phenyl-phosphonochloridous acid phenyl ester | 2171-93-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl-phosphonochloridous acid phenyl ester
• 英文别名: Chloro-phenoxy-phenylphosphane
• CAS: 2171-93-9
• 化学式: C₁₂H₁₀ClOP
• 分子量: 236.638
• InChiKey: QEQRZYWARAIAMX-UHFFFAOYSA-N

物化性质

• 沸点：
  312.9±25.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  phenyl-phosphonochloridous acid phenyl ester 在 溴 作用下， 以 氯仿 为溶剂， 生成 3.4-Dibrom-1-phenoxy-phospholan-1-oxyd
  参考文献：
  名称：

  Synthesis of heterocyclic compounds containing phosphorus in the ring

  摘要：

  DOI：

  10.1007/bf00907487
• 作为产物：
  描述：

  二苯基苯基亚膦酸酯 、 氯 生成 phenyl-phosphonochloridous acid phenyl ester
  参考文献：
  名称：

  GLOEDE, J.;COSTISELLA, B.;GROSS, H., Z. ANORG. UND ALLG. CHEM., 1986, 535, N 4, 221-228

  摘要：

  DOI：

文献信息

• Method for the separation of acids from chemical reaction mixtures by means of ionic fluids
  申请人：Volland Martin

  公开号：US20050020857A1

  公开（公告）日：2005-01-27

  Process for preparing aminodihalophosphines, diaminohalophosphines, triaminophosphines, phosphorous ester diamides, aminophosphines, diaminophosphines, phosphorous ester amide halides and aminophosphine halides with elimination of an acid in the presence of an auxiliary base, wherein the auxiliary base b) and the acid form a salt which is liquid at temperatures at which the desired product is not significantly decomposed during the process of separating off the liquid salt and c) the salt of the auxiliary base forms two immiscible liquid phases with the desired product or the solution of the desired product in a suitable solvent.

  制备氨基二卤代膦、二胺卤代膦、三胺膦、磷酸酯二酰胺、氨基膦、二氨基膦、磷酸酯酰胺卤和氨基膦卤的过程，其中在辅助碱存在下消除酸，辅助碱b）和酸形成一种在所需产品在过程中分离液态盐时不会明显分解的温度下为液态的盐，并且c）辅助碱的盐与所需产品或所需产品在适当溶剂中的溶液形成两个不相溶的液态相。
• SEPARATION OF ACIDS FROM CHEMICAL REACTION MIXTURES BY MEANS OF IONIC LIQUIDS
  申请人：Volland Martin

  公开号：US20080083606A1

  公开（公告）日：2008-04-10

  Process for preparing aminodihalophosphines, diaminohalophosphines, triaminophosphines, phosphorous ester diamides, aminophosphines, diaminophosphines, phosphorous ester amide halides and aminophosphine halides with elimination of an acid in the presence of an auxiliary base, wherein the auxiliary base b) and the acid form a salt which is liquid at temperatures at which the desired product is not significantly decomposed during the process of separating off the liquid salt and c) the salt of the auxiliary base forms two immiscible liquid phases with the desired product or the solution of the desired product in a suitable solvent.

  制备氨基二卤代膦、双氨基卤代膦、三氨基膦、磷酸酯二酰胺、氨基膦、双氨基膦、磷酸酯酰胺卤和氨基膦卤的过程，其中在辅助碱存在下消除酸，该辅助碱b）和酸形成一种盐，在分离液态盐的过程中，所需产物在不显著分解的温度下，该盐是液态的；c）辅助碱的盐与所需产物或所需产物在适当溶剂中的溶液形成两个不相溶的液态相。
• Chauzov, V. A.; Studnev, Yu. N.; Ragulin, L. I., Journal of general chemistry of the USSR, 1989, vol. 59, # 6.1, p. 1146 - 1148
  作者：Chauzov, V. A.、Studnev, Yu. N.、Ragulin, L. I.、Fokin, A. V.

  DOI：——

  日期：——
• Genkina,G.K. et al., Journal of general chemistry of the USSR, 1968, vol. 38, p. 2430 - 2433
  作者：Genkina,G.K. et al.

  DOI：——

  日期：——
• US7767852B2
  申请人：——

  公开号：US7767852B2

  公开（公告）日：2010-08-03