1-巯基蒽醌 | 6338-09-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 1-巯基蒽醌
• 英文名称: 1-mercapto-anthraquinone
• 英文别名: α-anthraquinonyl mercaptane；1-Mercapto-anthrachinon；Anthraquinone, 1-mercapto-；1-sulfanylanthracene-9,10-dione
• CAS: 6338-09-6
• 化学式: C₁₄H₈O₂S
• 分子量: 240.282
• InChiKey: YHCIQYSVFONICB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.1
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2930909090

反应信息

• 作为反应物：
  描述：

  1-巯基蒽醌 在 potassium hexacyanoferrate(III) 作用下， 生成 bis(1-anthraquinonyl) disulfide
  参考文献：
  名称：

  Gattermann, Justus Liebigs Annalen der Chemie, 1912, vol. 393, p. 194

  摘要：

  DOI：
• 作为产物：
  描述：

  1-氯蒽醌 在 sodium sulfide 、 乙醇 作用下， 生成 1-巯基蒽醌
  参考文献：
  名称：

  DE206536

  摘要：

  公开号：

文献信息

• POLYMERIC DYES
  申请人：Cremer Christian

  公开号：US20100192312A1

  公开（公告）日：2010-08-05

  A highly crosslinked polysiloxane dye comprising at least 10 Si atoms, including at least one moiety of the formula (I) whose open Si-bonds each are linked to an oxygen atom and open O-bond is linked to a silicon atom in the rest of the polysiloxane, and wherein T is a direct bond or an organic spacer group such as C 1 -C 18 alkylene, C 2 -C 12 alkenylene, C 5 -C 10 cycloalkylene, C 5 -C 10 arylene, —C 5 -C 10 arylene-(C 1 -C 10 alkylene)- each of which may be end-capped towards the linkage to Dye by CO, COO, NR 1 , CONR 1 , NR 1 CONR 1 , CS, CSS, CSNR 1 , NR 1 CSNR 1 , O, S, SO, SO 2 , C 5 -C 10 cycloalkylene, C 5 -C 10 arylene; or T is C 3 -C 18 alkylene interrupted, and optionally end-capped towards the linkage to Dye, by CO, COO, NR 1 , CONR 1 , NR 1 CONR 1 , CS, CSS, CSNR 1 , NR 1 CSNR 1 , O, S, SO, —SO 2 —, C 5 -C 10 cycloalkylene, C 5 -C 10 arylene; or is CO; (CH 2 CH 2 —O) 1-5 ; COO; N(R 1 ); CON(R 1 ); O; S; SO; SO 2 ; R 1 is hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl-C 1 -C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl); and Dye is a residue of an organic dye, is useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides.

  一种高度交联的聚硅氧烷染料，包括至少10个硅原子，其中至少有一个公式（I）的基团，其开放的硅键分别与氧原子相连，开放的O键与聚硅氧烷中的硅原子相连，其中T是直接键或有机间隔基团，例如C1-C18烷基，C2-C12烯基，C5-C10环烷基，C5-C10芳基，-C5-C10芳基-(C1-C10烷基)-，每个基团都可以通过CO，COO，NR1，CONR1，NR1CONR1，CS，CSS，CSNR1，NR1CSNR1，O，S，SO，SO2，C5-C10环烷基，C5-C10芳基端盖连接到染料；或T是C3-C18烷基中断，并且可以通过CO，COO，NR1，CONR1，NR1CONR1，CS，CSS，CSNR1，NR1CSNR1，O，S，SO，-SO2-，C5-C10环烷基，C5-C10芳基端盖连接到染料；或是CO;（CH2CH2-O）1-5; COO; N（R1）; CON（R1）; O; S; SO; SO2; R1是氢; 未取代或取代的，直链或支链，单环或多环，中断或未中断的C1-C14烷基; C2-C14烯基; C6-C10芳基; C6-C10芳基-C1-C10烷基; 或C5-C10烷基（C5-C10芳基）;染料是有机染料的残基，用于有机材料的染色，例如角蛋白含量的纤维，羊毛，皮革，丝绸，纤维素或聚酰胺。
• Substituent-Determined Intramolecular Hydrogen Transfer for Photopromoted Intermolecular Cycloaddition of Anthraquinones with Aryl Olefins
  作者：Fanyuanhang Yang、Ping Lin、Biping Xu、Yuzhen Gao、Weiping Su

  DOI：10.1021/acs.orglett.3c03354

  日期：2023.11.24

  The formation of intramolecular hydrogen bonds in anthraquinones makes them inert to photoinduced reactions; therefore, it is a great challenge to phototransform these compounds. Herein, we reported a formal visible-light-induced [4 + 2] cycloaddition of both 1-hydroxyanthraquinones and 1-aminoanthraquinones with olefins under external photocatalyst-free conditions with high regioselectivity. More

  蒽醌中分子内氢键的形成使其对光诱导反应呈惰性；因此，对这些化合物进行光转化是一个巨大的挑战。在此，我们报道了在无外部光催化剂的条件下，1-羟基蒽醌和1-氨基蒽醌与烯烃的正式可见光诱导[4 + 2]环加成反应，具有高区域选择性。公开了 60 多种底物，证明了该方案构建多种功能化蒽醌衍生物的可靠性。
• Non-aqueous type pigment dispersing agent, composition containing thereof, and non-aqueous pigment dispersion
  申请人：TOYO INK MANUFACTURING CO., LTD.

  公开号：EP0763378A2

  公开（公告）日：1997-03-19

  The present invention provide a non-aqueous type pigment dispersing agent having at least one portion which has a high affinity with a pigment and which has at least one type selected from the group consisting of an organic dye, anthraquinone and acridone only at a terminal end or at both terminal ends of at least one polymer selected from a linear urethanic polymer and a linear acrylic polymer, a pigment composition using the same and a pigment dispersion. The portion having a high affinity with the pigment can be adsorbed efficiently on the surface of a pigment. At the same time pigment, for example, used for ink or paint can be dispersed stably due to the affinity between the polymer portion and a disperse medium to improve the adaptability in use and the quality of coated products.

  本发明提供了一种非水型颜料分散剂，该分散剂至少有一部分与颜料具有高亲和力，并且至少有一种选自有机染料、蒽醌和吖啶酮的类型，仅位于至少一种选自线型氨基甲酸酯聚合物和线型丙烯酸聚合物的聚合物的一端或两端，还提供了使用该分散剂的颜料组合物和颜料分散体。与颜料具有高亲和力的部分可以有效地吸附在颜料表面。同时，由于聚合物部分与分散介质之间的亲和性，用于油墨或涂料等的颜料可以稳定分散，从而提高使用适应性和涂层产品的质量。
• ELECTROLYTE SOLUTION CONTAINING MAGNESIUM IONS
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：EP3439097A1

  公开（公告）日：2019-02-06

  An object of the present invention is to provide a highly practical electrolytic solution which has a high oxidative decomposition potential, enables the dissolution and precipitation of magnesium to stably repeatedly proceed, and is easy to prepare. The present invention relates to an electrolytic solution for a magnesium battery comprising: a compound represented by the general formula (I), a Lewis acid or a compound represented by the general formula (A), and a solvent; and to the compound represented by the general formula (I). In the formula (I), two X's each independently represent a halogeno group, and R1 represents an alkyl group having 1 to 6 carbon atoms; an alkoxy group having 1 to 6 carbon atoms; a phenoxy group; a -OMgX group (X is the same as X described above); an aryl group having 6 to 18 carbon atoms which has, as a substituent, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a vinyl group, a phenyl group, a phenoxy group, a halogeno group or a -B(OMgX)2 group (X is the same as X described above) or is unsubstituted; or a monocyclic or bicyclic heterocyclic group which has, as a substituent, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a vinyl group, a phenyl group, a phenoxy group, a halogeno group, or a -B(OMgX)2 group (X is the same as X described above) or is unsubstituted. In the general formula (A), four R6's each independently represent an alkyl group having 1 to 6 carbon atoms, a perfluoroalkyl group having 1 to 6 carbon atoms, a phenyl group, or a perfluorophenyl group.

  本发明的目的是提供一种实用性很强的电解溶液，它具有很高的氧化分解电位，能使镁的溶解和沉淀稳定地反复进行，并且易于制备。本发明涉及一种用于镁电池的电解溶液，包括：通式（I）代表的化合物、路易斯酸或通式（A）代表的化合物和溶剂；以及通式（I）代表的化合物。在式 (I) 中，两个 X 各自独立地代表卤代基团，R1 代表具有 1 至 6 个碳原子的烷基；具有 1 至 6 个碳原子的烷氧基；苯氧基；-OMgX 基团（X 与上述 X 相同）；具有 6 至 18 个碳原子的芳基，其取代基为具有 1 至 6 个碳原子的烷基、具有 1 至 6 个碳原子的烷氧基、乙烯基、苯基、苯氧基、卤素基或-B(OMgX)2 基（X 与上述 X 相同），或未被取代；或单环或双环杂环基团，其取代基为具有 1 至 6 个碳原子的烷基、具有 1 至 6 个碳原子的烷氧基、乙烯基、苯基、苯氧基、卤素基团或-B(OMgX)2 基团（X 与上述 X 相同）或未被取代的基团。在通式（A）中，四个 R6 各自独立地代表具有 1 至 6 个碳原子的烷基、具有 1 至 6 个碳原子的全氟烷基、苯基或全氟苯基。
• PHOSPHORUS ELECTROLYTIC SOLUTION CONTAINING MAGNESIUM IONS
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：EP3467931A1

  公开（公告）日：2019-04-10

  The present invention relates to an electrolytic solution for a magnesium battery, formed by mixing a compound represented by the following general formula (I), a Lewis acid or a compound represented by the following general formula (A), and a solvent; and the like. In the formula, m represents 0 or 2, n represents 2 in a case of m=0 and represents 0 or 1 in a case of m=2, X1 represents a chlorine atom or a bromine atom, and two R1's each independently represent a magnesium chloride oxy group; a magnesium bromide oxy group; an alkyl group which may have a halogeno group or the like as a substituent; an alkoxy group; an aryl group which may have an alkoxy group or the like as a substituent; an aryloxy group which may have an alkoxy group or the like as a substituent; or a group represented by the following general formula (1), and two R1's may also form the following general formula (2).}         Mg [N(SO2R10)2]2     (A) (In the formula, four R10's each independently represent an alkyl group, a perfluoroalkyl group, a phenyl group, or a perfluorophenyl group.)

  本发明涉及一种用于镁电池的电解溶液，该溶液由以下通式（I）代表的化合物、路易斯酸或以下通式（A）代表的化合物和溶剂等混合而成。 在式中，m 代表 0 或 2，n 在 m=0 的情况下代表 2，在 m=2 的情况下代表 0 或 1，X1 代表氯原子或溴原子，两个 R1 各自独立地代表氯化镁氧基；溴化镁氧基；烷基，其取代基可以是卤代基或类似物；烷氧基；可具有烷氧基或类似基团作为取代基的芳基；可具有烷氧基或类似基团作为取代基的芳氧基；或由以下通式(1)表示的基团，两个 R1 还可组成以下通式(2)。} 镁[N(SO2R10)2]2 (A) (式中，四个 R10 各自独立地代表一个烷基、一个全氟烷基、一个苯基或一个全氟苯基）。