2,3-bis(fluorosulfato)perfluoro-(2-methylpentane) | 132182-90-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 2,3-bis(fluorosulfato)perfluoro-(2-methylpentane)
• 英文别名: 1,1,1,2,2,3,5,5,5-nonafluoro-3,4-bis(fluorosulfonyloxy)-4-(trifluoromethyl)pentane
• CAS: 132182-90-2
• 化学式: C₆F₁₄O₆S₂
• 分子量: 498.172
• InChiKey: WURNCZKVBJKQII-UHFFFAOYSA-N

物化性质

• 沸点：
  48-50 °C(Press: 20 Torr)
• 密度：
  1.924±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.18
• 重原子数：
  28.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  86.74
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  2,3-bis(fluorosulfato)perfluoro-(2-methylpentane) 在 五氟化锑 作用下， 反应 12.0h， 以87%的产率得到perfluoro-2,2-dimethoxy-3-oxolane
  参考文献：
  名称：

  Electrophilic isomerization of fluoroaliphatic oxygen-containing compounds

  摘要：

  An unusual electrophilic cyclization of fluorine-containing carbonyl compounds and alpha-oxides was discovered. Upon the action of SbF5, perfluorinated ketones, diketones, and alpha-oxides isomerize to oxolanes. This reaction proceeds with the obligatory participation of the terminal CF3 group.

  DOI：

  10.1007/bf00961053
• 作为产物：
  描述：

  全氟(2-甲基-2-戊烯) 、 氟磺酸 生成 2,3-bis(fluorosulfato)perfluoro-(2-methylpentane)
  参考文献：
  名称：

  ROGOVIK, V. M.;KOVALSKIJ, YA. I.;DELYAGINA, N. I.;MYSOV, E. I.;GIDA, V. M+, IZV. AN CCCP. CEP. XIM.,(1990) N, S. 2048-2056

  摘要：

  DOI：

文献信息

• Fluoroaliphatic esters of fluorosulfonic acid. 3. Decomposition of poly(fluorosulfato)perfluoroalkanes under the action of antimony pentafluoride
  作者：V. M. Rogovik、S. D. Chepik、N. I. Delyagina、E. I. Mysov、V. F. Cherstkov、S. R. Sterlin、L. S. German

  DOI：10.1007/bf00958253

  日期：1990.9

  Vicinal bis(fluorosulfato) perfluoroalkanes containing FSO3 groups in the middle of a fluorocarbon chain eliminate one or two molecules of sulfuryl fluoride under the action of SbF5, forming a mixture of isomeric alpha-fluorosulfato ketones and alpha-diketones.
• Fluoroaliphatic esters of fluorosulfonic acid. 2. Reaction of bis(fluorosulfato)perfluoroalkanes with cesium fluoride
  作者：V. M. Rogovik、N. I. Delyagina、E. I. Mysov、V. F. Cherstkov、S. R. Sterlin、L. S. German

  DOI：10.1007/bf00958252

  日期：1990.9

  2,3-Bis(fluorosulfato) perfluoroalkanes split under the action of CsF in the absence of solvents, giving a mixture of alpha-fluorosulfatoperfluoro ketones, perfluoroalkene sulfates, and perfluoro alpha-diketones. The occurrence of these reactions in solutions results mainly in the formation of oxides of the corresponding fluoroolefins or products of their conversions. The reactions carried out are the first examples of nucleophilic substitution at a secondary carbon atom in a perfluorinated saturated chain.
• Fluoroaliphatic esters of fluorosulfonic acid. 1. Reactions of higher fluoroolefins with electrochemically generated peroxydisulfuryl difluoride
  作者：V. M. Rogovik、Ya. I. Koval'skii、N. I. Delyagina、E. I. Mysov、V. M. Gida、V. A. Grinberg、V. F. Cherstkov、S. R. Sterlin、L. S. German

  DOI：10.1007/bf00958251

  日期：1990.9

  The electrolysis of fluorosulfonic acid in the presence of perfluoro-2-alkenes in an electrolyzer without a diaphragm results in the formation of a mixture of products, whose composition is determined by both the anodic and cathodic processes.
• Fluoroaliphatic esters of fluorosulfonic acid. 5. Conjugate radical fluorosulfatohalogenation of higher fluoroolefins
  作者：V. M. Rogovik、A. F. A�rov、N. I. Delyagina、V. F. Cherstkov、S. R. Sterlin、L. S. German

  DOI：10.1007/bf01150910

  日期：1992.4

  A study has been made of the electrochemical fluorosulfation of perfluoro-2-alkenes in the presence of halogens, leading to the formation of fluoroaliphatic vicinal fluorosulfatohalides. The reaction proceeds as a conjugate radical addition of peroxydisulfuryl difluoride and the halogen at the double bond of the olefin; the ratio of the resulting regioisomers is determined by steric factors.
• ROGOVIK, V. M.;DELYAGINA, N. I.;MYSOV, E. I.;CHERSTKOV, V. F.;STERLIN, S.+, IZV. AN CCCP. CEP. XIM.,(1990) N, S. 2057-2063
  作者：ROGOVIK, V. M.、DELYAGINA, N. I.、MYSOV, E. I.、CHERSTKOV, V. F.、STERLIN, S.+

  DOI：——

  日期：——