myristyldimethylamine 1-oxide

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: myristyldimethylamine 1-oxide
• 英文别名: N-methyl-N-tetradecylformamide
• 化学式: C₁₆H₃₃NO
• 分子量: 255.444
• InChiKey: RDWJZODGDKGKFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  十四烷基二甲基叔胺 、 potassium thioacyanate 在 叔丁基过氧化氢 、 iron(II) chloride 作用下， 以 甲醇 、 癸烷 为溶剂， 反应 1.5h， 以46%的产率得到2-(methyl(tetradecyl)amino)acetonitrile
  参考文献：
  名称：

  硫氰酸钾作为氰化物来源，用于叔胺的氧化α-氰化反应

  摘要：

  安全处理的硫氰酸钾在硫上的氧化释放出氰化物单元，该氰化物单元在存在共氧化叔胺的情况下被捕集，形成α-氨基腈。这些氰化物在水溶液中起作用，不需要催化剂，也不会形成有毒的副产物。

  DOI：

  10.1021/jo502846c

文献信息

• INFRARED DYE FOR SILVER HALIDE-BASED PHOTOGRAPHIC ELEMENTS
  申请人：Zengerle Paul L.

  公开号：US20090234131A1

  公开（公告）日：2009-09-17

  A non-infrared sensitized low silver photographic element with a non-light sensitive layer, preferably an antihalation layer, containing a diphenylaminocyclopentene heptacyanine benzothiazolium infrared dye where the benzothiazolium groups have electron-withdrawing substituents on the phenyl ring and solubilzed alkyl groups on the nitrogen. The infrared dye can be present as a liquid-crystalline dispersion. This class of infrared dyes form J-aggregrated species in a liquid-crystalline or a solid particle dispersion with high IR density and low visible absorbance.

  一种非红外敏化低银光感光元件，具有非光敏感层，最好是一种含有二苯胺环戊烯七氰基苯并噻唑离子红外染料的抗光散层，其中苯并噻唑离子基团在苯环上具有电子吸引取代基，氮原子上具有可溶性烷基基团。红外染料可以以液晶分散形式存在。这类红外染料在液晶或固体颗粒分散体系中形成J-聚集物种，具有高红外密度和低可见吸收率。
• Azo coupling reactions of hydrophobic compounds
  申请人：Mineur Catherine

  公开号：US20060235227A1

  公开（公告）日：2006-10-19

  A process for forming a diazo compound comprises reacting an organic compound bearing an acidic hydrogen with an aryl-diazonium salt in the presence of an inorganic base and a non-halogenated solvent. The process is simpler and more environmentally friendly than known processes.

  形成重氮化合物的过程包括在无卤代溶剂存在下，将带有酸性氢的有机化合物与芳基重氮盐反应，在无机碱的存在下进行。该过程比已知的过程更简单和更环保。
• LIGHT EMITTING DEVICE CONTAINING PHOSPHORESCENT COMPLEX
  申请人：Ren Xiaofan

  公开号：US20080020237A1

  公开（公告）日：2008-01-24

  An OLED device comprises a cathode, an anode, and has therebetween a light emitting layer comprising a phosphorescent emitter represented by Formula (I): L n M   (I) wherein each L is a cyclometallated ligand with at least one containing a coumarin group, M is Ir or Pt, and n is 3 when M is Ir and 2 when M is Pt. The invention also comprised the compound of formula (I).

  一种OLED器件包括阴极、阳极，并且在两者之间具有一个发光层，该发光层包括由式(I)表示的磷光发射体：LnM  (I)其中每个L是至少含有一个香豆素基团的环金属配体，M是Ir或Pt，当M为Ir时，n为3，当M为Pt时，n为2。该发明还包括式(I)的化合物。
• Photographic yellow dye-forming couplers
  申请人：EASTMAN KODAK COMPANY

  公开号：EP1014186A1

  公开（公告）日：2000-06-28

  A photographic element comprises a light sensitive silver halide emulsion layer having associated therewith an open chain α-carbonyl acetanilide yellow dye-forming coupler having the formula: wherein R1 is selected from the group consisting of alkyl, aryl, heterocyclic, and amino groups, provided that R1 may form a ring bonded to another carbon atom which is a member of Ring "A"; each R2 is independently selected from the group consisting of those substituents having a Hammett's sigma value of 0 or less, and m is from 0 to 4; each R3 and R4 for each of the n carbon atoms is independently selected from the group consisting of hydrogen, alkoxy, aryl, heterocyclic, aryloxy, and alkyl groups, and n is 0 to 16; each R5 independently selected from the group consisting of amino, alkyl groups, and groups linked to the "B" ring by oxygen or sulfur, and p is 1 to 3, provided that two R5 groups may join to form a ring; R6 is selected from the group consisting of alkyl, aryl, and amino groups; each L is independently a divalent linking group and q is 0 to 3; and Ring "A" is bonded indirectly to the 3-, 4-, or 5-position of Ring "B"; and Z is hydrogen, or a group capable of coupling-off when the coupler reacts with an oxidized color developing agent.

  一种摄影元素包括具有与之相关联的开链α-酮基乙酰苯胺黄色染料生成偶联剂的感光性银卤化物乳胶层，其具有以下结构式：其中R1选自烷基、芳基、杂环基和氨基组成的群，前提是R1可能形成与另一个碳原子结合的环，该碳原子是“A”环的成员；每个R2独立地选自具有Hammett的sigma值为0或更低的取代基的群，m为0至4；每个R3和R4对于n个碳原子中的每个碳原子，独立地选自氢、烷氧基、芳基、杂环基、芳氧基和烷基组成的群，n为0至16；每个R5独立地选自氨基、烷基和通过氧或硫连接到“B”环的基团，p为1至3，前提是两个R5基团可以结合形成环；R6选自烷基、芳基和氨基组成的群；每个L独立地是二价连接基团，q为0至3；和“A”环间接连接到“B”环的3-、4-或5-位置；Z是氢，或者是在偶联剂与氧化的着色显影剂发生反应时能够偶联脱落的基团。
• Synthesis for quinacridone compounds
  申请人：——

  公开号：US20040002605A1

  公开（公告）日：2004-01-01

  Disclosed is a process for forming a N,N′-diarylquinacridone compound comprising the step of reacting a 1,4-dialkylcarboxylate-2,5-bis(N -arylamino) benzene with an iodoaryl compound to form the corresponding 2,5 -bis(N-diarylamino) compound. The process is versatile and provides high yields and purity for the synthesis of N,N′-diarylquinacridone compounds.

  本文披露了一种形成N,N'-二芳基喹诺啉酮化合物的过程，包括步骤是将1,4-二烷基羧酸酯-2,5-双(N-芳基氨基)苯与碘芳基化合物反应，形成相应的2,5-双(N-二芳基氨基)化合物。该过程具有多功能性，可高产率、高纯度地合成N,N'-二芳基喹诺啉酮化合物。