diphenyl bromophosphite | 70445-76-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenyl bromophosphite
• 英文别名: bromo-diphenoxy-phosphine；Brom-diphenoxy-phosphin；Phosphorigsaeure-diphenylester-bromid；Diphenylphosphorbromidit；bromo(diphenoxy)phosphane
• CAS: 70445-76-0
• 化学式: C₁₂H₁₀BrO₂P
• 分子量: 297.088
• InChiKey: DLTNIVLVYWVQGP-UHFFFAOYSA-N

物化性质

• 沸点：
  189-192 °C(Press: 11 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  diphenyl bromophosphite 在 selenium 作用下， 生成 bromoselenophosphoric acid O,O'-diphenyl ester
  参考文献：
  名称：

  Strecker; Grossmann, Chemische Berichte, 1916, vol. 49, p. 75

  摘要：

  DOI：
• 作为产物：
  描述：

  tris(2,2,3,3,4,4,5,5-octafluoropentyl) phosphite 、 1H,1H,5H-octafluoropentyl phosphorodibromidite 生成 diphenyl bromophosphite
  参考文献：
  名称：

  Chauzov, V. A.; Studnev, Yu. N.; Ragulin, L. I., Journal of general chemistry of the USSR, 1989, vol. 59, # 6.1, p. 1146 - 1148

  摘要：

  DOI：

文献信息

• Catalyst for polymerization and co-polymerization of ethylene
  申请人：——

  公开号：US20010031694A1

  公开（公告）日：2001-10-18

  The present invention relates to a catalyst for polymerization and co-polymerization of ethylene. More particularly, the present invention relates to a solid titanium catalyst containing magnesium, wherein said catalyst is produced by preparing a magnesium solution by contact-reacting a halogenated magnesium compound with alcohol; reacting said solution with an ester compound having at least one hydroxy group, or a phosphorous compound and a silicon compound having alkoxy groups; producing a solid component with an adjusted particle morphology by adding a mixture of a titanium compound and a silicon compound; reacting the same with an aluminum compound; and then reacting the same with a titanium compound, or a titanium compound and a vanadium compound. As a result, the catalyst of the present invention has high catalytic activity with excellent catalyst morphology.

  本发明涉及一种乙烯聚合和共聚合催化剂。更具体地说，本发明涉及一种含镁的固体钛催化剂，其中所述催化剂是通过以下方法制备的：将卤代镁化合物与醇接触反应制备镁溶液；将所述溶液与具有至少一个羟基的酯化合物或磷化合物和具有烷氧基的硅化合物反应；加入钛化合物和硅化合物的混合物，使其与铝化合物反应，然后与钛化合物或钛化合物和钒化合物反应，制得具有调整颗粒形态的固体组分。因此，本发明的催化剂具有很高的催化活性和优异的催化剂形态。
• Catalyst for polymerization and copolymerization of ethylene
  申请人：——

  公开号：US20040033888A1

  公开（公告）日：2004-02-19

  A solid titanium complex catalyst for polymerization and copolymerization of ethylene is prepared by the process comprising: (1) preparing a magnesium solution by reacting a halogenated magnesium compound with an alcohol; (2) reacting the magnesium solution with a phosphorus compound and a silicon compound having at least one alkoxy group to produce a magnesium composition; and (3) producing a solid titanium catalyst through recrystallization by reacting the magnesium composition solution with a mixture of a titanium compound and a haloalkane compound; and optionally reacting the solid titanium catalyst with an additional titanium compound. The solid titanium complex catalyst for polymerization and copolymerization of ethylene according to present invention exhibits high polymerization activity, and can be advantageously used in the polymerization and copolymerization of ethylene to produce polymers of high bulk density and narrow molecular weight distribution.

  一种用于乙烯聚合和共聚的固体钛络合物催化剂的制备过程包括(1) 将卤代镁化合物与醇反应制备镁溶液；(2) 将镁溶液与磷化合物和具有至少一个烷氧基的硅化合物反应制备镁组合物；(3) 将镁组合物溶液与钛化合物和卤代烃化合物的混合物反应，通过重结晶制备固体钛催化剂；还可选择将固体钛催化剂与另一种钛化合物反应。根据本发明，用于乙烯聚合和共聚的固体钛复合催化剂具有很高的聚合活性，可以很好地用于乙烯的聚合和共聚，生产出体积密度高、分子量分布窄的聚合物。
• Method for preparing catalyst for olefin polymerization
  申请人：——

  公开号：US20040063572A1

  公开（公告）日：2004-04-01

  Disclosed is a preparation method of titanium catalyst for olefin polymerization, the method comprising (1) preparing magnesium compound solution by resolving non-deoxidative magnesium halide and IIIA group atom compound in a solvent mixture of cyclic ether, at least one alcohol, phosphorus compound and organosilane with or without hydrocarbon solvent; (2) reacting said magnesium compound solution with titanium compound, silicon compound, tin compound or mixture thereof to produce a support; and (3) reacting said support with titanium compound and electron donor to produce solid complex titanium catalyst, wherein the particle size and particle size distribution f said catalyst are regulated by controlling solubility of the reactants in said steps (2) and/or (3).

  本发明公开了一种用于烯烃聚合的钛催化剂的制备方法，该方法包括：(1)通过在环醚、至少一种醇、磷化合物和有机硅烷的混合溶剂中溶解非氧化性卤化镁和IIIA基团原子化合物来制备镁化合物溶液，可以使用或不使用烃溶剂；(2) 将所述镁化合物溶液与钛化合物、硅化合物、锡化合物或其混合物反应，生成载体；以及 (3) 将所述载体与钛化合物和电子供体反应，生成固体复合钛催化剂，其中所述催化剂的粒度和粒度分布可通过控制所述步骤（2）和/或（3）中反应物的溶解度来调节。
• Krolevets, A. A.; Dolodonov, I. S., Journal of general chemistry of the USSR, 1992, vol. 62, # 10.1, p. 1872 - 1876
  作者：Krolevets, A. A.、Dolodonov, I. S.

  DOI：——

  日期：——
• Principles of Phosphorus Chemistry. VIII. Reorganization of Triply Connected Monophosphorus Compounds
  作者：Ekkehard Fluck、John R. Van Wazer、Leo C. D. Groenweghe

  DOI：10.1021/ja01533a005

  日期：1959.12