anthraquinone-1-sulfonyl chloride | 4025-69-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: anthraquinone-1-sulfonyl chloride
• 英文别名: anthraquinone-2-sulfonyl chloride；1-anthraquinonesulfonyl chloride；9,10-dioxo-9,10-dihydro-anthracene-1-sulfonyl chloride；9,10-Dioxo-9,10-dihydro-anthracen-1-sulfonylchlorid；Anthrachinon-1-sulfonylchlorid；1-Chlorosulfonylanthraquinone；9,10-dioxoanthracene-1-sulfonyl chloride
• CAS: 4025-69-8
• 化学式: C₁₄H₇ClO₄S
• 分子量: 306.726
• InChiKey: YRHBFXZMYZMWFO-UHFFFAOYSA-N

物化性质

• 熔点：
  218 °C
• 沸点：
  514.8±39.0 °C(Predicted)
• 密度：
  1.567±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.7
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2914700090

反应信息

• 作为反应物：
  描述：

  anthraquinone-1-sulfonyl chloride 生成 1-氯蒽醌
  参考文献：
  名称：

  Ullmann; Kertesz, Chemische Berichte, 1919, vol. 52, p. 555

  摘要：

  DOI：
• 作为产物：
  描述：

  1-蒽醌磺酸 在 氯化亚砜 作用下， 生成 anthraquinone-1-sulfonyl chloride
  参考文献：
  名称：

  Meyer,H.; Schlegl, Monatshefte fur Chemie, 1913, vol. 34, p. 576

  摘要：

  DOI：

文献信息

• Fluorescence as a Means for Kinetic Studies. III. Bimolecular Reaction of Fluorescent Reagent as Quenching Probes
  作者：Hideharu Ushiki、Akio Okamoto、Kazuyuki Horie、Itaru Mita

  DOI：10.1246/bcsj.56.3181

  日期：1983.10

  In order to study the rate of bimolecula reaction between 9-(3-aminopropyl)carbazole and dansyl chloride, the change of fluorescent intensity of dansyl group has been measured. It has been found that the rate of increase in fluorescent intensity of the dansyl group is equal to the rate of decrease in fluorescent intensity of the carbazolyl group during progress of this bimolecular reaction. Another

  为了研究9-(3-氨基丙基)咔唑与丹磺酰氯的双分子反应速率，测定了丹磺酰基团荧光强度的变化。已经发现，在该双分子反应过程中，丹磺酰基荧光强度的增加速率等于咔唑基荧光强度的降低速率。还简要检查了另一种淬灭探针。
• ARYLSULFINATE SALTS IN INITIATOR SYSTEMS FOR POLYMERIC REACTIONS
  申请人：Kalgutkar S. Rajdeep

  公开号：US20060111462A1

  公开（公告）日：2006-05-25

  Compositions are provided that that can be used as an initiator system for free radical polymerization reactions. More specifically, the initiator systems include an electron acceptor and an electron donor. The electron donors are arylsulfinate salts having a cation that contains at least one carbon atom and either a positively charged nitrogen atom or a positively charged phosphorus atom. Methods of polymerization are also provided that can be used to prepare polymeric material with the initiator systems. The initiator systems can be thermal initiator systems, photoinitiator systems, or combinations thereof.

  提供了可用作自由基聚合反应起始剂系统的组合物。更具体地说，该起始剂系统包括一个电子受体和一个电子给体。电子给体是含有至少一个碳原子和一个带正电氮原子或带正电磷原子的阳离子的芳基磺酰盐。还提供了可以使用该起始剂系统制备聚合材料的聚合方法。该起始剂系统可以是热起始剂系统、光引发剂系统或两者的组合。
• Arylsulfinate salts in initiator systems for polymeric reactions
  申请人：Kalgutkar S. Rajdeep

  公开号：US20050070622A1

  公开（公告）日：2005-03-31

  Compositions are provided that that can be used as an initiator system for free radical polymerization reactions. More specifically, the initiator systems include an electron acceptor and an electron donor. The electron donors are arylsulfinate salts having a cation that contains at least one carbon atom and either a positively charged nitrogen atom or a positively charged phosphorus atom. Methods of polymerization are also provided that can be used to prepare polymeric material with the initiator systems. The initiator systems can be thermal initiator systems, photoinitiator systems, or combinations thereof.

  提供了可用作自由基聚合反应的引发剂体系的组合物。更具体地，引发剂体系包括一个电子受体和一个电子给体。电子给体是含有至少一个碳原子和一个带正电荷的氮原子或磷原子的芳基磺酸盐阳离子。还提供了用于制备聚合材料的聚合方法。引发剂体系可以是热引发剂体系、光引发剂体系或两者的组合。
• Arylsulfinate salts in photoinitiator systems for polymerization reactions
  申请人：Kalgutkar S. Rajdeep

  公开号：US20050070624A1

  公开（公告）日：2005-03-31

  Compositions are provided that include an electron donor and a sensitizing compound. More specifically, the electron donor is an arylsulfinate salt. Methods of polymerization are also provided that can be used to prepare polymeric material from a photopolymerizable composition that includes ethylenically unsaturated monomers and a photoinitiator system. The photoinitiator system includes an electron donor and a sensitizing compound.

  提供了包括电子供体和敏化化合物的组合物。更具体地，电子供体是芳基亚磺酸盐。还提供了聚合的方法，可以用于从光聚合组合物中制备聚合材料，该组合物包括乙烯基不饱和单体和光引发剂体系。光引发剂体系包括电子供体和敏化化合物。
• ARYSULFINATE SALTS IN PHOTOINITIATOR SYSTEMS FOR POLYMERIZATION REACTIONS
  申请人：Kalgutkar S. Rajdeep

  公开号：US20070249749A1

  公开（公告）日：2007-10-25

  Compositions are provided that include an electron donor and a sensitizing compound. More specifically, the electron donor is an arylsulfinate salt. Methods of polymerization are also provided that can be used to prepare polymeric material from a photopolymerizable composition that includes ethylenically unsaturated monomers and a photoinitiator system. The photoinitiator system includes an electron donor and a sensitizing compound.

  提供了包括电子给体和感光化合物的复合物。更具体地，电子给体是芳基磺酸盐。还提供了聚合方法，可用于从光聚合可聚合物组成物中制备聚合材料。光引发剂系统包括电子给体和感光化合物。