isocyanate de phenoxysulfonyle | 14773-85-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: isocyanate de phenoxysulfonyle
• 英文别名: Phenoxysulfonylisocyanate；phenyl N-(oxomethylidene)sulfamate
• CAS: 14773-85-4
• 化学式: C₇H₅NO₄S
• 分子量: 199.187
• InChiKey: BFKZWJPWBGAKLZ-UHFFFAOYSA-N

物化性质

• 沸点：
  106-109 °C(Press: 10 Torr)
• 密度：
  1.36±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  81.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  isocyanate de phenoxysulfonyle 在 水 作用下， 以 正庚烷 为溶剂， 反应 2.0h， 生成 phenyl sulfamate
  参考文献：
  名称：

  EP1736467

  摘要：

  公开号：
• 作为产物：
  描述：

  氯磺酰异氰酸酯 、 苯酚 以 氯苯 为溶剂， 反应 10.0h， 以61%的产率得到isocyanate de phenoxysulfonyle
  参考文献：
  名称：

  Preparation and Antimicrobial Studies of Acyclic Sulfamates.

  摘要：

  A series of acyclic sulfamates have been prepared and tested for antimicrobial activity. Thus, the oxysulfonyl isocyanates, ROSO2NCO (1a, R = 4-methoxyphenyl; 1b, R = phenyl; 1c, R = 4-chlorophenyl and 1d, R = 2,2,2-trifluoroethyl) have been prepared in 76-91% yield from chlorosulfonyl isocyanate. Treatment of lad with glycidol gave the glycidyl carbamates 2a-d. Internal cyclisation afforded the corresponding 3-hydroxymethyl-2-oxazolidinones 3a d, which in turn were hydrolysed to give the free amino alcohols 4a-d. The yields were in the range 39-85%. A preliminary agar diffusion test of 2a-d, 3a d, 4a d indicated 2a-d and 3e to be possible antimicrobial agents. A more thorough analysis of these compounds revealed a minimum inhibition concentration (MIC) of 128 and 64 mg 1(-1) for glycidyl p-methoxyphenoxysulfonylcarbamate (2a) and glycidyl phenoxysulfonylcarbamate (2b) respectively, against Branhamella catarrhalis.

  DOI：

  10.3891/acta.chem.scand.53-0446

文献信息

• Addition of various unsaturated alcohols to sulfonylisocyanate derivatives: Synthesis of new unsaturated N-sulfonyl carbamates
  作者：Ahlem Radhouani、Mohamed Beji

  DOI：10.1080/10426507.2015.1072186

  日期：2016.5.3

  GRAPHICAL ABSTRACT Abstract The synthesis of new unsaturated N-sulfonylcarbamates by the addition of unsaturated alcohols to aroxy(alkoxy)sulfonylisocyanates is reported. The reaction is carried out at room temperature in the presence or absence of solvent, depending on the nature of the starting alcohol. The products were obtained in good yields and characterized with IR, 1H, and 13C NMR and HRMS

  图形摘要 摘要 报道了通过将不饱和醇加成到芳氧基（烷氧基）磺酰基异氰酸酯上来合成新的不饱和 N-磺酰基氨基甲酸酯。根据起始醇的性质，该反应在室温下在溶剂存在或不存在下进行。产品以良好的收率获得，并通过 IR、1H 和 13C NMR 和 HRMS 分析进行表征。
• 4-thioxo-2-azetidinones by cycloaddition of thioketenes with isocyanates
  作者：Ernst Schaumann、Armin Röhr、Gunadi Adiwidjaja

  DOI：10.1016/s0040-4039(00)92874-0

  日期：1980.1

  The (2+2) cycloaddition of thioketenes with isocyanates yields 4-thioxo-2-azetidinones , which can be hydrolyzed to the N-unsubstituted compound and thus used as versatile intermediates.

  硫烯酮与异氰酸酯的（2 + 2）环加成反应生成4-thioxo-2-azetidinones ，该酮可水解为N-未取代的化合物，因此可用作通用中间体。
• NONAQUEOUS ELECTROLYTE SOLUTION AND ENERGY DEVICE USING SAME
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20200274199A1

  公开（公告）日：2020-08-27

  The present invention provides an energy device having excellent properties. Also provided is a nonaqueous electrolyte solution containing a compound represented by the following Formula (1), wherein R 11 , R 12 and R 13 each independently represent an organic group having 1 to 3 carbon atoms; and R 11 and R 12 , R 11 and R 13 , or R 12 and R 13 are optionally bound with each other to form a 5-membered ring or a 6-membered ring, with a proviso that a total number of carbon atoms of R 11 , R 12 and R 13 is 7 or less.

  本发明提供了一种具有优异性能的能源装置。同时还提供了一种非水电解质溶液，其中包含由以下式（1）表示的化合物，其中R11、R12和R13各自独立地表示具有1到3个碳原子的有机基团；且R11和R12、R11和R13或R12和R13可以选择地相互结合形成一个5元环或6元环，条件是R11、R12和R13的总碳原子数不超过7。
• Herbicidal sulfamates and preparation and use thereof
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0004163A1

  公开（公告）日：1979-09-19

  N-(Heterocyclicaminocarbonyl) arylsulfamates of the general formula wherein R1 is H, OCH3 or alkyl of 1-3 carbons; X and Y are CH3, CH3CH2, various alkoxy groups, CH3S, CH3CH2S, or X may be CF3 or Cl; Z is CH or N; R2-R6 are H or various substituents; and agriculturally suitable salts thereof, are of interest for plant growth retardation, brush control and weed control in crops. They may be made by reacting an appropriate arylox- aryloxysulfonyl isocyanate with an appropriate 2-aminopyrimidine or 2-amino-1,3,5-triazine. For use, an effective amount of the compound is applied to the locus of the undesired vegetation to be controlled.

  通式为 N-(杂环氨基羰基)芳基氨基磺酸盐 其中 R1 为 H、OCH3 或 1-3 个碳原子的烷基； X 和 Y 是 CH3、CH3CH2、各种烷氧基、CH3S、CH3CH2S，或 X 可以是 CF3 或 Cl； Z 是 CH 或 N； R2-R6 是 H 或各种取代基； 及其农业上适用的盐类，可用于作物的植物生长延缓、灌木丛控制和杂草控制。它们可通过适当的芳氧基-芳氧基磺酰基异氰酸酯与适当的 2-氨基嘧啶或 2-氨基-1,3,5-三嗪反应制成。使用时，将有效量的化合物施用到需要控制的不想要的植被上。
• Herbicidal triazole ureas
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0073562A2

  公开（公告）日：1983-03-09

  Triazole and imidazole ureas of the formulae wherein R' is H. CH3 or C2H5; R1 is H, C! or various organic groups: R1' is CH3, C2H5, SCH3, OCH3 or OC2H5: R2 is alkyl, substituted alkyl, alkenyl or alkynyl: R2' is CH3, C2H5 or OCH3; W is O or S: and Z and Z' are phenyl, naphthyl, pyridyl or thienyl, any of which may be substituted, or Z may additionally be an optionally substituted benzyl, phenoxy or furyl groupe; exhibit pre-emergence and post-emergence herbicidal activity. The compounds may be formulated for agricultural use in conventional manner. The novel triazole derivatives may be made by reacting a compound of formula with an isocyanate or isothiocyanate of formula The imidazole derivatives may be made analogously.

  式中的三唑和咪唑脲类 其中 R' 是 H. CH3 或 C2H5； R1 是 H、C！或各种有机基团： R1' 是 CH3、C2H5、SCH3、OCH3 或 OC2H5： R2 是烷基、取代烷基、烯基或炔基： R2' 是 CH3、C2H5 或 OCH3； W 是 O 或 S：以及 Z 和 Z'是苯基、萘基、吡啶基或噻吩基，其中任何一个都可以被取代，或者 Z 还可以是任选取代的苄基、苯氧基或呋喃基； 具有萌芽前和萌芽后除草活性。这些化合物可按常规方法配制成农用制剂。 新型三唑衍生物可通过将式化合物 与式中的异氰酸酯或异硫氰酸酯反应制得。 咪唑衍生物可通过类似方法制得。