3-溴硒吩 | 25109-24-4

• 物质功能分类: 化学试剂 - 有机试剂 - 硒化合物
• 分子结构分类: 有机化合物 - 有机卤素化合物 - 芳基卤化物
• 中文名称: 3-溴硒吩
• 英文名称: bromo-3 selenophene
• 英文别名: 3-bromoselenophene；3-bromo-selenophene；Dibrom-3-selenophen；3-Brom-selenophen；3-Bromselenophen
• CAS: 25109-24-4
• 化学式: C₄H₃BrSe
• 分子量: 209.932
• InChiKey: WWYHTIYRNWMTJS-UHFFFAOYSA-N

物化性质

• 沸点：
  71-73 °C(Press: 12 Torr)
• 密度：
  2.1362 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.51
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-溴硒吩 在 正丁基锂 、 对甲苯磺酰叠氮 作用下， 生成 3-azidoselenophene
  参考文献：
  名称：

  Gronowitz, Salo; Zanirato, Paolo, Journal of the Chemical Society. Perkin transactions II, 1994, # 8, p. 1815 - 1820

  摘要：

  DOI：
• 作为产物：
  描述：

  硒酚 在 溴 、 sodium acetate 、 锌 作用下， 生成 3-溴硒吩
  参考文献：
  名称：

  Hallberg, Anders; Liljefors, Sven; Pedaja, Peter, Synthetic Communications, 1981, vol. 11, # 1, p. 25 - 28

  摘要：

  DOI：

文献信息

• [EN] C(SP3)-C(SP2) CROSS-COUPLING REACTION OF ORGANOZINC REAGENTS AND HETEROCYCLIC (PSEUDO)HALIDES<br/>[FR] RÉACTION DE COUPLAGE CROISÉ C(SP3)-C(SP2) DE RÉACTIFS D'ORGANOZINC ET DE (PSEUDO)HALOGÉNURES HÉTÉROCYCLIQUES
  申请人：UNIV HONG KONG SCI & TECH

  公开号：WO2018019291A1

  公开（公告）日：2018-02-01

  Provided is a method of synthesizing a C(sp3)-C(sp2) cross-coupled compound comprising reacting a C(sp3) coupling partner with a C(sp2) coupling partner, a catalyst, and a solvent; wherein the C(sp3) coupling partner comprises an organic zinc reagent; and wherein the C(sp2) coupling partner comprises a heterocyclic halide or a heterocyclic pseudo halide. The method further comprises synthesis of the organic zinc reagent, wherein the synthesis comprises reacting a zinc powder with an acid, filtering, washing, and drying to obtain an activated zinc powder; and reacting the activated zinc powder with a metal iodide catalyst and a second solvent and heating for a predetermined time to obtain the organic zinc reagent.

  提供了一种合成C(sp3)-C(sp2)交叉偶联化合物的方法，包括将一个C(sp3)偶联配体与一个C(sp2)偶联配体、催化剂和溶剂反应；其中C(sp3)偶联配体包括有机锌试剂；而C(sp2)偶联配体包括杂环卤化物或杂环假卤化物。该方法进一步包括合成有机锌试剂，其中合成包括将锌粉与酸反应，过滤，洗涤和干燥以获得活化锌粉；并将活化锌粉与金属碘催化剂和第二溶剂反应并加热一定时间以获得有机锌试剂。
• 一种含氧族元素的并五稠环共轭分子与其衍 生物的合成方法以及用途
  申请人：浙江华显光电科技有限公司

  公开号：CN104370937B

  公开（公告）日：2018-04-10

  本发明涉及一种含氧族元素的并五稠环共轭分子与其衍生物的合成方法及其用途，其中所述含氧族元素的并五稠环共轭分子结构为：所述含氧族元素的并五稠环共轭分子衍生物结构为：。
• [EN] CONJUGATED POLYMERS AND DEVICES INCORPORATING THE SAME<br/>[FR] POLYMÈRES CONJUGUÉS ET DISPOSITIFS LES COMPORTANT
  申请人：RAYNERGY TEK INC

  公开号：WO2015100441A1

  公开（公告）日：2015-07-02

  Disclosed are conjugated polymers having desirable properties as semiconducting materials. Such polymers are cheap and easy to synthesize, and can exhibit good solubility and great solution processibility, and that enable highly efficient OPVs.

  本发明涉及一种具有半导体材料理想特性的共轭聚合物。这些聚合物价格便宜、易于合成，同时具有良好的溶解度和出色的溶液加工性能，能够实现高效率的有机光伏器件。
• CONJUGATED POLYMERS AND DEVICES INCORPORATING THE SAME
  申请人：RAYNERGY TEK INCORPORATION

  公开号：US20160141499A1

  公开（公告）日：2016-05-19

  Disclosed are conjugated polymers having desirable properties as semiconducting materials. Such polymers are cheap and easy to synthesize, and can exhibit good solubility and great solution processibility, and that enable highly efficient OPVs.

  本发明涉及具有半导体材料所需的理想性能的共轭聚合物。这些聚合物便宜且易于合成，并且可以展现良好的溶解度和出色的溶液加工性能，从而使高效率的有机光伏电池成为可能。
• Synthesis, Crystal Structures, and Electrical Properties of Anion Radical Salts of Novel Electron Acceptors, 2,6-Dicyanomethylene-4-oxo-2,6-dihydrocyclopentadithiophene (CPDT-TCNQ) and Its Diselenophene Analogue (CPDS-TCNQ), Having Three Electron-Withdrawing Groups
  作者：Shinji Tarutani、Kazuko Takahashi

  DOI：10.1246/bcsj.77.463

  日期：2004.3

  Novel heterophene analogues of tetracyanodiphenoquinodimethane (TCNDQ) having three electron-withdrawing groups in one molecule, 2,6-dicyanomethylene-4-oxo-2,6-dihydrocyclopentadithiophene (CPDT-TCNQ: 1) and 2,6-dicyanomethylene-4-oxo-2,6-dihydrocyclopentadiselenophene (CPDS-TCNQ: 2), have been synthesized. CPDT-TCNQ and CPDS-TCNQ have a good coplanar conformation and have a fairly high electron-accepting ability due to the existence of the central carbonyl group in addition to the two terminal dicyanomethylene groups. The anion radical salts, Me4X(CPDT-TCNQ)2 (X = N, P, and As), Et4N(CPDT-TCNQ)2, and Me4X(CPDS-TCNQ)2 (X = P and As), showed a metallic conducting behavior (σrt = 260 to 42 S cm−1) down to 130–255 K. In the crystal structures of Me4X(CPDT-TCNQ)2 (X = N, P, and As), which are isostructural with each other, the acceptor molecules form rigid and tight two-dimensional networks consisting of strong S···N and O···H inter-column contacts in the side-by-side direction. However, these salts have an extremely one-dimensional electronic structure along the stacking direction. This fact indicates that the chalcogen atoms in the acceptor molecules do not increase the dimensionality of the electronic structures of the anion radical salts; that property is significantly different from the role of chalcogen atoms of TTF or BEDT-TTF type donor molecules. The existence of the central carbonyl group in CPDT-TCNQ and in CPDS-TCNQ plays a very important role to give metallic anion radical salts due to the rigid conformation. The phase transition at 130 K on Me4N(CPDT-TCNQ)2 is regarded as 2kF CDW instability. The origins of the phase transitions at 165 K for Me4P(CPDT-TCNQ)2 and 185 K for Me4As(CPDT-TCNQ)2 are regarded as 4kF CDW. Thus the phase transition mechanisms of these salts are significantly different from each other, although the crystal structures are isostructural.

  ion离子。

表征谱图