N-methyl-N'-(2-methylphenyl) formamidine | 42572-01-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-methyl-N'-(2-methylphenyl) formamidine
• 英文别名: N-methyl-N'-o-tolyl formamidine；N'-methyl-N-(2-methylphenyl)methanimidamide
• CAS: 42572-01-0
• 化学式: C₉H₁₂N₂
• mdl: MFCD19227998
• 分子量: 148.208
• InChiKey: VHBPKDUEKNEACG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.222
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-methyl-N'-(2-methylphenyl) formamidine 在 三乙胺 作用下， 以 四氢呋喃 、 三氯硫氯甲烷 、 苯 为溶剂， 生成 N-methyl-N-(trichloromethylthio)-N'-o-tolyl formamidine
  参考文献：
  名称：

  Pesticidal N-hydrocarbysulfenyl-N-alkyl-N'-arylformamidines

  摘要：

  揭示了新型杀虫N-烃基磺基衍生物N-烷基-N'-芳基甲酰胺的新型组成物及其在控制无脊椎动物害虫，特别是昆虫和蜱类中的应用方法。其中一些新型化合物特别有效的杀螨剂。

  公开号：

  US03954997A1

文献信息

• [EN] ANTI-INFLAMMATORY COMPLEXES<br/>[FR] COMPLEXES ANTI-INFLAMMATOIRES
  申请人：SIGNUM BIOSCIENCES INC

  公开号：WO2010090845A1

  公开（公告）日：2010-08-12

  Disclosed are certain complexes of AFC compounds and binding agents. Such complexes are useful, among other things, in the treatment of inflammatory diseases or disorders.

  披露了AFC化合物和结合剂的某些复合物。这些复合物在治疗炎症性疾病或紊乱等方面非常有用。
• Pesticidal N,N"-thio and dithio bis(substituted phenyl formamidines)
  申请人：The Upjohn Company

  公开号：US03947591A1

  公开（公告）日：1976-03-30

  Novel pesticidal compounds of the formula: ##SPC1## Wherein R.sub.1 and R.sub.2 are the same or different and are selected from the group consisting of lower alkyl of from 1 to 4 carbon atoms; R.sub.3 and R.sub.4 are the same or different and are selected from the group consisting of hydrogen, halogen, and lower alkyl of from 1 to 4 carbon atoms, n = 1 or 2 provided that when n is 2 then R.sub.1 and R.sub.2 are the same as R.sub.3 and R.sub.4 are the same. The compounds are combined with carriers to prepare compositions and are useful in controlling insect pests either as an insecticide or behavioral modifier and are particularly effective as miticides.

  化合物的式子为：##SPC1## 其中，R.sub.1和R.sub.2相同或不同，选自由1到4个碳原子的低烷基组成的群；R.sub.3和R.sub.4相同或不同，选自氢、卤素和由1到4个碳原子的低烷基组成的群，n = 1或2，但当n为2时，R.sub.1和R.sub.2与R.sub.3和R.sub.4相同。这些化合物与载体结合以制备组合物，可用于控制昆虫害，作为杀虫剂或行为调节剂，特别有效的是作为螨虫剂。
• Novel phosphoramidothioate derivatives, pesticidal compositions containing them, processes for preparing the novel derivatives and the use of the novel derivatives for combating pests
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0002826A1

  公开（公告）日：1979-07-11

  Novel phosphoramidothioate derivatives, pesticidal compositions containing them, processes for preparing the novel derivatives and the use of the novel derivatives for combating pests. Novel compounds are provided which exhibit activity as pesticides for combating fungi, arthropods and/or nematodes. The 'novel compounds have the formula: wherein A is phenyl or naphthyl, each optionally substituted with various defined substituents, R is hydrogen or (C1-C6)alkyl, R1is a) (C1-C6)alkyl optionally substituted with various defined substituents, b) (C3-C8)cycloalkyl, c) (C3-C6)alkenyl optionally substituted with various defined substituents, d) (C3-C6)alkenyl, e) phenylalkyl or naphthylalkyl each having a total of up to eleven carbon atoms and each being optionally substituted in the aryl portion with various defined substituents. R2 is a) (C1-C6)alkylthio, b) phenoxy or naphthoxy each optionally substituted with nitro, or c) a group of the formula -NZ'Z" wherein Z' is hydrogen or (C1-C6)alkyl, and Z" is hydrogen, (C1-C6)alkyl, (C3-C6) alkenyl, di(C,-C3)alkylamino, 2-ethylthioethyl, 2-methoxyethyl or alkoxycarbonylalkyl having up to four carbon atoms in each of the alkoxy and alkyl moieties, R3 is (C,-C,)alkyl, and X is oxygen or sulfur.

  新型硫代磷酸酰胺衍生物、含有这些衍生物的杀虫组合物、新型衍生物的制备工艺以及新型衍生物在防治害虫方面的用途。 本发明提供的新型化合物具有作为杀虫剂防治真菌、节肢动物和/或线虫的活性。这些 "新型化合物 "具有如下式子 式中 A 是苯基或萘基，每个苯基或萘基都可选地被各种定义的取代基取代、 R 是氢或 (C1-C6) 烷基、 R1 是 a) (C1-C6) 烷基，可选择被各种定义的取代基取代、 (C3-C8) 环烷基、 c) 可任选被各种定义的取代基取代的 (C3-C6) 烯基、 d) (C3-C6) 烯基、 e) 苯基烷基或萘基烷基，每个烷基都具有多达 11 个碳原子，且芳基部分任选被各种定义的取代基取代。 R2 是 a) (C1-C6)alkylthio、 b) 苯氧基或萘氧基，各自可选择被硝基取代，或 c) 式-NZ'Z "的基团，其中 Z' 为氢或 (C1-C6) 烷基，Z "为氢、(C1-C6)烷基、(C3-C6) 烯基、二(C,-C3)烷基氨基、2-乙硫基乙基、2-甲氧基乙基或烷氧基羰基烷基，每个烷氧基和烷基中最多有四个碳原子、 R3 是（C,-C,）烷基，以及 X 是氧或硫。
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC BODY
  申请人：Zeon Corporation

  公开号：EP3106478A1

  公开（公告）日：2016-12-21

  This polymerizable compound is represented by a formula (I), this polymerizable composition contains said polymerizable compound and a polymerization initiator, this polymer is obtained by polymerizing the polymerizable compound or polymerizable composition, and this optically anisotropic product is comprised from the polymer. In the formula, each of Y1 to Y8 represents -O-, -S-, -O-C(=O)-, -C(=O)-O-, etc., Ya represents -O-, -S-, -O-C(=O)-, -C(=O)-O-, etc., each of G1 and G2 represents a divalent linear aliphatic group having 1 to 20 carbon atoms, etc., each of Z1 and Z2 represents an alkenyl group having 2 to 10 carbon atoms, etc., Ax represents an organic group having an aromatic ring and 2 to 30 carbon atoms, A1 represents a trivalent aromatic group, etc., each of A2 and A3 represents a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms, each of A4 and A5 represents a divalent aromatic group having 4 to 30 carbon atoms, etc., Q1 represents an alkyl group having 1 to 6 carbon atoms, etc., and each of m and n represents 0 or 1.

  这种可聚合化合物用式（I）表示，这种可聚合组合物含有所述可聚合化合物和聚合引发剂，这种聚合物是通过聚合可聚合化合物或可聚合组合物得到的，这种光学各向异性产品由聚合物组成。式中，Y1 至 Y8 各代表-O-、-S-、 -Ya 代表-O-、-S-、-O-C(=O)-、-C(=O)-O-等，G1 和 G2 各自代表具有 1 至 20 个碳原子的二价线性脂肪族基团等，Z1 和 Z2 各自代表具有 2 至 10 个碳原子的烯基等，Ax 代表具有芳香环和 2 至 30 个碳原子的有机基团，A1 代表三价芳香族基团等、A2 和 A3 各代表具有 3 至 30 个碳原子的二价脂环烃基，A4 和 A5 各代表具有 4 至 30 个碳原子的二价芳香基等，Q1 代表具有 1 至 6 个碳原子的烷基等，m 和 n 各代表 0 或 1。
• PYRIDINECARBOXAMIDES AS CXCR2 MODULATORS
  申请人：Syntrix Biosystems, Inc.

  公开号：EP2942346B1

  公开（公告）日：2020-05-06