(2,4-dimethylphenyl)(o-tolyl)methanone | 13152-98-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,4-dimethylphenyl)(o-tolyl)methanone
• 英文别名: 2,4,2'-trimethyl-benzophenone；α-Oxo-2.4.2'-trimethyl-diphenylmethan；o-Tolyl-(2.4-dimethyl-phenyl)-keton；2,4,2'-Trimethyl-benzophenon；(2,4-Dimethylphenyl)(2-methylphenyl)methanone；(2,4-dimethylphenyl)-(2-methylphenyl)methanone
• CAS: 13152-98-2
• 化学式: C₁₆H₁₆O
• mdl: MFCD01123318
• 分子量: 224.302
• InChiKey: HKJNGBXQWSMYIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.187
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (2,4-dimethylphenyl)(o-tolyl)methanone 在 羟胺 作用下， 生成 2-methyl-benzoic acid-(2,4-dimethyl-anilide)
  参考文献：
  名称：

  Smith, Chemische Berichte, 1891, vol. 24, p. 4047

  摘要：

  DOI：
• 作为产物：
  描述：

  邻甲基苯甲酰氯 、 间二甲苯 在 三氯化铝 作用下， 生成 (2,4-dimethylphenyl)(o-tolyl)methanone
  参考文献：
  名称：

  Smith, Chemische Berichte, 1891, vol. 24, p. 4047

  摘要：

  DOI：

文献信息

• Transition-metal-free, ambient-pressure carbonylative cross-coupling reactions of aryl halides with potassium aryltrifluoroborates
  作者：Fengli Jin、Wei Han

  DOI：10.1039/c5cc01968k

  日期：——

  We disclose an unprecedented transition-metal-free carbonylative cross coupling of aryl halides with potassium aryl trifluoroborates even at atmospheric pressure of carbon monoxide. This protocol is efficient, operationally simple, and shows...

  我们公开了空前的无过渡金属的芳基卤化物与芳基三氟硼酸钾的无过渡金属羰基交叉偶合，即使在一氧化碳的大气压下也是如此。该协议高效，操作简单，并显示...
• Dem'yanovich; Shishkina; Borisenko, Russian Journal of Organic Chemistry, 2000, vol. 36, # 8, p. 1168 - 1172
  作者：Dem'yanovich、Shishkina、Borisenko

  DOI：——

  日期：——
• New chiral ligands: 1,4-diols prepared from (S)-1-phenylethanol
  作者：I. N. Shishkina、E. Yu. Sokolovskaya、K. A. Potekhin、Yu. V. Nelyubina、R. K. Askerov、V. M. Dem’yanovich

  DOI：10.1134/s1070428010090125

  日期：2010.9

  The stereochemistry of condensation of dilithiated 1-phenylethanol with various carbonyl compounds was investigated. In most cases the reaction proceeds nonstreoselectively, and only in the condensation with PhCOBu-t and 2,4-(MeO)(2)C(6)H(3)COPh only one of the diastereomeric diols prevailed. It was shown by XRD analysis that in the prevailing diastereomeric diol the newly formed chiral carbinol center possessed the same configuration as the initial alcohol. The synthesized diols form homochiral dimers in the crystal lattice.
• PHOTOSENSITIVE COLORING COMPOSITION AND METHOD OF MANUFACTURING OPTICAL FILTER
  申请人：FUJIFILM Corporation

  公开号：US20200225576A1

  公开（公告）日：2020-07-16

  Provided is a photosensitive coloring composition with which a pixel having excellent adhesiveness with a support and excellent rectangularity can be formed. In addition, provided is also a method of manufacturing an optical filter including a pixel having excellent adhesiveness with a support and excellent rectangularity. This photosensitive coloring composition is a photosensitive coloring composition for exposure to light having a wavelength of 300 nm or shorter, the photosensitive coloring composition including a coloring material and a curable compound. In a case where a film having a thickness of 0.5 μm after drying is formed using the photosensitive coloring composition, an optical density of the above-described film with respect to light having a wavelength of 248 nm is 1.6 or higher. It is preferable that a content of the coloring material is 50 mass % or higher with respect to a total solid content of the photosensitive coloring composition.
• PHOTOSENSITIVE COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：US20200392344A1

  公开（公告）日：2020-12-17

  Provided is a photosensitive composition including a radically polymerizable compound, a photoradical polymerization initiator, and at least one selected from a chain transfer agent or a radical trapping agent.