六氰基苯 | 1217-44-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 六氰基苯
• 中文别名: 苯-1,2,3,4,5,6-六甲腈
• 英文名称: 1,2,3,4,5,6-Hexacyanobenzol
• 英文别名: hexacyanobenzene；Pentacyano-benzonitril；Hexacyan-benzol；Hexacyanobenzol；Hexacyanbenzol；Benzenehexacarbonitrile；benzene-1,2,3,4,5,6-hexacarbonitrile
• CAS: 1217-44-3
• 化学式: C₁₂N₆
• 分子量: 228.172
• InChiKey: YLDBWNXELVQOFK-UHFFFAOYSA-N

物化性质

• 熔点：
  310 °C (decomp)
• 沸点：
  550.8±50.0 °C(Predicted)
• 密度：
  1.53±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  143
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 海关编码：
  2926909090

反应信息

• 作为反应物：
  描述：

  六氰基苯 、 1-N,1-N,3-N,3-N,5-N,5-N-六甲基苯-1,3,5-三胺 以 乙腈 为溶剂， 生成 (TDMAB)(HCNB)
  参考文献：
  名称：

  Keller, H. J.; Niebl, R.; Renner, G., Zeitschrift fur Naturforschung, B: Chemical Sciences, 1989, vol. 44, # 3, p. 327 - 332

  摘要：

  DOI：
• 作为产物：
  描述：

  trichlorotricyanocyclopropane 在 (18-crown-6)potassium 作用下， 以 四氢呋喃 为溶剂， 以25%的产率得到六氰基苯
  参考文献：
  名称：

  Studies on the tricyanocyclopropenyl system

  摘要：

  DOI：

  10.1016/s0040-4039(00)86951-8

文献信息

• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20160072082A1

  公开（公告）日：2016-03-10

  Imidazophenanthridine ligands and metal complexes are provided. The compounds exhibit improved stability through a linking substitution that links a nitrogen bonded carbon of an imidizole ring to a carbon on the adjacent fused aryl ring. The compounds may be used in organic light emitting devices, particularly as emissive dopants, providing devices with improved efficiency, stability, and manufacturing. In particular, the compounds provided herein may be used in blue devices having high efficiency.

  提供了咪唑菲啉配体和金属配合物。这些化合物通过连接取代基展现出改善的稳定性，该连接将咪唑环的氮键合碳与相邻融合芳基环上的碳连接起来。这些化合物可以用于有机发光器件，特别是作为发射杂质，为设备提供改善的效率、稳定性和制造工艺。具体来说，本文提供的化合物可以用于具有高效率的蓝色器件。
• Anhydrous flouride salts and reagents and methods for their production
  申请人：DiMagno G. Stephen

  公开号：US20060089514A1

  公开（公告）日：2006-04-27

  Anhydrous organic fluoride salts and reagents prepared by a method comprising the nucleophilic substitution of a fluorinated aromatic or fluorinated unsaturated organic compound with a salt having the formula: [Q n M] x+ A x − in an inert polar, aprotic solvent; wherein M is an atom capable of supporting a formal positive charge, the n groups Q are independently varied organic moieties, n is an integer such that the [Q n M] carries at least one formal positive charge, x is an integer defining the number of formal positive charge(s), +, carried by the [Q n M], A − is an anionic nucleophile capable of substituting for F in the fluorinated compound and F represents fluorine or a radioisotope thereof.

  由一种方法制备的无水有机氟化物盐和试剂，该方法包括用具有以下公式的盐进行氟化芳香族或氟化不饱和有机化合物的亲核取代：[QnM]x+Ax−，其中M是能够支持正式正电荷的原子，n个Q基团是独立变化的有机基团，n是一个整数，使得[QnM]至少带有一个正式正电荷，x是定义由[QnM]携带的正式正电荷数的整数，+，A−是能够取代氟化合物中F的阴离子亲核试剂，F代表氟或其同位素。
• ORGANIC ELECTROLUMINESCENT DEVICE AND INDOLE DERIVATIVE
  申请人：Igarashi Tatsuya

  公开号：US20100066243A1

  公开（公告）日：2010-03-18

  An organic electroluminescent device is provided and includes: a pair of electrodes; and at least one organic layer between the pair of electrodes, the at least one organic layer including a light-emitting layer containing a light-emitting material. The at least one organic layer includes at least one layer containing an indole derivative represented by formula (1). R 102 , R 103 , R 104 , R 105 and R 106 each independently represents a hydrogen atom or a substituent; R 101 represents a substituent linking via a carbon atom; R 101 and R 106 may be bonded to each other to form a ring; R 107 represents a substituent; n 101 represents 1 or 2; and n 102 represents an integer of from 0 to 5, provided that n 101 +n 102 ≦6.

  提供了一种有机电致发光器件，包括：一对电极；和至少一个位于电极对之间的有机层，该至少一个有机层包括含有发光材料的发光层。该至少一个有机层包括至少一层，其中包含由公式（1）表示的吲哚衍生物。R102、R103、R104、R105和R106各自独立地表示氢原子或取代基；R101表示通过碳原子连接的取代基；R101和R106可以相互连接形成环；R107表示取代基；n101表示1或2；n102表示从0到5的整数，前提是n101 + n102≤6。
• Fluoride relay: a new concept for the rapid preparation of anhydrous nucleophilic fluoride salts from KF
  作者：Haoran Sun、Stephen G. DiMagno

  DOI：10.1039/b614368g

  日期：——

  Fluoride relay is used to generate exceptionally nucleophilic fluoride reagents from KF on a time scale commensurate with radiotracer synthesis.

  氟化物中继用于在与放射性示踪剂合成相称的时间范围内从KF生成异常的亲核氟化物试剂。
• ORGANIC ELECTROLUMINESCENCE DEVICE, NOVEL PLATINUM COMPLEX COMPOUND AND NOVEL COMPOUND CAPABLE OF BEING A LIGAND THEREOF
  申请人：Murakami Takeshi

  公开号：US20090261721A1

  公开（公告）日：2009-10-22

  An organic electroluminescence device, includes: a pair of electrodes; and at least one organic layer including a light emitting layer, the light emitting layer being provided between the pair of electrodes, wherein at least one layer of the at least one organic layer contains a compound represented by formula (1) as defined in the specification.

  一种有机电致发光装置，包括：一对电极；以及至少一层有机层，包括发光层，所述发光层位于电极对之间，其中，所述至少一层有机层中至少含有一种由式（1）所表示的化合物，该式在说明书中有定义。