2-[(3-苯基苯氧基)甲基]环氧乙烷 | 56874-00-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-[(3-苯基苯氧基)甲基]环氧乙烷
• 英文名称: 2-{[([1,1'-biphenyl]-3-yl)oxy]methyl}oxirane
• 英文别名: 2-[(3-phenylphenoxy)methyl]oxirane
• CAS: 56874-00-1
• 化学式: C₁₅H₁₄O₂
• 分子量: 226.275
• InChiKey: DCYSZVJAQDUNOS-UHFFFAOYSA-N

物化性质

• 沸点：
  195-203 °C(Press: 2 Torr)
• 密度：
  1.136±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-[(3-苯基苯氧基)甲基]环氧乙烷 、 5,5-二甲基海因 在 吡啶 作用下， 以 乙醇 为溶剂， 反应 4.0h， 以0.71 g的产率得到3-(3'-(3''-phenylphenoxy)-2'-hydroxypropyl)-5,5-dimethylimidazolidine-2,4-dione
  参考文献：
  名称：

  Analysis of β-amino alcohols as inhibitors of the potential anti-tubercular target N-acetyltransferase

  摘要：

  The synthesis and inhibitory potencies of a novel series of beta-amino alcohols, based on the hit-compound 3-[3`-(4 ''-cyclopent-2```-en-1```-ylphenoxy)-2`-hydroxypropyl]-5,5 dimethylimidazolidine-2,4-dione as specific inhibitors of mycobacterial N-acetyltransferase (NAT) enzymes are reported. Effects of synthesised compounds on growth of Mycobacterium tuberculosis have been determined. (c) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmcl.2010.12.099
• 作为产物：
  描述：

  间羟基联苯 、 环氧氯丙烷 在 sodium hydroxide 作用下， 生成 2-[(3-苯基苯氧基)甲基]环氧乙烷
  参考文献：
  名称：

  Ether

  摘要：

  公开号：

  US02181085A1

文献信息

• NOVEL HOLOGRAPHIC MEDIA AND PHOTOPOLYMERS
  申请人：Fäcke Thomas

  公开号：US20110065827A1

  公开（公告）日：2011-03-17

  The invention relates to holographic media containing specific photopolymers, a process for the production thereof, and unsaturated glycidyl ether acrylate urethanes as writing monomers which are suitable for the preparation of photopolymers.

  本发明涉及包含特定光聚合物的全息介质，其生产过程，以及适用于制备光聚合物的不饱和环氧丙烯酸酯脲。
• Holographic media and photopolymers
  申请人：Bayer MaterialScience AG

  公开号：US08329773B2

  公开（公告）日：2012-12-11

  The invention relates to holographic media containing specific photopolymers, a process for the production thereof, and unsaturated glycidyl ether acrylate urethanes as writing monomers which are suitable for the preparation of photopolymers.

  本发明涉及含有特定光聚合物的全息介质，其生产过程以及适用于制备光聚合物的不饱和环氧丙烯酸酯尿素写入单体。
• Difunctional (meth)acrylate writing monomers
  申请人：Fäcke Thomas

  公开号：US09057946B2

  公开（公告）日：2015-06-16

  The invention relates to compounds, of formula (I) in which X is CH3 or hydrogen, Z is a linear or branched C2 to C4 alkyl radical, R is a linear or branched, optionally heteroatom-substituted aliphatic, aromatic or araliphatic radical, Y in each occurrence is independently hydrogen, methyl, ethyl, propyl, n-butyl, tert-butyl, chlorine, bromine, iodine, methylthio, phenyl or phenylthio, n is from 0 to 4 and m is from 0 to 5. The invention further relates to the use of such a compound as writing monomer in a photopolymer formulation. In addition, a photopolymer formulation comprising as least a polyisocyanate component, a polyol component, a photoinitiator and a compound of formula (I) as writing monomer, and also the use of the photopolymer formulation for producing holographic media, are likewise subjects of the invention.

  本发明涉及式（I）的化合物，其中X是CH3或氢，Z是线性或分支的C2到C4烷基基团，R是线性或分支的、可选地含杂原子的脂肪族、芳香族或芳烃基团，Y在每次出现时独立地是氢、甲基、乙基、丙基、正丁基、叔丁基、氯、溴、碘、甲硫基、苯基或苯硫基，n为0到4，m为0到5。本发明还涉及将这种化合物用作光聚合物配方中的写入单体的用途。此外，本发明还涉及一种光聚合物配方，包括至少一种聚异氰酸酯组分、一种聚醇组分、一个光引发剂和式（I）的化合物作为写入单体，以及使用该光聚合物配方制备全息媒体的用途。
• DIFUNCTIONAL (METH)ACRYLATE WRITING MONOMERS
  申请人：Fäcke Thomas

  公开号：US20130252140A1

  公开（公告）日：2013-09-26

  The invention relates to compounds, of formula (I) in which X is CH 3 or hydrogen, Z is a linear or branched C2 to C4 alky radical, R is a linear or branched, optionally heteroatom-substituted aliphatic, aromatic or araliphatic radical, Y in each occurrence is independently hydrogen, methyl, ethyl, propyl, n-butyl, tert-butyl, chlorine, bromine, iodine, methylthio, phenyl or phenylthio, n is from 0 to 4 and m is from 0 to 5. The invention further relates to the use of such a compound as writing monomer in a photopolymer formulation. In addition, a photopolymer formulation comprising as least a polyisocyanate component, a polyol component, a photoinitiator and a compound of formula (I) as writing monomer, and also the use of the photopolymer formulation for producing holographic media, are likewise subjects of the invention.

  本发明涉及公式(I)中的化合物，其中X为CH3或氢，Z为线性或支链的C2到C4烷基基团，R为线性或支链的、可选地含杂原子的脂肪族、芳香族或芳基脂肪族基团，Y在每次出现时独立地为氢、甲基、乙基、丙基、正丁基、叔丁基、氯、溴、碘、甲硫基、苯基或苯硫基，n为0到4，m为0到5。本发明还涉及将该化合物用作光聚物配方中的写入单体的用途。此外，一种光聚物配方包括至少聚异氰酸酯组分、聚醇组分、光引发剂和公式(I)中的化合物作为写入单体，以及使用该光聚物配方制备全息媒体，也是本发明的主题。
• Neue holografische Medien und Photopolymere
  申请人：Bayer MaterialScience AG

  公开号：EP2219075A1

  公开（公告）日：2010-08-18

  Die Erfindung betrifft holografische Medien enthaltend spezielle Photopolymere, ein Verfahren zu deren Herstellung, sowie ungesättigte Glycidyletheracrylaturethane als Schreibmonomere, die sich zur Herstellung von Photopolymeren eignen.

  本发明涉及含有特殊光聚合物的全息介质及其生产工艺，以及作为适合生产光聚合物的书写单体的不饱和缩水甘油醚丙烯酸乙烷。