酸的脱氢残基；一个卤代silyl基团；或卤代silyl基团的卤素被取代的取代silyl基团上的官能团，与(meth)allylsilyl基团键合。
• (Meth)allylsilane compound, silane coupling agent thereof, and functional material using the same
  申请人：Shimada Toyoshi

  公开号：US09228107B2

  公开（公告）日：2016-01-05

  A (meth)allylsilane compound that a functional group of a (meth)allylsilyl group or a halogenosilyl group bonded to the (meth)allylsilyl group via a spacer group is bonded directly or through a divergent spacer group to a dehydrogenated residue of an amino group of an amino group-containing compound; a carbaminic acid ester group or an amide group derived from a dehydrogenated residue of the amino group; an aromatic compound; a polymerizable unsaturated groups; perfluoro group; a dehydrogenated residue of saccharide or a carbohydrate polyol (excluding when the divergent spacer group is an alkylene group, or an alkylene group and an arylene group); a dehydrogenated residue of an amino acid; a halogenosilyl group; or a substituted silyl group in which a halogen of the halogenosilyl group is substituted.

  一种（甲基）烯丙基硅烷化合物，其中一个（甲基）烯丙基硅基团或卤代硅基团通过一个间隔基团直接或通过一个分支间隔基团与含氨基化合物的氨基残基的脱氢残基结合；一种由氨基残基的脱氢残基衍生的氨基甲酸酯基团或酰胺基团；芳香族化合物；可聚合不饱和基团；全氟基团；糖或碳水化合物多元醇的脱氢残基（当分支间隔基团为烷基或烷基和芳基时除外）；氨基酸的脱氢残基；卤代硅基团；或卤素被取代的卤代硅基团中的取代硅基团。
• (Meth)allylsilane compound, silane coupling agent therefor, and functional material using same
  申请人：Shimada Toyoshi

  公开号：US09409929B2

  公开（公告）日：2016-08-09

  A (meth)allylsilane compound chemically bonded to various alcohol derivatives including polyol derivatives such as saccharides, is raw material used to cause a substrate to express functionalities such as a defogging property and separation characteristics for column chromatography, can be easily prepared, is easily purified, and is stable and easy to handle, and a functional material in which those functionalities are expressed, while silyl group-containing groups are conveniently carried at a high density on the surface of the substrate, by using the (meth)allylsilane compound as a silane coupling agent for silane-coupling to the substrate. The (meth)allylsilane compound includes a (meth)allylsilyl group-containing alkyl group or a (meth)allylsilylalkyl group-containing aralkyl group that is bonded to an alcohol derivative. In the functional material, the silane coupling agent is ether-bonded to surface hydroxyl groups exposed on a substrate through the surface hydroxyl groups by silane coupling to have an ether bond on the functional material.

  一种(meth)allylsilane化合物，化学上与各种醇衍生物包括多元醇衍生物如糖类化合物结合，是用于使底物表达去雾性和柱层析分离特性等功能的原材料，可以轻松制备，易于纯化，稳定且易于处理，并且使用(meth)allylsilane化合物作为硅烷偶联剂进行硅烷偶联到底物表面，方便地携带含有硅基团的基团高密度地存在于底物表面上，从而表达这些功能的功能性材料。 (meth)allylsilane化合物包括与醇衍生物结合的(meth)allylsilyl基团含有的烷基或(meth)allylsilyl烷基含有的芳基烷基。在功能性材料中，硅烷偶联剂通过硅烷偶联与底物表面暴露的表面羟基结合，形成醚键，连接在功能性材料上。
• (METH) ALLYLSILANE COMPOUND, SILANE COUPLING AGENT THEREFOR, AND FUNCTIONAL MATERIAL USING SAME
  申请人：Shimada, Toyoshi

  公开号：EP2727923B1

  公开（公告）日：2017-10-18