bis-iodo{N-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diamine}platinum(II) | 135389-34-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis-iodo{N-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diamine}platinum(II)
• CAS: 135389-34-3
• 化学式: C₈H₈F₄I₂N₂Pt
• 分子量: 657.048
• InChiKey: QLZVVGVWHYHVMO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  六氟苯 、 bis-iodo{N-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diamine}platinum(II) 在 TlO₂CC₆F₄H 作用下， 以 吡啶 为溶剂， 以19%的产率得到{N-(pentafluorophenyl)-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato(2-)}dipyridineplatinum(II)*0.4Et2O
  参考文献：
  名称：

  Organoamidometallics—IV. Syntheses of N,N′-bis(polyfluorophenyl)ethane-1,2-diaminato(2−)platinum(II) complexes with two different fluorocarbon groups

  摘要：

  The N,N'-bis(polyfluorophenyl)ethane-1,2-diaminato(2-)platinum(II) complexes [Pt(N(p-HC6F4)CH2CH2NR)(py)2] (R = p-HC6F4, p-BrC6F4, C6F5 or p-MeC6F4; py = pyridine) have been prepared by decarboxylation reactions between [PtI2(p-HC6F4NHCH2CH2NH2)], thallium(I) 2,3,5,6-tetrafluorobenzate and a suitable polyfluorobenzene, RF, in hot dry pyridine. When R not-equal p-HC6F4, the two different polyfluorophenyl groups can be distinguished by different F3,5 resonances in the F-19 NMR spectra. The reactant and analogous complexes [PtX2(RNHCH2CH2NH2)](R = p-HC6F4, X = I or Cl; R = C6F5, X = I) were prepared by treatment of K2PtX4(X = I or Cl) with the appropriate N-polyfluorophenylethane-1,2-diamine.

  DOI：

  10.1016/s0277-5387(00)83764-x
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 N-(2,3,5,6-tetrafluorophenyl)-1,2-diaminoethane 在 potassium iodide 作用下， 以 乙醇 、 水 为溶剂， 以16%的产率得到bis-iodo{N-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diamine}platinum(II)
  参考文献：
  名称：

  Organoamidometallics—IV. Syntheses of N,N′-bis(polyfluorophenyl)ethane-1,2-diaminato(2−)platinum(II) complexes with two different fluorocarbon groups

  摘要：

  The N,N'-bis(polyfluorophenyl)ethane-1,2-diaminato(2-)platinum(II) complexes [Pt(N(p-HC6F4)CH2CH2NR)(py)2] (R = p-HC6F4, p-BrC6F4, C6F5 or p-MeC6F4; py = pyridine) have been prepared by decarboxylation reactions between [PtI2(p-HC6F4NHCH2CH2NH2)], thallium(I) 2,3,5,6-tetrafluorobenzate and a suitable polyfluorobenzene, RF, in hot dry pyridine. When R not-equal p-HC6F4, the two different polyfluorophenyl groups can be distinguished by different F3,5 resonances in the F-19 NMR spectra. The reactant and analogous complexes [PtX2(RNHCH2CH2NH2)](R = p-HC6F4, X = I or Cl; R = C6F5, X = I) were prepared by treatment of K2PtX4(X = I or Cl) with the appropriate N-polyfluorophenylethane-1,2-diamine.

  DOI：

  10.1016/s0277-5387(00)83764-x