[Ru(η5,η1-C5H2Me2CO2(CH2)2PPh2)(CH3CN)2][PF6] | 261359-76-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ru(η5,η1-C5H2Me2CO2(CH2)2PPh2)(CH3CN)2][PF6]
• 英文别名: [(η5:η1-2,4-Me2C5H2CO2CH2CH2PPh2)Ru(MeCN)2][PF6]；acetonitrile;2-diphenylphosphanylethyl 2,4-dimethylcyclopenta-1,3-diene-1-carboxylate;ruthenium(2+);hexafluorophosphate
• CAS: 261359-76-6
• 化学式: C₂₆H₂₈N₂O₂PRu*F₆P
• 分子量: 677.528
• InChiKey: HRHXEHLIOCSACP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  三甲基膦 、 [Ru(η5,η1-C5H2Me2CO2(CH2)2PPh2)(CH3CN)2][PF6] 以 丙酮 为溶剂， 以100%的产率得到[(η5:η1-2,4-Me2-C5H2CO2CH2CH2PPh2)Ru(trimethylphosphine)(acetonitrile)][PF6]
  参考文献：
  名称：

  Highly selective induction of metal-centered chirality in the ligand exchange reaction of planar-chiral cyclopentadienyl–ruthenium complex bearing an anchor phosphine ligand

  摘要：

  用膦和亚磷酸处理平面手性环戊二烯膦钌配合物，可诱导出以金属为中心的手性，并具有很高的立体选择性（≥99% de）。

  DOI：

  10.1039/b009412i
• 作为产物：
  描述：

  benzene;2-diphenylphosphanylethyl 3,5-dimethylcyclopenta-1,3-diene-1-carboxylate;ruthenium(2+);hexafluorophosphate 、 乙腈 以 乙腈 为溶剂， 以>99的产率得到[Ru(η5,η1-C5H2Me2CO2(CH2)2PPh2)(CH3CN)2][PF6]
  参考文献：
  名称：

  Dodo, Noriko; Matsushima, Yuji; Uno, Mitsunari, Journal of the Chemical Society, Dalton Transactions, 2000, # 1, p. 35 - 42

  摘要：

  DOI：

文献信息

• Control of Stereochemistry at the Metal Center in Planar-Chiral Cyclopentadienyl Ruthenium Complexes with Anchor Phosphine on Complexation with Salicylideneaminato Ligands
  作者：Kiyotaka Onitsuka、Yoshiki Ajioka、Yuji Matsushima、Shigetoshi Takahashi

  DOI：10.1021/om0102246

  日期：2001.7.1

  studies including NOE measurements revealed that the configuration of the major isomers is SCpRRu/RCpSRu. Similar reactions of planar-chiral cyclopentadienyl ruthenium complexes [η5-C5H2(Me)(R)COOEt}Ru(PPh3)(MeCN)2][PF6] (7) (7a, R = Me; 7b, R = Ph) having no anchor phosphine ligands with 2 also gave salicylideneaminato complexes (8 and 9) with a low selectivity. Epimerization of a pure sample of the major

  平面手性的环戊二烯基膦钌配合物的反应[η 5，η 1 - C 5 ħ 2（Me）的（R）COO（CH 2）2 PPH 2 }钌（MeCN中）2 ] [PF 6 ]（1A， R = Me; 1b，R = Ph）与水杨内酰胺钠（2）导致形成水杨内酰胺络合物（3和4，R = Me; 5和6，R = Ph）以高选择性（高达> 99％de）诱导金属中心手性。产物的非对映选择性不取决于水杨基亚胺基配体的芳环上的取代基，而是取决于环戊二烯基和亚氨基上的氮的取代基。X射线衍射和NMR研究（包括NOE测量）表明，主要异构体的构型为S Cp R Ru / R Cp S Ru。平面手性的环戊二烯基的钌络合物的类似反应[η 5 - C 5 ħ 2（Me）的（R）COOEt烷基}钌（PPH 3）（MeCN中）2 ] [PF 6 ]（7）（7a，R ＝ Me；7b，R ＝ Ph）不具有2的锚定膦配体，也产生了低选
• Regio- and Enantioselective O-Allylation of Phenol and Alcohol Catalyzed by a Planar-Chiral Cyclopentadienyl Ruthenium Complex
  作者：Kiyotaka Onitsuka、Haruki Okuda、Hiroaki Sasai

  DOI：10.1002/anie.200704457

  日期：2008.2.8
• Enantioface-Selective Coordination of Prochiral 1,3-Dienes to Planar-Chiral Cyclopentadienyl-Ruthenium Complexes
  作者：Yuji Matsushima、Kiyotaka Onitsuka、Shigetoshi Takahashi

  DOI：10.1021/om049917n

  日期：2004.5.1

  The treatment of planar-chiral (eta(5):eta(1) cyclopentadienylphosphine)bis(acetonitrile)ruthenium complexes 1 with prochiral dienes led to the ligand-exchange reaction that gave (eta(5):eta(1)- cyclopentadienylphosphine)(eta(4)-diene)ruthenium complexes 4-6 and 8-11 with high enantio-face selectivity (up to > 99% de). The configuration of the (eta(4)-diene)ruthenium complexes was determined by crystallographic study of (eta(4)-isoprene)ruthenium complex 6b-I and spectral analyses, including NOE measurements. The selectivity of the reaction is under thermodynamic control of the resulting eta(4)-diene complexes and is affected by the substituents on both the cyclopentadienyl ligand and the diene.
• Diastereoselective Oxidative Addition of Allyl Chloride to Planar-Chiral Cyclopentadienyl−Ruthenium Complexes
  作者：Yuji Matsushima、Kiyotaka Onitsuka、Shigetoshi Takahashi

  DOI：10.1021/om049616d

  日期：2004.8.1

  The reaction of planar-chiral cyclopentadienyl-ruthenium complexes with allyl chloride at room temperature resulted in the diastereoselective formation of pi-allyl-ruthenium complexes, in which the chirality at the Ru center depended on the substituent at the 4-position of the cyclopentadienyl group. Epimerization at the Ru center of pi-allyl complexes at 90 degreesC suggested that the diastereoselectivity was under kinetic control.