ethyl 6-(6-(6-(6-(6-(ethoxycarbonyl)pyridin-2-yl)pyridin-2-yl)pyrimidin-4-yl)pyridin-2-yl)pyridine-2-carboxylate | 856887-80-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: ethyl 6-(6-(6-(6-(6-(ethoxycarbonyl)pyridin-2-yl)pyridin-2-yl)pyrimidin-4-yl)pyridin-2-yl)pyridine-2-carboxylate
• 英文别名: Ethyl 6-[6-[6-[6-(6-ethoxycarbonylpyridin-2-yl)pyridin-2-yl]pyrimidin-4-yl]pyridin-2-yl]pyridine-2-carboxylate
• CAS: 856887-80-4
• 化学式: C₃₀H₂₄N₆O₄
• 分子量: 532.558
• InChiKey: CFGLKDXRKZDIBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  40
• 可旋转键数：
  10
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  130
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  ethyl 6-(6-(6-(6-(6-(ethoxycarbonyl)pyridin-2-yl)pyridin-2-yl)pyrimidin-4-yl)pyridin-2-yl)pyridine-2-carboxylate 、 terbium(III) trifluoromethanesulfonate 以 乙腈 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Luminescense properties of new complexes of Eu(III) and Tb(III) with heterotopic ligands

  摘要：

  As a result of coordination between ligands L and L' and europium(III) and terbium(III) ions, the new architectures were formed. The formulae of the complexes have been assigned on the basis of the spectroscopic data in solution and microanalyses. The europium complexes show excellent luminescence properties with high quantum yield (1b-Eu3L2) and effective intramolecular energy transfer from the ligand to the Eu(III) ions. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.08.011
• 作为产物：
  描述：

  6-(6-(6-(6-(6-carboxypyridin-2-yl)pyridin-2-yl)pyrimidin-4-yl)pyridin-2-yl)pyridine-2-carboxylic acid 在 氯化亚砜 作用下， 反应 39.0h， 生成 ethyl 6-(6-(6-(6-(6-(ethoxycarbonyl)pyridin-2-yl)pyridin-2-yl)pyrimidin-4-yl)pyridin-2-yl)pyridine-2-carboxylate
  参考文献：
  名称：

  Preparation of new heterotopic ligands

  摘要：

  A six-step synthesis of two new heterotopic ligands, each possessing two unusual N,N,N,O tetradentate binding Subunits, has been developed. This work presents a particularly facile and rapid synthetic protocol for the preparation of these ligands, which one expected to act as useful components in inorganic self-assembly for the preparation of various types of complexes. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2005.03.131